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Types of Organic Reactions Unit: Organic Chemistry Addition: In an addition reaction, two molecules are added together to make one larger molecule. There are always two reactants and one product. This type of reaction usually involves unsaturated molecules. The multiple bond is lost, and the other molecule adds to either side of the multiple bond. In general, this is what occurs: The molecule A-B can represent many different reactants Reactant Name of Process Product (Alkene +) Hydrogen Hydrogenation Alkane (Alkyne +) Hydrogen Hydrogenation Alkene (limited amounts of hydrogen) Or Alkane (excess of hydrogen) Water Hydration Alcohol HF, HCl, HI, HBr Hydrohalogenation Halogenatated alkane Halogen Halogenation Double Halogenated alkane Condensation (also called Elimination) In a condensation reaction, two organic molecules react together to produce one larger organic molecule and a molecule of water. For this type of reaction to occur, one of the molecules must have a hydroxyl group, and the other must have an active site with hydrogens, such as another hydroxyl group, or an amino group. An example of each of these is below. This reaction involves two compounds with hydroxyl groups (two alcohols or an alcohol and a carboxylic acid). It produces an ether or an ester. A condensation reaction between an alcohol and a carboxylic acid, producing an ester is called an ESTERIFICATION reation. This reaction starts with an alcohol and an primary amine, and produces a secondary amine. 1 Types of Organic Reactions Unit: Organic Chemistry Hydrolysis A hydrolysis reaction is the opposite of a condensation reaction. For this reaction, a large organic molecule is reacted with water to produce two smaller organic molecules. For example: Substitution: A substitution reaction occurs when one atom is removed and replaced with another atom. This is not a very common type of organic reaction, but is the only way to add a halogen to an alkane. A catalyst, heat and/or pressure are required to have this reaction proceed. Oxidation An oxidation reaction in organic chemistry occurs when oxygen is added or hydrogens are removed from a compound. An oxidizing agent (a chemical that causes oxidation) must be added. Examples of oxidizing agents are potassium permanganate (KMnO4), sulphuric acid or potassium dichromate (K2Cr2O7). Removal of Hydrogens Addition of Oxygen 2