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Question, hints, and answers. Look at hints if you need help. Look at answers if you just don’t know. Message me on face book for tutoring (Keshara Senanayake) 1. Based on intermolecular forces, which of these substances would have the highest boiling point? (1 point) *hint HYDROGEN BONDS = strong intermolecular force, stronger intermolecular force = higher boiling point a . b . H e C H 4 c . O 2 d . N H 3 2. A gas occupies a volume of 444 mL at 273 K and 79.0 kPa. What is the final kelvin temperature when the volume of the gas is changed to 1880 mL and the pressure is changed to 38.7 kPa? (1 point) *hint use combined gas law equation P1V1/T1 = P2V2/T2 a . b . c . d . 31. 5K 29 2K 56 6K 23 60 K 3. Which substance is correctly paired with its type of bonding? (1 point) *hint 0.4 - 1.7 polar covalent less then 0.4 is nonpolar. Beyond 2.0 is ionic. Also look at structure. NH3 has a unshared pair on top a . b . c . NaBr - nonpolar covalent HCl - nonpolar covalent Br2 - polar covalent d . NH3 - polar covalent 4. Which pair of formulas correctly represents a molecular formula and its corresponding empirical formula? (1 point) *hint look for proportional ratios a . b . c . d . C2H2 and CH C3H4 and CH2 C4H6 and CH C5H8 and C2H2 5. The nucleus of an atom of cobalt-58 contains (1 point) *hint look at periodic table and at atomic number/atomic mass. Atomic number is protons/electrons. Atomic mass is protons + neutrons.) a . 27 protons and 31 neutrons b . c . d . 27 protons and 32 neutrons 59 protons and 60 neutrons 60 protons and 60 neutrons 6. Which quantity of particles is correctly represented by the formula H2SO4? (1 point) *hint remember Avogadro, 1 (mole) of anything same # (Avogadro’s #) a . b . c . 1.0 mole of ions 1.0 mole of molecules 6.02 x 1023 ions d . 6.02 x 1023 atoms 7. One mole of O2 has approximately the same mass as one mole of (1 point) *hint (Oxygen is a diatomic, O2 is 32g) a . C H 4 b . c . d . S L i H C l 2 8. Which electron configuration represents the electrons of an atom in an excited state? (1 point) *hint the rule for filling up each energy level is 2n^2, so its 2-8-18 …, in excited state an electron moves up or down) a . 2-81 b . 8 c . d . 2-86 2-817-6 2-818-5 9. Which properties are most common in nonmetals? (1 point) *hint nonmetals tend to gain electrons more often and often you need a higher energy to remove an electron from it. Definition of electronegative and ionization energy. a . b . low ionization energy and low electronegativity low ionization energy and high electronegativity c . high ionization energy and low electronegativity d . high ionization energy and high electronegativity 10. What is the total number of electrons found in an atom of sulfur? (1 point) *hint look at atomic number a . 6 b . 8 c . 1 6 d . 3 2 11. Which ion has the largest radius? (1 point) *hint elements more to the left and down are bigger (atomic radius decreases to the right of a period or up a group) a . N a + b . K + c . M g 2 + d . C a 2 + 12. Pure silicon is chemically classified as a metalloid because silicon (1 point) *hint metalloid has both metal/nonmetal characteristics a . b . c . is malleable and ductile is an excellent conductor of heat and electricity exhibits hydrogen bonding d . exhibits metallic and nonmetallic properties 13. The forces between atoms that create chemical bonds are the result of interactions between (1 point) *hint think of an atom a . nuclei b . electrons c . protons and electrons d . protons and nuclei 14. Which molecule has an asymmetrical shape? (1 point) *hint visualize the lewis dot structure of each of these. Which of these are NOT symmetrical. Which has unshared electrons a . N 2 b . C l 2 c . N H 3 d . C C l 4 15. What happens when NaCl(s) is dissolved in water? (1 point) *hint oxygen (-) (oxygen anion) likes Na (+) (cation) a . b . c . d . Cl- ions are attracted to the oxygen atoms of water molecules. Na+ ions are attracted to the oxygen atoms of water molecules. Cl- ions are repelled by the hydrogen atoms of water molecules. Na+ ions are repelled by the oxygen atoms of water molecules. 