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SCH3U 1. Review for Periodic Table and Reactions October 5, 2010 An unknown gas was burned in oxygen to produce nitrogen gas and water vapour. Was the unknown gas an element? Explain. 2. Classify each of the following as a physical or chemical change. Briefly justify your answer. a) b) c) d) e) f) g) fermenting of grapes formation of snowflakes burning of gasoline compressing of garbage baking bread carving wood frying an egg h) i) j) k) l) m) rusting of iron a tree growing a candle giving off light digestion of food ice melting on a hot stove souring of milk 3. When a copper wire is heated in the presence of oxygen, a black substance is formed. Is the black substance likely to be an element, a mixture or a compound? Explain. 4. For an ion of sulfur-32 that has a charge of 2-, state the following: a) the atomic number b) the mass number d) the number of neutrons c) the number of protons e) the number of electrons 5. Suppose that you were presented with a sample of the element strontium (atomic number 38). a) Predict three physical properties that would be demonstrated by strontium. b) Compare the chemical reactivity of strontrium and barium. Justify your answer with specific reference to atomic theory. 6. Select the answer to each question from the following key: i) neutron ii) proton iii) atom iv) electron v) molecule a) The one with the smallest mass b) A particle which helped explain discrepancies in atomic mass and led to the discovery of isotopes c) The smallest part of an atom SCH3U Review for Periodic Table and Reactions October 5, 2010 7. Draw a Bohr diagram showing all the particles in each of the following atoms: a) 23 b) Na 11 20 c) O 8 9 9 Be 8. Complete the following chart: Element 170 Atomic Number Mass Number Number of Protons Number of Electrons Number of Neutrons Hf 72 85 Kr 36 38 19 K 9. The oxygen atom contains valence electrons. 10. The calcium atom is found is what family? 11. The atomic number for phosphorus is 12. The zinc atom has . protons. 13. Fill in the missing items in the following chart: Complete Isotope Symbol 39 Mass Number Atomic Number K+1 ion 19 Si atom 28 Kr atom 84 14 36 Total number of neutrons Number of electrons in the outermost energy level SCH3U Review for Periodic Table and Reactions October 5, 2010 14. Complete the following chart Symbol 73 Atomic Number Mass Number Number of Protons Number of Neutrons Number of Electrons Ge 32 125 51 37 28 52 31 15. Use the periodic table to identify each of the following: a) an element which has 5 electrons in each atom b) an element which has 5 electrons in its outer energy level c) an element for which the second energy level is completely filled d) an element which forms ions by gaining only one electron e) how many elements are there in the sixth period? f) the element which has the most metallic properties Multiple Choice Answer the following questions by circling the correct response on the answer sheet provided. (1 mark each) 16. The subatomic particle that has the smallest mass is the a.electron b.proton c. neutron d.nucleus 17. The atomic mass of barium is due to the number of a. neutrons and electrons in the nucleus b. electrons in the nucleus c. protons and neutrons in the nucleus d. protons and electrons in the atom 18. Choose the pair of elements that will form a compound with the most ionic character a. Li & O b. C & O c. F & F d. Cl & Br 19. In the alkali metals group, as the atomic number increases a. the electronegativity increases b. the electronegativity decreases c. the atomic radius decreases d. the electron affinity increases 20. In a neutral atom a. the number of protons is always equal to the number of neutrons b. the number of neutrons is always equal to the number of electrons c. the number of protons is always equal to the number of electrons d. the atomic number is always equal to the number of neutrons 21. Consider the equation X(g) + energy = X+ + e–. The "energy" represents a. electron affinity b. heat of sublimation c. ionization energy d. sublimation energy SCH3U Review for Periodic Table and Reactions October 5, 2010 22. Electron