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研 究 業 ‒ 査 績 読 リ 論 ス ト 文‒ (1) The First Example of Asymmetric Selenoxide Elimination: Application to the Synthesis of Chiral Allenes N. Komatsu, Y. Nishibayashi, T. Sugita, S. Uemura J. Chem. Soc., Chem. Commun., 46-47 (1992). (2) Catalytic Asymmetric Oxidation of Sulfides to Sulfoxides Using R-(+)Binaphthol N. Komatsu, Y. Nishibayashi, T. Sugita, S. Uemura Tetrahedron Lett., 33, 5391-5394 (1992). (3) Asymmetric [2,3]Sigmatropic Rearrangement via Chiral Selenoxide with Sharpless Oxidants N. Komatsu, Y. Nishibayashi, S. Uemura Tetrahedron Lett., 34, 2339-2342 (1993). (4) Telluroxide Elimination by Oxidation of Alkyl Aryl Tellurides: Remarkable Effect of Added Triethylamine Y. Nishibayashi, N. Komatsu, K. Ohe, S. Uemura J. Chem. Soc., Perkin Trans. 1, 1133-1138 (1993). (5) Asymmetric Selenoxide Elimination Leading to Chiral Allenic Sulfones N. Komatsu, T. Murakami, Y. Nishibayashi, T. Sugita, S. Uemura J. Org. Chem., 58, 3697-3702 (1993). (6) Dinuclear (η5-C5Me5)Ru Complexes Triply Bridged by Tellurium or Selenium Ligands - Syntheses and Characterisation of (η5-C5Me5)Ru(µ2-RTeTeR)(µ2TeR)2Ru(η5-C5Me5) and [(η5-C5Me5)Ru(µ2-SeR)3Ru(η5-C5Me5)]Cl (R = Tol, Ph) H. Matsuzaka, T. Ogino, M. Nishio, M. Hidai, Y. Nishibayashi, S. Uemura J. Chem. Soc., Chem. Commun., 223-224 (1994). (7) Synthesis of Chiral Diferrocenyl Diselenides and Their Application to Asymmetric Reactions Y. Nishibayashi, J. D. Singh, S. Uemura, S. Fukuzawa Tetrahedron Lett., 35, 3115-3118 (1994). (8) Syntheses and Reactivities of Ferrocenyl Organyl Tellurides Y. Nishibayashi, T. Chiba, J. D. Singh, S. Uemura, S. Fukuzawa J. Organomet. Chem., 473, 205-213 (1994). 1 (9) Rhodium(I)-catalysed Asymmetric Hydrosilylation of Ketones using New Diferrocenyl Dichalcogenides (R,S)-{[EC5H3CHMe(NMe2)]Fe(C5H5)}2 (E=S, Se, Te) as Chiral Ligands Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, S. Uemura J. Chem. Soc., Chem. Commun., 1375-1376 (1994). (10) Asymmetric Synthesis and Highly Diastereoselective ortho-Lithiation of Oxazolinylferrocenes Y. Nishibayashi, S. Uemura Synlett, 79-81 (1995). (11) Stereo- and Chemo-Selectivity in Reduction of α-[Phenyl(or Methyl)seleno]alkyl Aryl Ketones with Metal Hydrides I. Aoki, Y. Nishibayashi, S. Uemura Bull. Chem. Soc. Jpn., 68, 337-340 (1995). (12) The First Example of Chirality Transfer in Allylic Telluroxides – Possible [2,3]Sigmatropic Rearrangement T. Chiba, Y. Nishibayashi, J. D. Singh, K. Ohe, S. Uemura Tetrahedron Lett., 36, 1519-1522 (1995). (13) Synthesis of [R,S;R,S]- and [S,R;S,R]-Bis[2-[1-(dimethylamino)ethyl]ferrocenyl] Diselenides and Their Application to Asymmetric Selenoxide Elimination and [2,3]Sigmatropic Rearrangement Y. Nishibayashi, J. D. Singh, S. Fukuzawa, S. Uemura J. Org. Chem., 60, 4114-4120 (1995). (14) High Chirality Transfer in Chiral Selenimides via [2,3]Sigmatropic Rearrangement Y. Nishibayashi, T. Chiba, K. Ohe, S. Uemura