16. When compared with the energy of an electron in the first shell of a carbon atom, the energy of an electron in the second shell of a carbon atom is (1 point) *hint increase in potential energy as you go up shells a . b . c . less great er the same 17. Which set of symbols represents atoms with valence electrons in the same electron shell? (1 point) *hint look at elements in same group a . b . c . Ba, Br, Bi Sr, Sn, I O, S, Te d . Mn, Hg, Cu 18. The formula H2O2 is an example of (1 point) *hint this is not in the lowest ratio a . b . c . d . a molecular formula an empirical formula an ionic formula an organic formula 19. Which radioisotope undergoes beta decay and has a half-life of less than 1 minute? (1 point) *look in reference table for the decay rate of each a . b . c . d . Fr22 0 K42 N16 P32 20. Experiments performed to reveal the structure of atoms led scientists to conclude that an atom's (1 point) *hint modern atomic theory a . b . c . positive charge is evenly distributed throughout its volume negative charge is mainly concentrated in its nucleus mass is evenly distributed throughout its volume d . volume is mainly unoccupied 21. Which process represents a chemical change? (1 point) *hint chemical change means you cant go back to original state by physical methods. When you melt ice or evaporate water its still the same thing. (physical changes) a . b . c . d . melting of ice corrosion of copper evaporation of water crystallization of sugar 22. Which type of radiation continues in a straight line when passed through an electric field? (1 point) *hint remember radiation, not particles. Beta is misleading a . b . c . d . alp ha bet a ga mm a prot on 23. Molecules in a sample of NH3(l) are held closely together by intermolecular forces *hint In the NH3 molecule, there is a covalent bond between N and H. But the N "wants" the electrons more than the H does, so it pulls them closer to itself. You end up with a little more than half the negative charge from the bond on the N, and a little less than half on the H. That means N has a partial negative charge and H has a partial positive charge. These partial charges are attracted to each other, and that's what holds the molecules close together. a . b . (1 point) existing between ions existing between electrons c . d . caused by different numbers of neutrons caused by unequal charge distribution 24. Which sample of matter is a mixture? (1 point) *aq means dissolved in water, (aqueous) a . b . c . d . H2O( s) H2O( g) NaCl (l) NaCl (aq) 25. The concept of an ideal gas is used to explain (1 point) *hint remember kinetic molecular theory. BEHAVIOR! a . b . c . d . the mass of a gas sample the behavior of a gas sample why some gases are monatomic why some gases are diatomic 26. Which statement concerning elements is true? (1 point) *hint remember specifics about atom models a . b . c . Different elements must have different numbers of isotopes. Different elements must have different numbers of neutrons. All atoms of a given element must have the same mass number. d . All atoms of a given element must have the same atomic number. 27. Which characteristic is a property of molecular substances? (1 point) *hint a candle is a molecular substance a . good heat conductivity b . good electrical conductivity c . low melting point d . high melting point 28. All chemical reactions have a conservation of (1 point) *hint mass and charge are very important things a . mass, only b . mass and charge, only c . charge and energy, only d . mass, charge, and energy 29. Which substance represents a compound? (1 point) *hint simple letters doesn’t signify elements. Co is cobalt. CO is carbon and oxygen (carbon monoxide) a . b . c . d . C( s) C o( s) O2 C O( g) 30. At 298 K, oxygen (O2) and ozone (O3) have different properties because their (1 point) *hint these guys have different shapes, shapes changes its characteristics a . atoms have different atomic numbers b . atoms have different atomic masses c . molecules have different molecular structures d . molecules have different average kinetic energies 31. Which compound contains only covalent bonds? (1 point) *hint ionic is nonmetal with metal a . b . NaO H Ba( OH)2 c . d . Ca( OH)2 CH3 OH 32. What determines the order of placement of the elements on the modern Periodic Table? (1 point) *hint first periodic table was ordered by atomic mass but later changed to atomic ___ a . b . c . d . atomic number atomic mass the number of neutrons, only the number of neutrons and protons 33. The atomic mass of an element is the weighted average of the masses of (1 point) *hint you would want all right? a . b . c . d . its two most abundant isotopes its two least abundant isotopes all of its naturally occurring isotopes all of its radioactive isotopes 34. Which statement is true about a proton and an electron? (1 point) *hint electron’s mass 1/1856 of a protons a . b . c . They have the same masses and the same charges. They have the same masses and different charges. They have different masses and the same charges. d . They have different masses and different charges. 