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Chapter 2
The Chemical Context of Life
PowerPoint Lectures for
Biology, Ninth Edition
Neil Campbell and Jane Reece
Elements and Compounds
• An element is a substance that cannot be
broken down to other substances by chemical
reactions
• A compound is a substance consisting of
two or more elements in a fixed ratio
Sodium
Chlorine
Sodium chloride
Essential Elements of Life
• Carbon, hydrogen, oxygen, and nitrogen make
up 96% of living matter
• Trace elements are those required by an
organism in minute quantities
Atomic Number and Atomic Mass
• Atoms of the various elements differ in number of
subatomic particles
– Atomic number
– Mass number
– Atomic mass
Isotopes
• Atoms of an element have the same number of
protons but may differ in number of neutrons
• some are radioactive
• Some applications of radioactive isotopes
in biological research:
– Dating fossils
– Tracing atoms through metabolic
processes
– Diagnosing medical disorders
The Energy Levels of Electrons
• Energy is the capacity to cause change
• Potential energy is the energy that matter
has because of its location or structure
• electron shell
A ball bouncing down a flight
of stairs provides an analogy for
energy levels of electrons.
Third energy level (shell)
Second energy level (shell)
Energy
absorbed
First energy level (shell)
Energy
lost
Atomic
nucleus
Electron Orbitals
• An orbital is the three-dimensional space
where an electron is found 90% of the time
Covalent Bonds
Hydrogen atoms (2 H)
• A covalent bond is
the sharing of a pair
of valence electrons
by two atoms
Hydrogen
molecule (H2)
• A molecule consists of two or more atoms held
together by covalent bonds
– single covalent bond
– double covalent bond
Oxygen (O2)
Name
(molecular
formula)
Water (H2O)
Electronshell
diagram
Structural
formula
Spacefilling
model
Name
(molecular
formula)
Methane (CH4)
Electronshell
diagram
Structural
formula
Spacefilling
model
δ–
O
H
δ+
H
H2O
δ+
Ionic Bonds
• Atoms sometimes strip electrons from
their bonding partners
– Example: sodium to chlorine
Na
Cl
Na+
Cl–
Sodium atom
(an uncharged
atom)
Chlorine atom
(an uncharged
atom)
Sodium ion
(a cation)
Chlorine ion
(an anion)
Sodium chloride (NaCl)
• An anion is a negatively charged ion
• A cation is a positively charged ion
• An ionic bond is an attraction between an anion
and a cation
Na+
Cl–
Weak Chemical Bonds
• Weak chemical bonds reinforce shapes of
large molecules and help molecules
adhere to each other
– Ionic bonds
– Hydrogen bonds
– Van der Waals Interactions
Hydrogen Bonds
δ–
δ+
Water
(H2O)
δ+
Hydrogen bond
δ–
Ammonia
(NH3)
δ+
δ+
δ+
Van der Waals Interactions
• Molecules or atoms that are very close
together can be attracted by fleeting
charge differences
Molecular Shape and Function
• A molecule’s shape is usually very
important to its function
– determined by the positions of its atoms’
valence orbitals
s orbital
z
Three p orbitals
Four hybrid orbitals
x
y
Tetrahedron
Hybridization of orbitals
Chemical reactions make and break chemical
bonds
• The starting molecules of a chemical reaction
are called reactants
• The final molecules of a chemical reaction
are called products
2 H2
O2
Reactants
2 H2O
Reaction
Products