J. Chem. Soc., Chem. Commun., 1243-1244 (1995). (15) The First Example of Enantioselective Carbenoid Addition to Organochalcogen Atoms : Application to [2,3]Sigmatropic Rearrangement of Allylic Chalcogen Ylides Y. Nishibayashi, K. Ohe, S. Uemura J. Chem. Soc., Chem. Commun., 1245-1246 (1995). (16) Highly Selective Asymmetric Intramolecular Selenocyclisation Y. Nishibayashi, S. K. Srivastava, H. Takada, S. Fukuzawa, S. Uemura J. Chem. Soc., Chem. Commun., 2321-2322 (1995). 2 (17) Allylic Amine Formation by Imination of Allylic Tellurides Y. Nishibayashi, S. K. Srivastava, K. Ohe, S. Uemura Tetrahedron Lett., 36, 6725-6728 (1995). (18) Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand for the Asymmetric Hydrosilylation of Ketones Y. Nishibayashi, K. Segawa, K. Ohe, S. Uemura Organometallics, 14, 5486-5487 (1995). (19) Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application to Asymmetric Nucleophilic Ring-Opening of meso-Epoxides Y. Nishibayashi, J. D. Singh, S. Fukuzawa, S. Uemura J. Chem. Soc., Perkin Trans. 1, 2871-2876 (1995). (20) Palladium-catalyzed Cross-coupling Reactions between Organic Tellurides and Alkenes Y. Nishibayashi, C. S. Cho, S. Uemura J. Organomet. Chem., 507, 197-200 (1996). (21) Novel Chiral Ligands, Diferrocenyl Dichalcogenides and Their Derivatives, for the Rh(I)- and Ir(I)-Catalyzed Asymmetric Hydrosilylation Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, K. Ohe, S. Uemura Organometallics, 15, 370-379 (1996). (22) Enantioselective ortho-Lithiation of Substituted Ferrocenes Y. Nishibayashi, Y. Arikawa, K. Ohe, S. Uemura J. Org. Chem., 61, 1172-1174 (1996). (23) Iridium(I)-Catalysed Asymmetric Hydrosilylation of Ketones using Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand Y. Nishibayashi, K. Segawa, H. Takada, K. Ohe, S. Uemura Chem. Commun., 847-848 (1996). (24) Novel Asymmetric Catalytic Synthesis of Sulfimides H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura Chem. Commun., 931-932 (1996). 3 (25) Oxidative Addition of Diferrocenyl Dichalcogenides to [(η5-C5Me5)Ru(µ3Cl)]4. Syntheses, Crystal Structures and Some Reactivities of Ferrocenylchalcogenolate-Bridged Diruthenium Complexes [(η5C5Me5)RuCl(µ2-EFc)]2 (E=S, Se, Te; Fc=ferrocenyl) H. Matsuzaka, J.-P. Qü, T. Ogino, M. Nishio, Y. Nishibayashi, Y. Ishii, S. Uemura, M. Hidai J. Chem. Soc., Dalton Trans., 4307-4312 (1996). (26) Palladium-catalyzed Homocoupling Reactions of Organic Tellurides Y. Nishibayashi, C. S. Cho, K. Ohe, S. Uemura J. Organomet. Chem., 526, 335-339 (1996). (27) Rhodium(I)-, Iridium(I)-, and Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones using Diferrocenyl Dichalcogenides as Chiral Ligands Y. Nishibayashi, J. D. Singh, Y. Arikawa, S. Uemura, M. Hidai J. Organomet. Chem., 531, 13-18 (1997). (28) Allylation of Arenes Catalysed by Thiolate-Bridged Diruthenium Complexes Y. Nishibayashi, M. Yamanashi, Y. Takagi, M. Hidai Chem. Commun., 859-860 (1997). (29) Synthesis, Structures