35. Which of these phrases best describes an atom? (1 point) *hint modern atomic theory a . b . c . d . a positive nucleus surrounded by a hard negative shell a positive nucleus surrounded by a cloud of negative charges a hard sphere with positive particles uniformly embedded a hard sphere with negative particles uniformly embedded 36. Which nuclide is a radioisotope used in the study of organic reaction mechanisms? (1 point) *hint what do scientist use to date old artifacts? a . carbon12 b . c . d . carbon14 uranium235 uranium238 37. In a fusion reaction, reacting nuclei must collide. Collisions between two nuclei are difficult to achieve because the nuclei are (1 point) *hint they tend to repel. Like charges repel a . b . c . d . both negatively charged and repel each other both positively charged and repel each other oppositely charged and attract each other oppositely charged and repel each other 38. Compared to the boiling point of H2S, the boiling point of H2O is relatively high. Which type of bonding causes this difference? (1 point) *hydrogen bonding is between Hydrogen and with either flourine, oxygen, and nitrogen. a . b . c . d . coval ent ionic netw ork hydro gen 39. The gram atomic mass of oxygen is 16.0 grams per mole. How many atoms of oxygen does this mass represent? (1 point) *hint per mole same amount of atoms (Avogadro’s number) a . 16.0 b . c . d . 32.0 6.02 x 1023 2(6.02 x 1023) 40. Which element in Group 1 has the greatest tendency to lose an electron? (1 point) *hint the larger atom, further away from nucleus. Go down group a . b . c . d . cesiu m rubidiu m potass ium sodiu m 41. Which element is classified as a metalloid (semimetal)? (1 point) *hint look at periodic table a . b . c . d . sulfu r silic on bari um bro min e 42. A student calculates the density of an unknown solid. The mass is 10.04 grams, and the volume is 8.21 cubic centimeters. How many significant figures should appear in the final answer? (1 point) *hint use the number with the least amount of significant digits a . b . 4 3 c . d . 2 1 43. Which group contains a liquid that is a nonmetal at STP? (1 point) *hint group 17 contains Br which is a liquid. Iodine is a solid. Mercury is a liquid (it’s a metal though) a . b . c . d . 1 4 1 5 1 6 1 7 44. How many days are required for 200. gram of radon-222 to decay to 50.0 grams? (1 point) *hint look at the reference table for half life times a . b . c . d . 11.5 days 7.64 days 3.82 days 1.91 days 45. When ionic bonds are formed, metallic atoms tend to (1 point) *metals become cations. Loose and get (+) a . b . lose electrons and become negative ions lose electrons and become positive ions c . gain electrons and become negative ions d . gain electrons and become positive ions 46. The ability to conduct electricity in the solid state is a characteristic of metallic bonding. This characteristic is best explained by the presence of (1 point) *hint we need a moving electrons something to be conducting. When an ionic solid is dissolved in water it can conduct also. a . high ionization energies b . high electronegativities c . mobile protons d . mobile electrons 47. Atoms of which element have the weakest attraction for electrons? (1 point) *hint metals don’t want electrons a . b . c . d . N a P S S i 48. An atom with the electron configuration 2 2 1s 2s 2p63s23p63d54s2 has an incomplete (1 point) *hint d sublevel in 3rd principal energy level can fill 10 electrons a . b . c . 2p sublevel second principal energy level third principal energy level d . 4s sublevel 49. What is the pressure of a mixture of CO2, SO2, H2O gases, if each gas has a partial pressure of 250 torr? (1 point) *Daltons law of partial pressures. p1 + p2 + p3 + p4 + …. = pt (pressure total) a . b . c . d . 250 torr 500 torr 750 torr 1000 torr 50. The particles of a substance are arranged in a definite geometric pattern and are constantly vibrating. This substance can be in (1 point) *hint solids are moving (slightly) a . b . c . d . 1)d 2)c 3)d 4)a 5)b 6)d 7)b 8)c 9)d 10)c 11)b 12)d the solid phase, only the liquid phase, only either the liquid or the solid phase neither the liquid nor the solid phase 13) c * 14)c 15)b 16)b 17)c 18)a 19)a 20)d 21)b 22)c 23)d 24)d 25)b 26)d 27)c 28)b 29)d 30)c 31)d 32)a 33)c 34)d 35)b 36)b 37)b 38)d 39)c 40)a 41)b 42)b 43)d 44)b 45)b 46)d 47)a 48)c 49)d 50)a (I think these are the answers) facebook If you need any kind of explanation message “Keshara Senanayake” on