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An excursion into modern superconductivity: from nanoscience to cold atoms and holography Antonio M. García-García Yuzbashyan Rutgers Richter Regensburg Altshuler Columbia Sangita Bose, Tata, Max Planck Stuttgart Urbina Regensburg Kern Stuttgart Diego Rodriguez Masaki Tezuka Queen Mary Kyoto Sebastian Franco Santa Barbara Jiao Wang NUS Superconductivity in nanograins Practical New forms of superconductivity Superconductivity Increasing the superconductor Tc Technical New tools String Theory Theoretical Enhancement and control of superconductivity in nanograins Phys. Rev. Lett. 100, 187001 (2008) Yuzbashyan Rutgers Altshuler Columbia Sangita Bose, Tata, Max Planck Stuttgart arXiv:0911.1559 Nature Materials Richter Regensburg Urbina Regensburg Kern Ugeda, Brihuega Main goals 1. Analytical description of a clean, finite-size BCS superconductor? 2. Are these results applicable to realistic grains? 3. Is it possible to increase the critical temperature? L The problem BCS gap equation V bulk Δ~ De-1/ Can I combine this? Semiclassical 1/kF L <<1 Berry, Gutzwiller, Balian V finite Δ=? ? Is it already done? Relevant Scales Δ0 Superconducting gap L typical length Mean level spacing l coherence length F Fermi Energy ξ Superconducting coherence length Conditions BCS / Δ0 << 1 Semiclassical 1/kFL << 1 Quantum coherence l >> L ξ >> L For Al the optimal region is L ~ 10nm Maybe it is possible Go ahead! Corrections to BCS smaller or larger? Let’s think about this This has not been done before It is possible but, is it relevant? If so, in what range of parameters? A little history Superconductivity in particular geometries Parmenter, Blatt, Thompson (60’s) : BCS in a rectangular grain Heiselberg (2002): BCS in harmonic potentials, cold atom appl. Shanenko, Croitoru (2006): BCS in a wire Devreese (2006): Richardson equations in a box Kresin, Boyaci, Ovchinnikov (2007) Spherical grain, high Tc Olofsson (2008): Estimation of fluctuations in BCS, no correlations Nature of superconductivity (?) in ultrasmall systems Breaking of superconductivity for / Δ0 > 1? Estimation. No rigorous! Anderson (1959) Thermodynamic properties Muhlschlegel, Scalapino (1972) Experiments Tinkham et al. (1995) . Guo et al., Science 306, 1915, Superconductivity Modulated by quantum Size Effects. T = 0 and / Δ0 > 1 (1995-) Richardson, von Delft, Braun, Larkin, Sierra, Dukelsky, Yuzbashyan Description beyond BCS Even for / Δ0 ~ 1 there is “supercondutivity 1.Richardson’s equations: Good but Coulomb, phonon spectrum? 2.BCS fine until / Δ0 ~ 2 / Δ0 >> 1 No systematic BCS treatment of the dependence of size and shape We are in business! Hitting a bump λ/V ? In,n should admit a semiclassical expansion but how to proceed? I ~1/V? Fine, but the matrix elements? For the cube yes but for a chaotic grain I am not sure From desperation to hope ? A B VI ( , ' ) 2 2 f ( ' , F , L) kF L kF L Yes, with help, we can Regensburg, we have got a problem!!! Do not worry. It is not an easy job but you are in good hands Nice closed results that do not depend on the chaotic cavity For l>>L ergodic theorems assures universality f(L,- ’, F) is a simple function A few months later Semiclassical (1/kFL >> 1) expression of the matrix elements valid for l >> L!! ω = -’ Relevant in any mean field approach with chaotic one body dynamics Now it is easy 3d chaotic Sum is cut-off ξ Boundary conditions Universal function Enhancement of SC! 3d chaotic Al grain kF = 17.5 nm-1 = 7279/N mV 0 = 0.24mV L = 6nm, Dirichlet, /Δ0=0.67 For L< 9nm leading correction comes from I(,’) L= 6nm, Neumann, /Δ0,=0.67 L = 8nm, Dirichlet, /Δ0=0.32 L = 10nm, Dirichlet, /Δ0,= 0.08 3d integrable Numerical & analytical Cube & rectangle From theory to experiments Real (small) Grains L ~ 10 nm Sn, Al… Is it taken into account? Coulomb interactions No, but screening should be effective Surface Phonons No, but no strong effect expected Deviations from mean field Yes Decoherence Yes Fluctuations No Mesoscopic corrections versus corrections to mean field Finite size corrections to BCS Matveev-Larkin Pair breaking Janko,1994 The leading mesoscopic corrections contained in (0) are larger The correction to (0) proportional to has different sign Experimentalists are coming Sorry but in Pb only small fluctuations Are you 300% sure? arXiv:0904.0354v1 However in Sn is very different !!!!!!!!!!!!! !!!!!!!!!!!!! !!! Pb and Sn are very different because their coherence lengths are very different. 