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Exam Study Sheet (as of January 2017) Exam Matrix Unit Multiple Choice Short Answer Total Marks % Value of Exam Atomic Structure 6 0 6 5.2 Bonding 18 20 38 32.8 Thermodynamics 15 22 37 31.9 Chemical Kinetics 11 24 35 30.2 Total 50 66 116 100 Unit Topics Review 1. 2. (0 specific marks) Know the following terms: molar mass. Conduct mole conversions and stoichiometric calculations. Strand I Unit 1 1. 2. 3. 4. 5. 6. 7. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. Atomic Structure Know the following terms: aufbau principle, electronegativity, octet rule, orbital, quanta, sub-shell, uncertainty principle and valence. Review the development of quantum atomic theory (quantum mechanical theory). Identify, define and compare the different quantum numbers. Determine quantum signature of electrons. Identify the conclusions regarding quatum theory of various scientists (de Broglie, Heisenberg, Hund, Michelson, Pauli, Planck, Schrödinger, Sommerfeld and Zeeman). Determine the electronic configurations for atoms/ions. Determine how and when to promote electrons. Unit 2 1. Structure and Properties Bonding Know the following terms: aggregate, bond angle, covalent bond, delocalized electron, dipole, hybridization, inductive dipole, ionic bond, lattice, Lewis diagram, London Dispersion Force (LDF), orbital, polar, pseudocovalent, quanta, sub-shell, VSEPR, solubility, unsymmetrical, valence and van der Waals. Determine how and when to hybridize orbitals. Determine hybridized states of atoms when they forms single, double or triple bonds (e.g. carbon). Draw Lewis diagrams and calculate/use formal charge to determine probable/optimal configurations. Determine/draw and name the shape of molecules. Identify factors that determine the shape of molecules (e.g. number of lone pairs and bonding pairs, etc.). Determine/draw bond polarity and molecular polarity. Compare sigma and pi bonds. Draw/interpret and label bonding orbital diagrams. Compare intermolecular forces and intramolecular forces. Identify/explain properties of aggregate solids. Use properties of solids to identify types of aggregate solids. Compare the different intermolecular bonds present in molecular solids and their impact on the properties of these solids. Strand II Unit 3 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Thermodynamics Know the following terms: activation energy (EA), burning/combustion, bombardment, dissolving, enthalpy, molar heat, nucleon and resting mass. Compare exothermic and endothermic reactions/notation. Calculate the heat released or absorbed by dissolving. Conduct quantities of heat calculations using Q=mcΔT. Identify the conditions of standard enthalpy. Compare enthalpy of chemical reactions and changes of state (latent heat). Define and use Hess's law to determine heats of reactions/formation (both methods). Calculate enthalpy and molar enthalpy of reactions. Analyze different potential energy curves to determine if a reaction is spontaneous, endothermic or exothermic. Identify the different nuclear particles involved in nuclear reactions. Determine the reactants or products of nuclear reactions and balance these equations. Calculate the binding energy of nuclear reactions. Unit 4 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. Energy Changes and Rates of Reactions Chemical Kinetics Know the following terms: endothermic, exothermic and polyatomic ion. Calculate average reaction rates and instantaneous reaction rates from graphs. Calculate the rate of reactant consumption and product formation in reactions. Identify postulates of collision theory. Apply collision theory to explain reaction rates and factors affecting reaction rates. Explain how surface area, nature of reactants, concentration, temperature and catalysts which affect the rate of a reaction. Determine methods which can be used to speed up or slow down reactions. Calculate rate effects, rate laws, rate constants and rate constant units from data (simple rate laws only). Define activation energy and identify it in a potential energy graph. Calculate activation energy from a potential energy graph or data. Given a rate law, determine concentrations of reactants or rates. Determine reaction orders. Interpret a rate law and/or reaction orders to determine the impact on reaction rate. Prepared by A. Jarrett and K. Zuber