and Reactivities of Rhodium and Ruthenium Complexes with Novel Chiral Cyclopentadienyl-ferrocenyldiphenylphosphine Bidentate Ligand Y. Nishibayashi, I. Takei, M. Hidai Organometallics, 16, 3091-3093 (1997). (30) Synthesis and Structure of Novel Chiral Oxazolinylferrocenes Oxazolinylferrocenylphosphines, and Their Rhodium(I)-Complexes Y. Nishibayashi, K. Segawa, Y. Arikawa, K. Ohe, M. Hidai, S. Uemura J. Organomet. Chem., 545 & 546, 381-398 (1997). and (31) Catalytic Asymmetric Sulfimidation H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura, C. P. Baird, T. J. Sparey, P. C. Taylor J. Org. Chem., 62, 6512-6518 (1997). (32) Bimetallic System for Nitrogen Fixation: Ruthenium-assisted Protonation of Coordinated N2 on Tungsten with H2 Y. Nishibayashi, S. Iwai, M. Hidai Science, 279, 540-542 (1998). 4 (33) A Model for Protonation of Dinitrogen by Nitrogenase: Protonation of Coordinated Dinitrogen on Tungsten with Hydrosulfido-Bridged Dinuclear Complexes Y. Nishibayashi, S. Iwai, M. Hidai J. Am. Chem. Soc., 120, 10559-10560 (1998). (34) Ruthenium-catalyzed Asymmetric Hydrosilylation of Ketones and Imine Y. Nishibayashi, I. Takei, S. Uemura, M. Hidai Organometallics, 17, 3420-3422 (1998). (35) Synthesis of Heterobimetallic Fe-M (M=Ni, Pd, Pt) Complexes Containing 1,1'Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes S. Takemoto, S. Kuwata, Y. Nishibayashi, M. Hidai Inorg. Chem., 37, 6428-6434 (1998). (36) Ruthenium(II)-catalyzed Asymmetric Transfer Hydrogenation of Ketones using Chiral Oxazolinylferrocenylphosphines and its Ru(II) Complex Y. Arikawa, M. Ueoka, K. Matoba, Y. Nishibayashi, M. Hidai, S. Uemura J. Organomet. Chem., 572, 163-168 (1999). (37) The Use of Chiral Diferrocenyl Diselenides for Highly Selective Asymmetric Intramolecular Selenocyclization H. Takada, Y. Nishibayashi, S. Uemura J. Chem. Soc., Perkin Trans. 1, 1511-1516 (1999). (38) Iridium-Catalyzed Asymmetric Hydrosilylation of Imines by Chiral OxazolinylPhosphine Ligands I. Takei, Y. Nishibayashi, Y. Arikawa, S. Uemura, M. Hidai Organometallics, 18, 2271-2274 (1999). (39) Extremely High-Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl2(PPh3)(oxazolinylferrocenylphosphine) Y. Nishibayashi, I. Takei, S. Uemura, M. Hidai Organometallics, 18, 2291-2293 (1999). (40) Novel Catalytic Hydrogenolysis of Trimethylsilyl Enol Ethers by the Use of an Acidic Ruthenium Dihydrogen Complex Y. Nishibayashi, I. Takei, M. Hidai Angew. Chem., Int. Ed. Engl., 38, 3047-3050 (1999). 5 (41) Cyclization of Terminal Diynes Catalyzed by Thiolate-bridged Diruthenium Complexes: A Simple Synthetic Route to Endo-Macrocyclic (Z)-1-En-3-ynes Y. Nishibayashi, M. Yamanashi, I. Wakiji, M. Hidai Angew. Chem., Int. Ed. Engl., 39, 2909-2911 (2000). (42) Synthesis and Structures of 1,1'-Ferrocenedithiolato-Bridged Di- and Trinuclear Ruthenium Complexes S. Takemoto, S. Kuwata, Y. Nishibayashi, M. Hidai Organometallics, 19, 3249-3252 (2000). (43) Formation of Ammonia in the Reactions of a Tungsten Dinitrogen with Ruthenium Dihydrogen Complexes under Mild Reaction Conditions 6 (49) Asymmetric Synthesis of Epoxides from Aromatic Aldehydes and Benzyl Halides Catalyzed by C2 Symmetric Optically Active Sulfides Having Binaphthyl Skeleton Y. Miyake, A. Oyamada, Y. Nishibayashi, S. Uemura Heteroatom Chemistry, 13, 270–275 (2002). (50) Ruthenium-Catalyzed Cycloaddition of Propargylic Alcohols with Phenol Derivatives via Allenylidene Intermediates: Catalytic Use of the Allenylidene Ligand as C3 Unit Y. Nishibayashi, Y. Inada, M. Hidai, S. Uemura J. Am. Chem. Soc., 124, 7900–7901 (2002). (51) Palladium(II) Complex-Catalysed Enantioselective Benzolylation of Alcohols Using Carbon Monoxide and Organobismuth(V) Compound T. Iwata, Y. Miyake, Y. Nishibayashi, S. Uemura J. Chem. Soc., Perkin Trans. 1, 1548-1554 (2002). (52) Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, S. Uemura J. Am. Chem. Soc., 124, 11846–11847 (2002). (53) Asymmetric Baeyer-Villiger Oxidation of Cyclic Ketones Using Chiral Organoselenium Catalysts Y. Miyake, Y. Nishibayashi, S. Uemura Bull. Chem. Soc. Jpn., 75, 2233–2237 (2002). (54) Ruthenium-Catalyzed Propargylic Substitution Reaction of Propargylic Alcohols with Thiols: A General Synthetic Route to Propargylic Sulfides Y. Inada, Y. Nishibayashi, M. Hidai, S. Uemura J. Am. Chem. Soc., 124, 15172–15173 (2002). (55) Kinetic Resolution of Racemic Ferrocenylphosphine Compounds by Enantioselective Oxidation Using Cyclic Selenoxides as Having a Chiral Ligand Y. Miyake, A. Yamauchi, Y. Nishibayashi, S. Uemura Bull. Chem. Soc. Jpn., 76, 381–387 (2003). (56) Synthesis of Diruthenium Complexes Containing Chiral Thiolate-bridged Ligands and Their Application to Catalytic Propargylic Alkylation of Propargylic Alcohols with Acetone Y. Nishibayashi, G. Onodera, Y. Inada, M. Hidai, S. Uemura Organometallics, 22, 873–876 (2003). 7 (57) Propargylation of Aromatic Compounds with Propargylic Alcohols Catalyzed by Cationic Diruthenium Complex Y. Nishibayashi, Y. Inada, M. Yoshikawa, M. Hidai, S. Uemura Angew. Chem., Int. Ed., 42, 1495–1498 (2003). (58) Ruthenium-Catalyzed Carbon–Carbon Bond Formation between Propargylic Alcohols and Alkenes via the Allenylidene –Ene Reaction Y. Nishibayashi, Y. Inada, M. Hidai, S. Uemura J. Am. Chem. Soc., 125, 6060–6061 (2003). (59) Novel Ruthenium- and Platinum-Catalyzed Sequential Reactions: Synthesis of Tri- and Tetra-Substituted Furans and Pyrroles from Propargylic Alcohols and Ketones Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. D. Milton, M. Hidai, S. Uemura Angew. Chem., Int. Ed., 42, 2681–2684 (2003). (60) Oxidative Kinetic Resolution of Racemic Alcohols Catalyzed by Chiral Ferrocenyloxazolinylphosphine–Ruthenium Complexes Y. Nishibayashi, A. Yamauchi, G. Onodera, S. Uemura J. Org. Chem., 68, 5875 (2003). (61) Novel Catalytic Hydrogenolysis of Silyl Enol Ethers by the Use of Acidic