5.33 Å 7 nm I V STM tip Å 33.5 Pb/Sn nano-particle BN Rh(111) 0.0 0Å 0nm dI/dV (T ) Theory + Direct observation of thermal fluctuations and the gradual breaking of superconductivity in single, isolated Pb nanoparticles Pb ? Theoretical description of dI/dV ? (T ) dI/dV Dynes formula Solution Thermal fluctuations + BCS Finite size effects + Deviations from mean field Dynes fitting Problem: > How? Finite T Thermal fluctuations Static Path approach BCS finite size effects Part I Deviations from BCS Richardson formalism No quantum fluctuations! T=0 BCS finite size effects Part I Deviations from BCS Richardson formalism Altshuler, Yuzbashyan, 2004 No quantum fluctuations! Not important h ~ 6nm Cold atom physics and novel forms of superconductivity Cold atoms settings Temperatures can be lowered up to the nano Kelvin scale Interactions can be controlled by Feshbach resonances Ideal laboratory to test quantum phenomena Until 2005 2005 - now 1. Disorder & magnetic fields Test of Anderson localization, Hall Effect 2. Non-equilibrium effects Test ergodicity hypothesis 3. Efimov physics Bound states of three quantum particles do exist even if interactions are repulsive What is the effect of disorder in 1d Fermi gases? Stability of the superfluid state in a disordered 1D ultracold fermionic gas Masaki Tezuka (U. Tokyo), Antonio M. Garcia-Garcia arXiv:0912.2263 DMRG analysis of Why? Only two types of disorder can be implemented experimentally Speckel potential speckle Modugno Our model!! incommensurate lattice pure random with correlations quasiperiodic localization for any localization transition at finite 2 Results I Attractive interactions enhance localization U=1 c = 1<2 Results II Weak disorder enhances superfluidity Results III A pseudo gap phase exists. Metallic fluctuations break long range order Results IV Spectroscopic observables are not related to long range order String theory meets condensed matter Strongly coupled field theory N=4 Super-Yang Mills CFT Why? Weakly coupled gravity dual Anti de Sitter space AdS Applications in high Tc superconductivity Powerful tool to deal with strong interactions Why now? New field. Potential for high impact JHEP 1004:092 (2010) What is next? Transition from qualitative to quantitative Phys. Rev. D 81, 041901 (2010) Collaboration with string theorists Problems 1. Estimation of the validity of the AdS-CFT approach 2. Large N limit For what condensed matter systems these problems are minimized? Phase Transitions triggered by thermal fluctuations Why? 1. Microscopic Hamiltonian is not important 2. Large N approximation OK Holographic approach to phase transitions Phys. Rev. D 81, 041901 (2010) 1. d=2 and AdS4 geometry 2. For c3 = c4 = 0 mean field results 3. Gauge field A is U(1) and is a scalar 4. A realization in string theory and M theory is known for certain choices of ƒ 5. By tuning ƒ we can reproduce many types of phase transitions Results I For c4 > 1 or c3 > 0 the transition becomes first order A jump in the condensate at the critical temperature is clearly observed for c4 > 1 The discontinuity for c4 > 1 is a signature of a first order phase transition. Results II 1. For c3 < -1 2. For Second order phase transitions with non mean field critical exponents different are also accessible O2 T Tc 1 1/ 2 2 1 1/ 2 Condensate for c = -1 and c4 = ½. β = 1, 0.80, 0.65, 0.5 for = 3, 3.25, 3.5, 4, respectively 1 2 Results III The spectroscopic gap becomes larger and the coherence peak narrower as c4 increases. Future 1. Extend results to β <1/2 2. Adapt holographic techniques to spin discrete 3. Effect of phase fluctuations. Mermin-Wegner theorem? 4. Relevance in high temperature superconductors THANKS! Unitarity regime and Efimov states 3 identical bosons with a large scattering length a Energy Efimov trimers Bound states exist even for repulsive interactions! 3 particles 1/a trimer Predicted by V. Efimov in 1970 trimer Ratio = 514 Bond is purely quantum- mechanical trimer Naidon, Tokyo Form an infinite series (scale invariance) What would I bring to Seoul National University? Expertise in interesting problems in condensed matter theory Cross disciplinary profile and interests with the common thread of superconductivity Teaching and leadership experience from a top US university Collaborators Decoherence and geometrical deformations Decoherence effects and small geometrical deformations weaken mesoscopic effects How much? To what extent is our formalism applicable? Both effects can be accounted analytically by using an effective cutoff in the trace formula for the spectral density Our approach provides an effective description of decoherence Non oscillating deviations present even for L ~ l What next? Quantum Fermi gases From few-body to many-body Discovery of new forms of quantum matter Relation to high Tc superconductivity Holographic approach to phase transitions Phys. Rev. D 81, 041901 (2010) 1. A condensate that is non zero at low T and that vanishes at a certain T = Tc 2. It is possible to study different phase transitions 3. A string theory embedding is known A U(1) field , p scalars F Maxwell tensor E. Yuzbashyan, Rutgers B. Altshuler Columbia JD Urbina Regensburg S. Bose Stuttgart M. Tezuka Kyoto K. Richter Regensburg Let’s do it!! D. Rodriguez Queen Mary J. Wang Singapore P. Naidon Tokyo K. Kern, Stuttgart S. Franco, Santa Barbara