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Jeopardy Vocabulary Dehydration Synthesis/ Combustion Electrophilic Hydrogenation/ Electrophilic addition - HX Radical reactions addition - HOH $100 $100 $100 $100 $100 $200 $200 $200 $200 $200 $300 $300 $300 $300 $300 $400 $400 $400 $400 $400 $500 $500 $500 $500 $500 Final Jeopardy 1 - $100 What is the positively charged carbon called? Carbocation 1 - $200 What is a species with a lone, unpaired electron called? A free-radical 1 - $300 What is a positively charged substance desired negative charge called? An electrophile 1 - $400 What is the type of addition that occurs when addition to an alkene occurs on the same side of the plane of atoms? Syn Addition 1 - $500 What is the name of the rule that states that the nucleophilic part of the reagent will bind with the most stable carbon of the substrate? Markovnikov’s rule 2 - $100 What is produced through the dehydration synthesis reaction between two primary alcohols? An ether 2 - $200 What is the best acid to use to catalyze a dehydration synthesis reaction (in part due to its strong dehydrating ability)? H2SO4 (sulfuric acid) 2 - $300 What ester is made when reacting butyric acid (butanoic acid) with methanol? Methyl butanoate 2 - $400 What is the hydrocarbon being burned if exactly 5 moles of molecular oxygen is needed for complete combustion of this alkane? Propane (C3H8) 2 - $500 What are the products of COMPLETE combustion? Carbon Dioxide & Water Carbon monoxide & carbon are produced when there are insufficient amounts of oxygen. 3 - $100 What type of alkene is ethene; symmetrical or unsymmetrical? symmetrical 3 - $200 What is the major product for the electrophilic addition reaction between propene and H-Br? 2-bromopropane 3 - $300 What is the first & slowest step of any electrophilic addition reaction? What is the electrophile of this reaction? The formation of the carbocation The hydrogen (from either the H-X or from H-OH) 3 - $400 What are the major & minor products of the following reaction? 3 - $500 What is the major product of the following: 4 - $100 Hydrogenation reactions are catalyzed by metals that adsorb hydrogen to their surface. What is an example of a metal that would be suitable to catalyze this type of reaction? Pt, Rh, or Ni 4 - $200 What is the product for the hydrogenation reaction involving 1-butene & H2(g) using Pt to catalyze this reaction? butane 4 - $300 What are the three steps of all radical reactions? Describe each. Step 1 – initiation – creation of radicals Step 2 – propagation – use of a radical to create product, but resulting in formation of another radical Step 3 – termination – two radicals combine to make product, removing radicals from reaction vessel 4 - $400 What type of bond breakage results on the formation of radicals? Homolytic fission or homolytic cleavage 4 - $500 What are the products of the following halogenation reaction? 5 - $100 What is produced when any alkene undergoes the acid-catalyzed addition reaction with water? An alcohol 5 - $200 What is the major product for the acid catalyzed hydration of 2-methylbut-2-ene? 2-methylbutan-2-ol 5 - $300 What is the major product of the following reaction? 5 - $400 What reagent is used if an anti-Markovnikov product is desired? H2O2 5 - $500 Identify the products of the following reaction: Final Jeopardy Show the mechanism used to explain the formation of 2-methyl-2-bromopentane from the electrophilic addition reaction between 2methylpent-2-ene and HBr. Make certain to include the rate determining step and use arrows correctly. See notes or see answer in class.