Ruthenium Dihydrogen Complexes I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura, M. Hidai J. Organomet. Chem., 679, 32–42 (2003). (62) Preparation of a Series of Chalcogenolate-Bridged Diruthenium Complexes and their Catalytic Activities toward the Propargylic Substitution Reactions Y. Nishibayashi, H. Imajima, G. Onodera, M. Hidai, S. Uemura Organometallics, 23, 26–30 (2004). (63) Ruthenium-Catalyzed Cycloaddition between Propargylic Alcohols and Cyclic 1,3-Dicarbonyl Compounds via Allenylidene Intermediates Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, S. Uemura J. Org. Chem., 69, 3408–3412 (2004). (64) Synthesis of Dinuclear Complexes Bearing Metalloporphyrin-Phosphine Hybrid Ligand and Their Catalytic Activity toward Hydrosilylation of Ketones M. Saito, Y. Nishibayashi, S. Uemura Organometallics, 23, 4012–4017 (2004). 8 (65) A Non-metal System for Nitrogen Fixation Y. Nishibayashi, M. Saito, S. Uemura, S. Takekuma, H. Takekuma, Z. Yoshida Nature, 428, 279-280 (2004). (66) Stereospecific Carbon–Carbon Bond Formation by the Reaction of a Chiral Episelenonium Ion with Aromatic Compounds K. Okamoto, Y. Nishibayashi, S. Uemura, A. Toshimitsu Tetrahedron Lett., 45, 6137–6139 (2004). (67) Preparation of Alkanechalcogenolate- and Benzenechalcogenolate-Bridged Diruthenium Complexes and Their Catalytic Activities toward Propargylation of Acetone with Propargylic Alcohols Y. Nishibayashi, H. Imajima, G. Onodera, Y. Inada, M. Hidai, S. Uemura Organometallics, 23, 5100–5103 (2004). (68) Ruthenium- and Gold-Catalysed Sequential Reactions: a Straightforward Synthesis of Substituted Oxazoles from Propargylic Alcohols and Amides M. D. Milton, Y. Inada, Y. Nishibayashi, S. Uemura Chem. Commun., 2712–2713 (2004). (69) Double Phosphinylation of Propargylic Alcohols: a Novel Synthetic Route to 1,2-Bis(diphenylphosphino)ethane Derivatives M. D. Milton, G. Onodera, Y. Nishibayashi, S. Uemura Org. Lett., 6, 3993–3995 (2004). (70) Ruthenium-Catalyzed Allylation of Aromatic Compounds and Allylic Ether Formation G. Onodera, H. Imajima, M. Yamanashi, Y. Nishibayashi, M. Hidai, and S. Uemura Organometallics, 23, 5841–5848 (2004). (71) Ruthenium-Catalyzed Propargylic Substitution Reactions of Propargylic Alcohols with Oxygen-, Nitrogen-, and Phosphorus-Centered Nucleophiles Y. Nishibayashi, M. D. Milton, Y. Inada, M. Yoshikawa, I. Wakiji, M. Hidai, and S. Uemura Chemistry-A European Journal, 11, 1433–1451 (2005). (72) Ruthenium- and Platinum-Catalyzed Sequential Reactions: Selective Synthesis of Fused Polycyclic Compounds from Propargylic Alcohols and Alkenes Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, and S. Uemura J. Am. Chem. Soc., 126, 16066–16072 (2004). 