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Polymer Synthesis by In Vitro Enzyme Catalysis
Polymer Synthesis by In Vitro Enzyme Catalysis

... yl-R-ethyl-β-propiolactone) (17),12 and poly(lactic acid).13,14 Often, the synthetic methods used to prepare enantioenriched monomers either are tedious (requiring multistep reactions) or do not provide the monomer in sufficient enantiopurity. Attempts at carrying out stereoelective polymerizations ...
Organic synthesis and methodology related to the malaria drug artemisinin
Organic synthesis and methodology related to the malaria drug artemisinin

... described. Our attempts to access the artemisinin family of anti-malarials through the total synthesis of dihydro-epi-deoxyarteannuin B and dihydroartemisinic acid will be discussed fully. Key features of the syntheses will include alkylation of menthone derivatives using Noyori’s zincate enolate me ...
Lithium Bromide Original Commentary
Lithium Bromide Original Commentary

Aminoketone Rearrangements. 11. The Rearrangement of Phenyl a
Aminoketone Rearrangements. 11. The Rearrangement of Phenyl a

Efficient and Convenient Procedure for Protection of Hydroxyl
Efficient and Convenient Procedure for Protection of Hydroxyl

... a Products were identified by comparison of their physical and spectral data with those of authentic samples; b isolated yields; c in the presence of of 2 mmol of PCC. ...
The integration of flow reactors into synthetic organic chemistry
The integration of flow reactors into synthetic organic chemistry

... conduct chemical synthesis has remained relatively unchanged for over two centuries.12 – 14 Remarkably, apparatus such as standard glass round bottom flasks, condensers, measuring cylinders, test tubes and Bunsen burners are all still commonly in use today despite them being invented over 160 years ...
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Chapter 4-5
Chapter 4-5

Synthesis and thermal decarbonylation of W(CO)5 complexes
Synthesis and thermal decarbonylation of W(CO)5 complexes

The catalytic function of a silica gel-immobilized Mn(II)
The catalytic function of a silica gel-immobilized Mn(II)

... DTA), UV–vis and FT-IR spectroscopy. This new material is demonstrated to be a very active catalyst in clean epoxidation reactions using a combined oxidant of aqueous hydrogen peroxide and actonitrile in the presence of aqueous sodium hydrogencarbonate. The effects of reaction parameters such as sol ...
Learning Guide for Chapter 23: Amines
Learning Guide for Chapter 23: Amines

... reduction of amides VIII. Reduction of other groups to form amines - p 12 IX. Reactivity of anilines - p 15 aromatic substutition, use of diazonium ions I. Introduction to amines Amines are considered to be organic derivatives of ammonia. They are classified as primary, secondary, or tertiary depend ...
Carbonyl Condensation Reactions
Carbonyl Condensation Reactions

... The aldol reaction is synthetically useful because it forms new carbon–carbon bonds, generating products with two functional groups. Moreover, the β-hydroxy carbonyl compounds formed in aldol reactions are readily transformed into a variety of other compounds. Figure 24.3 illustrates how the crossed ...
Visible light photooxidation of nitrate: the dawn of
Visible light photooxidation of nitrate: the dawn of

... an incomplete conversion, which can be rationalized by a nonregioselective addition of NO3 to both ends of the alkyne,§ in accordance with previous reports. The low conversion (and resulting low product yield) is likely due to the fact that NO3 leads to degradation of catalyst 1. This effect could ...
lecture 6 oxidative addition
lecture 6 oxidative addition

... product‐forming step in a catalytic reaction. • In the oxidative addition direction, we break the A−B bond and form an M−A and an M−B bond. • The oxidation state (OS), electron count (EC), and coordination number (CN) all increase by two units during the reaction. • It is the change in formal oxidat ...
Elimination Reactions - result in the formation of a new π
Elimination Reactions - result in the formation of a new π

... In an E2 reaction, a strong base removes a proton beta to the leaving group so long as there exists a conformation in which the proton is anti-periplanar to the leaving group. Where there are several such protons, several products are possible: ...
Alkenes
Alkenes

... If the groups attached to the C=C are different, we distinguish the two isomers by adding the prefix Z (from German word Zusammen) if the higher-priority groups are together in the same side or E (from German word Entgegen) if the higherpriority groups are opposite sides depending on the atomic numb ...
Process for preparing polycarbonates
Process for preparing polycarbonates

... may be unsuitable in an industrial spray metal cleaning operation or for use as an active ingredient in detergents and rinse aids for household mechanical dishwashers. ...
CHEM 494 Lecture 8 - UIC Department of Chemistry
CHEM 494 Lecture 8 - UIC Department of Chemistry

Chapter 19 Carboxylic Acid Derivatives Nucleophilic Acyl
Chapter 19 Carboxylic Acid Derivatives Nucleophilic Acyl

... For thioesters: Sulfur is a third row element, like chlorine, and so it is considerably larger than oxygen. The C-S bond is relatively long and this makes for poor overlap of the lone pair 3p orbital and the π-orbital of the carbonyl. But thioesters are less reactive than acid chlorides and anhydrid ...
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Chemical Reaction Equations
Chemical Reaction Equations

... Limiting and Excess Reagents When no further changes appear to be occurring, we assume that all of the AgNO3(aq) that was initially present has now been completely reacted. A limiting reagent is the reactant whose entities are completely consumed in a reaction, meaning the reaction stops. In order ...
Example 4
Example 4

... Form a bond between the H (from the alcohol) and the O-H (from the hemiacetal) to form H2O. Form a bond between the O (from the alcohol) and the alpha-carbon to form an ACETAL. ...
PHYSICOCHEMICAL PROPERTIES OF ORGANIC MEDICINAL
PHYSICOCHEMICAL PROPERTIES OF ORGANIC MEDICINAL

ch221 class 5
ch221 class 5

... The terms are important because, although within a family, functional groups at 1o, 2o and 3o carbon atoms will have a similar chemistry, it will not be exactly the same for each. For example, 1-propanol (1o) may be more or less reactive in certain reactions than 2-propanol (2o). Naming Alkanes Triv ...
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Asymmetric induction



Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis.Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist.Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.
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