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Ch. 21 Nuclear Chemistry The Nucleus Nucleons: Protons and neutrons. Nuclide: an atom, identified by the number of protons and neutrons in its nucleus. Nuclides can be written with the name or symbol, followed by a dash with the mass number: Chlorine-35 or Cl-35, or as follows: Atomic mass = 35 Atomic number = 17 Cl 21-2 The Nucleus Mass Defect: the difference between the mass of an atom and the sum of the masses of its protons, neutrons and electrons. Nuclear Binding Energy: the energy released when a nucleus is formed from nucleons. Nuclear Shell Model: nucleons exist in different energy levels, or shells, in the nucleus. 21-3 Radioactive Decay Nuclear Reaction: a reaction that changes the nucleus of an atom. Transmutation: a change in the identity of a nucleus as a result of a change in the number of its protons. Nuclear Particles Type Symbol Charge Alpha particle Beta particle Positron Neutron Gamma Ray 4 2He -1β 0 +1β 0 1 0n γ +2 -1 +1 0 0 Radioactive Decay 21-5 Radioactive Decay Radioactive Decay: the spontaneous disintegration of a nucleus into a slightly lighter nucleus, accompanied by emission of particles, electromagnetic radiation or both. Nuclear Radiation: particles or electromagnetic radiation emitted from the nucleus during radioactive decay. Radioactive Nuclide: an unstable nucleus that undergoes radioactive decay. 21-6 Radioactive Decay Alpha emission (α): two protons and two neutrons bound together, emitted during some types of radioactive decay. 21-7 Radioactive Decay Beta emission (β): an electron emitted from the nucleus during some types of radioactive decay. 21-8 Radioactive Decay Positron emission : a particle that has the same mass as an electron, but has a positive charge and is emitted during some types of radioactive decay. 21-9 Radioactive Decay Gamma Rays (γ): high energy electromagnetic waves emitted from a nucleus as it changes from an excited state to a ground state. Example: Balance the following reaction: 212 Po → 4 He + ________ 84 2 4 He + 208 Pb Po → 84 2 82 1) Balance the following reaction: 253 Es + 4 He → 1 n + ________ 99 2 0 212 4 He → 1 n + 256 Es + 99 2 0 101 Md 253 Radioactive Decay Half-Life : the time required for half the atoms of a radioactive nuclide to decay. 21-11 Radioactive Decay Decay Series: a series of radioactive nuclide produced by successive radioactive decay until a stable nuclide is reached. 21-15 Radioactive Decay Nuclear Fission: a very heavy nucleus splits into more stable nuclei of intermediate mass, starting a chain rxn. 21-13 Radioactive Decay Nuclear Fusion: low mass nuclei combine to form a heavier, more stable nucleus. 21-14 Ch. 21 The End!