9 (73) Synergistic Dimetallic Effects in Propargylic Substitution Reaction Catalyzed by Thiolate-bridged Diruthenium Complex S. C. Ammal, N. Yoshikai, Y. Inada, Y. Nishibayashi, and E. Nakamura J. Am. Chem. Soc., 127, 9428-9438 (2005). (74) Asymmetric Carboselenenylation Reaction of Alkenes with Aromatic Compounds K. Okamoto, Y. Nishibayashi, S. Uemura, and A. Toshimitsu Angew. Chem., Int. Ed., 44, 3588-3591 (2005). (75) A Novel Method for the Preparation of Enantiomerically Pure Propargylic Substituted Compounds Y. Nishibayashi, H. Imajima, G. Onodera, and S. Uemura Organometallics, 24, 4106-4109 (2005). (76) Ruthenium-Catalyzed Reductive Coupling Reaction of Propargylic Alcohols via Hydroboration of Allenylidene Intermediates G. Onodera, Y. Nishibayashi, and S. Uemura Organometallics, 25, 35-37 (2006). (77) Ruthenium-Catalyzed Asymmetric Propargylic Substitution Reaction of Propargylic Alcohols with Acetone Y. Inada, Y. Nishibayashi, and S. Uemura Angew. Chem., Int. Ed., 44, 7715-7717 (2005). (78) Ruthenium-Catalyzed Formation of Aryl(diphenyl)phosphine Oxides by Reactions of Propargylic Alcohols with Diphenylphosphine Oxide G. Onodera, H. Matsumoto, M. D. Milton, Y. Nishibayashi, and S. Uemura Org. Lett., 7, 4029-4032 (2005). (79) Preparation of Dicationic Chalcogenolate-Bridged Diruthenium Complexes and Their Dual Catalytic Activity toward Reactions between Propargylic Alcohols and Acetone G. Onodera, H. Matsumoto, Y. Nishibayashi, and S. Uemura Organometallics, 24, 5799-5801 (2005). (80) Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols Y. Inada, M. Yoshikawa, M. D. Milton, Y. Nishibayashi, and S. Uemura Eur. J. Org. Chem., 881-890 (2006). 10 (81) Iridum- and Ruthenium-Catalyzed Sequential Reactions: Asymmetric αAlkylative Reduction of Ketones with Alcohols G. Onodera, Y. Nishibayashi, and S. Uemura Angew. Chem. Int. Ed., 45, 3819-3822 (2006). (82) Ruthenium-Catalyzed Propargylic Reduction of Propargylic Alcohols with Silanes Y. Nishibayashi, A. Shinoda, Y. Miyake, H. Matsuzawa, and M. Sato Angew. Chem. Int. Ed., 45, 4835-4839 (2006). (83) Ruthenium-Catalyzed Sequential Reactions: Deracemization of Secondary Benzylic Alcohols Y. Shimada, Y. Miyake, H. Matsuzawa, and Y. Nishibayashi Chemistry–An Asian Journal, 2, 393-396 (2007). (84) Ruthenium-Catalyzed Reactions of 1-Cyclopropyl-2-propyn-1-ols with Anilines and Water via Allenylidene Intermediates: Preparation of Tri- and Tetrasubstituted Conjugated Enynes Y. Yamauchi, G. Onodera, K. Sakata, M. Yuki, Y. Miyake, S. Uemura, and Y. Nishibayashi J. Am. Chem. Soc., 129, 5175-5179 (2007). (85) Synthesis and Reactivity of Diphosphine-Bridged Diruthenium Complexes Y. Miyake, Y. Nomaguchi, M. Yuki, and Y. Nishibayashi Organometallics, 26, 3611-3613 (2007). (86) Ruthenium-Catalyzed Enantioselective Propargylation of Aromatic Compounds with Propargylic Alcohols via Allenylidene Intermediates H. Matsuzawa, Y. Miyake, and Y. Nishibayashi Angew. Chem. Int. Ed., 46, 6488-6491 (2007). (87) Design and Preparation of a Chiral Ligand Based on a Pseudorotaxane Skeleton: Application to Rhodium-Catalyzed Enantioselective Hydrogenation of Enamides G. Hattori, T. Hori, Y. Miyake, and Y. Nishibayashi J. Am. Chem. Soc., 129, 12930-12931 (2007). (88) Remarkable Effect of N-Substituent on Enantioselective Ruthenium-Catalyzed Propargylation of Indoles with Propargylic Alcohols H. Matsuzawa, K. Kanao, Y. Miyake, and Y. Nishibayashi Org. Lett., 9, 5561-5564 (2007). 