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EAST PENNSBORO AREA SCHOOL DISTRICT Unit: COURSE: 234 ADVANCED CHEMISTRY II Balanced Chemical Equations and Stoichiometry Subject(s): Advanced Chemistry II Grade(s): 11, 12 Days: ? PA Standard: 3.2.C.A4; Balance chemical equations by applying the laws of conservation of mass; Use Stoichiometry to predict quantitative relationships in a chemical reaction. Instructional Tools: Key Learning(s): Unit Essential Question(s): What does a balanced chemical equation represent? Concept: 3.2.C.A4 Balanced Chemical Equations Concept: 3.2.C.A4 Balancing Chemical Equations Concept: 3.2.C.A4 Mass, Volume, and Mole Relationships Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions: What do balanced chemical equations represent? How are chemical equations balanced? (Including the balancing of redox equations) Vocabulary: What are the mass, volume, and mole relationships represented by a balanced chemical equation? Vocabulary: Word Equation Formula Equation Balanced Chemical Equation Coefficient Subscript Reactant Product Atom Inventory Mole Stoichiometry Mole Ratio Avogadro’s Number Average Atomic Mass Molar Mass Empirical Formula Molecular Formula Limiting Reactant Excess Reactant Theoretical Yield Actual Yield Percent Yield Board Approval: April 19, 2011 — 1— EAST PENNSBORO AREA SCHOOL DISTRICT Unit: COURSE: 234, ADVANCED CHEMISTRY II Equilibrium Days: ? Subject(s): Advanced Chemistry II Grade(s): 11, 12 PA Standard: 3.2.12.A5; Predict the shift in equilibrium when a system is subjected to stress. Instructional Tools: Key Learning(s): Unit Essential Question(s): What happens if a chemical reaction does not go to completion? Concept: Concept: Concept: 3.2.12.A5 Dynamic Equilibrium 3.2.12.A5 Equilibrium Constants for Gaseous Reactions 3.2.12.A5 Equilibrium Constants for Reactions in Solution Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions: What is dynamic equilibrium and how does it apply to physical and chemical changes? How are equilibrium reactions for gaseous reactions represented? How are equilibrium reactions for reactions in solution represented? Vocabulary: Vocabulary: Vocabulary: Dynamic Equilibrium Chemical Equilibrium LeChatelier’s Principle Homogeneous Equilibria Heterogeneous Equilibria Equilibrium Constant Kp Kc Common Ion Effect Buffer Hydrolysis Board Approval: April 19, 2011 — 2— EAST PENNSBORO AREA SCHOOL DISTRICT Unit: COURSE: 234, KINETICS ADVANCED CHEMISTRY II Subject(s): Advanced Chemistry II Days: ? Grade(s): PA State Standard: 3.2.10.A4; Identify the factors that affect the rates of reactions. 11, 12 Instructional Tools: Key Learning(s): Unit Essential Question(s): How is the rate of a chemical reaction measured? Concept: Concept: Concept: 3.2.10.A4 Reaction Rate 3.2.10.A4 Reactant Order, Rate Constants, and Reaction Rate Laws 3.2.10.A4 Activation Energy Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions: What is reaction rate for a chemical reaction and how is it affected by temperature changes? How is experimental data and graphical analysis used to determine reactant order, rate constants, and reaction rate laws? What role does activation energy play in reaction rate? Board Approval: April 19, 2011 — 3— Vocabulary: Vocabulary: Vocabulary: Temperature Reaction Rate Chemical Kinetics Instantaneous Rate Reactant Order Rate Constant Reaction Rate L:aw Differential Rate L:aw Integrated Rate Law Method of Initial Rates Initial Rate Overall Reaction Order First Order Reaction Integrated First-Order Rate Law Half-Life of a Reaction Integrated second-Order Rate Law Zero-Order Reaction Integrated Zero-Order Rate Law Pseudo-First-Order Rate Law Catalyst Activation Energy Collision Model Activated Complex Enzyme Concept: 3.2.10.A4 Rate-Determining Step and Reaction Mechanism Lesson Essential Questions: How are the ratedetermining step and reaction mechanism related? Vocabulary: Rate-Determining Step Reaction Mechanism Intermediate Elementary Step Molecularity Unimolecular Step Bimolecular Step Termolecular Step Board Approval: April 19, 2011 — 4— EAST PENNSBORO AREA SCHOOL DISTRICT Unit: COURSE: 234, ADVANCED CHEMISTRY II Reaction Types Days: ? Subject(s): Advanced Chemistry II Grade(s): 11, 12 PA Standard: 3.2.10.A4; Describe chemical reactions in terms of atomic rearrangement and/or electron transfer. Instructional Tools: Key Learning(s): Unit Essential Question(s): How are chemical reactions classified? Concept: Concept: Concept: 3.2.12.A4 Acid-Base Reactions 3.2.10.A4 Precipitation Reactions 3.2.12.A4 Oxidation-Reduction Reactions Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions: What happens during an acidbase reaction? What happens during a precipitation reaction? What happens during an oxidationreduction reaction? Board Approval: April 19, 2011 — 5— Vocabulary: Vocabulary: Vocabulary: Arrhenius Acid/Base Bronsted-Lowery Acid/Base Lewis Acid/Base Coordination Complex Amphoterism Hydronium Ion Conjugate Acid Conjugate Base Acid Dissociation Constant Strong Acid Weak Acid Monprotic Acid Diprotic Acid Oxyacids pH Scale Strong Base Weak Base Polyprotic Acid Triprotic Acid Salt Aqueous Solution Precipitation Reaction Precipitate Overall Ionic Equation Net Ionic Equation Spectator Ions Oxidation-Reduction (Redox) Reaction Oxidation Number Oxidation Reduction Oxidizing Agent Reducing Agent Half-Reactions Electrochemistry EAST PENNSBORO AREA SCHOOL DISTRICT Unit: Thermochemistry Days: ? COURSE: 234, ADVANCED CHEMISTRY II Subject(s): Advanced Chemistry II Grade(s): PA State Standard: 3.2.10.A4; Explain the difference between endothermic and exothermic reations. 11, 12 Instructional Tools: Key Learning(s): Unit Essential Question(s): How does heat, enthalpy, free energy, and spontaneity of chemical reactions relate? Board Approval: April 19, 2011 — 6— Concept: Concept: Concept: 3.2.10.A4 State Functions 3.2.10.A4 Heat and Enthalpy 3.2.10.A4 Entropy and Free Energy Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions: What are state functions? How do heat and enthalpy relate to chemical reactions? How do entropy and free energy relate to chemical reactions? Board Approval: April 19, 2011 — 7— Vocabulary: Vocabulary: Vocabulary: State Function Pathway Energy Law of Conservation of Energy Potential Energy Kinetic Energy Heat Work System Surroundings Exothermic Endothermic Thermodynamics First Law of Thermodynamics Internal Energy Enthalpy Enthalpy of Formation Enthalpy of Reaction Hess’ Law Enthalpy of Vaporization and Fusion Calorimeter Calorimetry Heat Capacity Specific Heat Capacity Molar Heat Capacity Standard State Spontaneous Process Entropy Free Energy Free Energy of Formation Free Energy of Reaction Second Law of Thermodynamics Third Law of Thermodynamics Concept: 3.2.10.A4 Free Energy, Equilibrium Constants, and Electrode Potentials Lesson Essential Questions: How do free energy, equilibrium constants, and electrode potentials relate? Board Approval: April 19, 2011 — 8—