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Atomic and Molecular Structure The periodic table displays the elements in increasing atomic number and shows how periodicity of the physical and chemical properties of the elements relates to atomic structure. As a basis for understanding this concept: a. Students know how to relate the position of an element in the periodic table to its atomic number and atomic mass. On the periodic tables given, atomic number is on the top, and atomic mass is on the bottom. The atomic number is the number of PROTONS. The mass number includes the number of protons and neutrons. The number of electrons on an uncharged atom is the same as the number of protons and the atomic number. Isotopes have the same number of protons, but a different number of neutrons. b. Students know how to use the periodic table to identify metals, semimetals, nonmetals, and halogens. c. Students know how to use the periodic table to identify alkali metals, alkaline earth metals and transition metals, trends in ionization energy, electronegativity, and the relative sizes of ions and atoms. MEMORIZE THE INFO ON THESE TABLES!!! Semimetals/ metalloids are on diagonal from top of group 3A to bottom of 8A. The arrows indicate the trend: Ionization energy and Electronegativity INCREASE in these directions Atomic size and Ionic size increase in these directions: d. Students know how to use the periodic table to determine the number of electrons available for bonding. The number of electrons on the same energy level (period) are the VALENCE ELECTRONS. These are the electrons available for bonding. Usually it is the same as the group number (1-8A). e. Students know the nucleus of the atom is much smaller than the atom yet contains most of its mass. Remember- The nucleus is in the center, with protons and neutrons, while the electrons occupy orbitals outside the nucleus. Protons have a positive charge, electrons have a negative charge, and neutrons have no charge. Nuclear Processes 11. Nuclear processes are those in which an atomic nucleus changes, including radioactive decay of naturally occurring and humanmade isotopes, nuclear fission, and nuclear fusion. As a basis for understanding this concept: a. Students know protons and neutrons in the nucleus are held together by nuclear forces that overcome the electromagnetic repulsion between the protons. The force that holds the nucleus together is the STRONG Force. b. Students know the energy release per gram of material is much larger in nuclear fusion or fission reactions than in chemical reactions. The change in mass (calculated by E = mc2 ) is small but significant in nuclear reactions. Fusion = atoms come together (H+H=He) Fission = atoms split c. Students know some naturally occurring isotopes of elements are radioactive, as are isotopes formed in nuclear reactions. Remember- Carbon-12 is the basis for all atomic measurements. Carbon-14 is a naturally occurring isotope with 2 extra neutrons that undergoes radioactive decay. The number after the element name indicates the mass number (number of protons and neutrons. Most radioactive isotopes decay into other radioactive isotopes (they stay radioactive!). d. Students know the three most common forms of radioactive decay (alpha, beta, and gamma) and know how the nucleus changes in each type of decay. e. Students know alpha, beta, and gamma radiation produce different amounts and kinds of damage in matter and have different penetrations. Alpha- This is a Helium nucleus (2 protons, 2 neutrons, no electrons) that is ejected from the NUCLEUS! Atomic number goes down by 2, mass number goes down by 4. Least penetrating (piece of paper can stop) Beta- This is an electron that results from a neutron changing to a proton. Atomic number increases by one, mass number stays the same. (Wood or foil will stop) Gamma- High energy Photon- no change in mass number or atomic number. Most penetrating (needs concrete or lead to stop it) Chemical Bonds 2. Biological, chemical, and physical properties of matter result from the ability of atoms to form bonds from electrostatic forces between electrons and protons and between atoms and molecules. As a basis for understanding this concept: a. Students know atoms combine to form molecules by sharing electrons to form covalent or metallic bonds or by exchanging electrons to form ionic bonds. Covalent = Atoms shared (Usually between non-metals) Metallic= electron sea model Ionic= electrons stolen (Between metals!) (metal with nonmetal) b. Students know chemical bonds between atoms in molecules such as H2 , CH4 , NH3 , H2 CCH2 , N2 , Cl2 , and many large biological molecules are covalent. c. Students know salt crystals, such as NaCl, are repeating patterns of positive and negative ions held together by electrostatic attraction. d. Students know the atoms and molecules in liquids move in a random pattern relative to one another because the intermolecular forces are too weak to hold the atoms or molecules in a solid form. e. Students know how to draw Lewis dot structures. Find group number for number of valence electronsdraw dots! Connect molecules by indicating shared dots (ideal number is 8) Conservation of Matter and Stoichiometry 3. The conservation of atoms in chemical reactions leads to the principle of conservation of matter and the ability to calculate the mass of products and reactants. As a basis for understanding this concept: a. Students know how to describe chemical reactions by writing balanced equations. b. Students know the quantity one mole is set by defining one mole of carbon 12 atoms to have a mass of exactly 12 grams. c. Students know one mole equals 6.02x1023particles (atoms or molecules). d. Students know how to determine the molar mass of a molecule from its chemical formula and a table of atomic masses and how to convert the mass of a molecular substance to moles, number of particles, or volume of gas at standard temperature and pressure. e. Students know how to calculate the masses of reactants and products in a chemical reaction from the mass of one of the reactants or products and the relevant atomic masses. Balance Equation- Remember criss-cross to balance charges in formulas and balance all atoms! Two on one side and three on another means both go to six! Iron + Oxygen gas → Iron (III) Oxide 4Fe + 3 O2 → 2 Fe2O3 ATOMS/ 6.02x1023/mole MOLES!!! Molar MASS MOLECULES Mass 22.4L/mole VOLUME Molar Mass of Na2CO3 = 2x23 (Na2) + 1x12 (C) + 3x16 (O3) = 106g/mole GET IT?