affinity increases as you go from left to right on the periodic table because a. atomic radius decreases b. ionization energy decreases c. of the periodic law d. all of the above 23. When fluorine forms an ionic bond it tends to a. lose electrons b. gain electrons c. share electrons d. lose protons 24. Copper (II) hydroxide is composed of a. 2 elements, 2 atoms b. 2 elements, 3 atoms c. 3 elements, 4 atoms d. 3 elements, 5 atoms 25. The IUPAC name for NO2 is a.nitrite b.nitrate c.dinitrogen oxide 26. The IUPAC name for P2I4 is a .phosphorus iodide c. tetraphosphorus diiodide b. d. d.nitrogen dioxide diphosphorus tetraiodide phosphorus pentaiodide 27. Which of the following formulas does NOT represent a molecular compound? a. CO(g) b. Co(s) c. CO2(g) d. CH4(g) 28. Which of these will experience dipole-dipole interactions? a. CH4, methane b. carbon monoxide c. oxygen gas d. silver nitrate 29. The name of HBrO3 (s) is a. bromic acid b. hydrogen perbromate d. hydrogen bromate c. bromous acid 30. Which of the following will form a formula unit? a. C and F b. C and O c. K and F d. K and Na 31. A compound composed of sodium, sulfur, and oxygen would be named a. sodium peroxide b.sulfuric acid c.sodium sulfide d.sodium sulfate 32. A metallic element X forms a carbonate with the formula X(CO3)2. The corresponding fluoride compound of element X would have the formula a. XF4 b. XF2 c. X4F2 d. X4F 33. The reaction of silver nitrate with zinc would be classified as a a. combustion reaction b.synthesis reaction c. double displacement reaction d.single displacement reaction 34. When baking soda is heated, sodium carbonate, water, and carbon dioxide gas are formed. This reaction can be classified as a.synthesis b.combustion c.decomposition d.single displacement 35. Which of the following always indicates that a chemical reaction has taken place? a. production of a gas b. absorption of heat c. change in colour d. appearance of a new substance 36. a. b. c. d. Which metal would not displace lead, Pb, in a lead nitrate, Pb(NO3)2, solution? copper, Cu potassium, K lithium, Li magnesium, Mg True and False. SCH3U Review for Periodic Table and Reactions October 5, 2010 37. ___ The radius of an ion is always larger than the atomic radius of the original atom. 38. ___Most of the metals found above hydrogen in the activity series are found as elements in the ground. 39. __ Gold is a highly reactive metal. 40. ___ Barium hydroxide produced in a double displacement reaction will precipitate out. 41. ___ Hydrogen is in the activity series because it classifies as a metal. 42. Draw the following Lewis symbols/Lewis structures (2 marks each) a) oxygen atom b) chloride ion c) hydrogen gas d) carbon tetrafluoride e) calcium chloride f) sodium hydroxide 43. Predict the products and write a balanced chemical equation for the following chemical reactions: a) Copper wire is added to an aqueous solution of silver nitrate. (3 marks) b) Potassium metal is added to water. (3 marks) c) Butane, C4H10 (g), reacts with atmospheric oxygen. (4 marks) 44. Write the complete chemical, total and net ionic equations for a double displacement reaction between calcium chloride and sodium phosphate. (8 marks) SCH3U Review for Periodic Table and Reactions October 5, 2010 45. Beakers A and B are filled with substances that are liquid at room temperature. The substance in beaker A experiences London dispersion forces. The substance in beaker B experience dipole-dipole interactions. Compare and contrast the two force types. Which substance will boil at a lower temperature and why? (5 marks) 46. For a science fair project, a student wants to design a simple device for removing certain gases from polluted air. He knows that polar molecules dissolve well in water, so he bubbles polluted air through a jug of water to remove unwanted gases. For his project, the student uses air containing the following gases: 1. N2(g) 2. O2(g) 3. HF(g) 4. NH3(g) 5. 6. 7. 8. CH4(g) OCl2(g) C3H8(g) CH3OCH3(g) Which gases will dissolve? (4 marks) 47. Explain how first ionization energy is related to atomic radius. (3 marks) 48. Describe what are polar covalent bonds. (3 marks)