11 (89) Ruthenium-Catalyzed Vinylic Substitution Reactions with Nucleophiles via Butatrienylidene Intermediates Y. Yamauchi, M. Yuki, Y. Tanabe, Y. Miyake, Y. Inada, S. Uemura, and Y. Nishibayashi J. Am. Chem. Soc., 130, 2908-2909 (2008). (90) Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines: A Novel Synthetic Approach to Chiral Propargylic Amines G. Hattori, H. Matsuzawa, Y. Miyake, and Y. Nishibayashi Angew. Chem. Int. Ed., 47, in press (2008). (91) Ruthenium-Catalyzed Dienyne Formation from Propargylic Alcohols and 1,3Conjugated Dienes M. Daini, M. Yoshikawa, Y. Inada, S. Uemura, K. Sakata, K. Kanao, Y. Miyake, and Y. Nishibayashi Organometallics, 27, in press (2008). (92) Ruthenium-Catalyzed Intramolecular Cyclization of 3-Butyne-1,2-diols into Furans Y. Yada, Y. Miyake, and Y. Nishibayashi Org. Lett., to be submitted. (93) Novel Monophosphido-Bridged Diruthenium Complexes: Efficient Preparative Method and Their Catalytic Activity toward Condensation of Aldehydes with Indoles Y. Miyake, S. Endo, Y. Nomaguchi, M. Yuki, and Y. Nishibayashi To be submitted. (94) Ruthenium-Catalyzed Enantioselective Carbon-Carbon Bond Formation via Allenylidene-Ene Reaction: Synthetic Approach to Chiral Choromane Derivatives K. Fukamizu, Y. Miyake, and Y. Nishibayashi To be submitted. (95) A DFT study on the Reaction Pathways for Carbon-Carbon Bond Forming Reactions between Propargylic Alcohols and Alkenes or Ketones Catalyzed by Thiolate-Bridged Diruthenium Complexes K. Sakata, Y. Miyake, and Y. Nishibayashi To be submitted. (96) 12 (97) (98) (99) (100) (101) (102) (103) (104) 13 ‒ 総 説・解 説‒ (1) Novel Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application to Asymmetric Reactions Y. Nishibayashi, S. Uemura Rev. Heteroatom Chem., MYU, Tokyo, Vol. 14, 83-118 (1996). (2) Chiral Bis(oxazoline)-copper Catalyzed Enantioselective Imination of Sulfides H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura Phosphorus, Sulfur, and Silicon, 120 & 121, 363-364 (1997). (3) ジルコニウムに配位する窒素分子の新しい反応 西林仁昭 Organometallic News, 95-96 (1997). (4) Highly Selective Asymmetric Intramolecular Selenocyclization H. Takada, Y. Nishibayashi, S. K. Srivastava, K. Ohe, S. Uemura Phosphorus, Sulfur, and Silicon, 136–138, 629-632 (1998). (5) 夢の常温での空中窒素固定法の開発に向けて,− 窒素錯体と水素錯体と の反応によるアンモニア合成− 干鯛眞信,西林仁昭 化学と工業,51 1897-1899 (1998). (6) 分子状水素錯体を用いた新規な水素化反応の開発 干鯛眞信,西林仁昭 Organometallic News, 121-124 (1998). (7) 4級ホスホニウム塩のセレンディピティー的な効果 リールの活性化と触媒活性の向上− 西林仁昭 化学,53 (12) 63-64 (1998). (8) Sigmatropic Rearrangements of Organoselenium Compounds Y. Nishibayashi, S. Uemura Organoselenium Chemistry: A Practical Approach; Ed. T. G. Back, Oxford University Press, Oxford, 207-221 (1999). 14 − 不活性な塩化ア (9) Selenoxide Elimination and [2,3]Sigmatropic Rearrangement Y. Nishibayashi, S. Uemura Topics of Current Chemistry, 208: Organoselenium Chemistry, Modern Developments in Organic Synthesis; Ed. T. Wirth, Springer-Verlag, Berlin, 201233 (2000). (10) Selenium Compounds as Ligands and Catalysts Y. Nishibayashi, S. Uemura Topics of Current Chemistry, 208: Organoselenium Chemistry, Modern Developments in Organic Synthesis; Ed. T. Wirth, Springer-Verlag, Berlin, 235255 (2000). (11) 「化学のフロンティア2000」 21世紀を担う次世代の空中窒素固定法の開発 素と水素からのアンモニア合成− 西林仁昭 化学と工業,53, 131-135 (2000). − 温和な条件下での窒 (12) Heterolytic Cleavage of Dihydrogen by Ruthenium and Molybdenum Complexes to Protonate Coordinated Dinitrogen and Cleave Si–O Bond M. Hidai and Y. Nishibayashi Recent Advances in Hydrides Chemistry; Ed. R. Poli, Elsevier Science, 117-138 (2001). (13) Kinetic Resolution of Racemic Ferrocenylphosphine Compounds Using Optically Active Cyclic Selenoxides as Oxidants Y. Miyake, A. Yamauchi, Y. Nishibayashi, S. Uemura Phosphorus, Sulfur, and Silicon, 177, 2107–2108 (2002). (14) オレフィンメタセシスによる大環状高分子化合物の合成 西林仁昭 Organometallic News, 110 (2003). (15) 新規 N,P-不斉配位子(FOXAP)の開発と不斉合成反応への応用 西林仁昭,植村 榮 Organic Square, 11, 1-3 (2003). (16) カルコゲン元素架橋二核ルテニウム錯体を触媒とする有機合成反応 西林仁昭,植村 榮,干鯛眞信 Organic Square, 13, 1-3 (2004). 15 (17) 次世代の窒素固定法の開発に向けて:フラーレンを用いた窒素固定法の 開発 西林仁昭 触媒, 47, 233-238 (2005). (18) A Non-Metal System for Nitrogen Fixation Utilizing Buckminsterfullerene Y. Nishibayashi, S. Uemura, S. Takekuma, Z. Yoshida Biological Nitrogen Fixation, Sustainable Agriculture and the Environment; Eds. Y.-P. Wang, M. Lin, Z.-X. Tian, C. Elmerich, W. E. Newton, Springer, 3940 (2005). (19) Ruthenium-Catalyzed Novel Carbon-Carbon Bond Forming Reactions via Ruthenium-Allenylidene Complexes Y. Nishibayashi, S. Uemura Current Organic Chemistry, 10, 135-150 (2006). (20) C-C Bond Formation by Substitution Reaction: Substitution at Propargylic and Benzylic Positions Y. Nishibayashi, S. Uemura Comprehensive Organometallic Chemistry III; Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, Vol. 11; 123-150 (2007). (21) C-C Bond Formation by Substitution Reaction: Allylic Alkylation Y. Nishibayashi, S. Uemura Comprehensive Organometallic Chemistry III; Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, Vol. 11; 75-122 (2007). (22) 光学活性フェロセニルオキサゾリニルホスフィン(FOXAP)配位子の開発 と触媒的不斉合成反応への応用 西林仁昭,三宅由寛,植村 榮 有機合成化学協会誌, 65, 761-771 (2007). (23) 二核ルテニウム錯体の特性を用いた新規触媒反応の開発̶ セレンディピ ティー的発見から阿吽の呼吸による協奏作用まで 西林仁昭 化学と工業, 60, 1088-1091 (2007). (24) Allenylidene Complexes in Catalysis Y. Nishibayashi, S. Uemura Metal Vinylidenes and Allenylidenes in Catalysis; Eds. P. H. Dixneuf and C. Bruneau, WILEY-VCH, in press (2008). 16 (25) Development of Optically Active Chiral Ligands Ferrocenyloxazolinylphosphines (FOXAPs) and Their Application to Catalytic Asymmetric Reactions Y. Miyake, Y. Nishibayashi, and S. Uemura Synlett, in press (2008). (26) (27) (28) (21) (22) (23) (24) 17