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Energy and Equilibria Lesson outline Lesson Content EE1 EE3 4.10, 4.11 & 4.12 P8687 How do you calculate the heat energy (molar enthalpy) of a combustion reaction? Know that copper calorimeters are used to measure the temperature change of water as a fuel is used to heat it Know how to set up an experiment for investigating the combustion of alcohols Calculate heat energy for combustion reactions, i.e. heating water with alcohol spirit burners Calculate molar enthalpy for combustion reactions 4.11 & 4.12 P8687 How do you represent enthalpy changes that occur during a chemical reaction? Know that ΔH (molar enthalpy) is negative for exothermic and positive for endothermic reactions Draw simple energy level diagrams to represent the change in enthalpy of exothermic and endothermic reactions Recall that the breaking of bonds is endothermic and that the making of bonds is exothermic Calculate the molar enthalpy of simple chemical reactions using average bond energies EE4 Page refs. How does temperature change during exothermic and endothermic reactions? Recall that exothermic reactions give out heat and that endothermic reactions take in heat Recall the equation used to calculate heat energy- q=mcT Know that foam calorimeters are used to measure temperature changes for displacement, dissolving and neutralisation reactions Calculate heat energy for these types of reactions Know that molar enthalpy is used to represent the change in energy of a reaction, per mole of limiting reagent Recall the equation used to calculate H=q / n Calculate molar enthalpy for the above reactions EE2 Key Assess -ment Syllabus statements 4.13, 4.14, 4.15 & 4.16 P8687 What are reversible reactions? Recall that some reactions are irreversible and can only go in the forward direction Recall that some reactions are reversible and are indicated by the symbol in equations Know that heating hydration copper(II) sulfate will remove the water and that adding water will reverse the reaction Know that heating ammonium chloride will cause it to reform in a cooler area of the test tube TTS iGCSE CHEMISTRY 4.22 & 4.23 P110 -111 Folder E/G/A/N Energy and Equilibria EE5 What is dynamic equilibrium? Define dynamic equilibrium as both the forward and backward reactions taking place at the same time, but the concentrations of reactant and products remaining constant. Know that an increase in pressure will favour the side with less gas particles for a reaction at equilibrium Know that an increase in temperature will favour the direction which takes in heat (endothermic) for a reaction at equilibrium Know that an increase in concentration of reactants will favour the forward reaction (towards the products) for a reaction at equilibrium EE6 P112 -113 5.21, 5.22, 5.23 & 5.24 P198 -199 How can you make ammonia on an industrial scale? Recall that nitrogen from air, and hydrogen from natural gas or the cracking of hydrocarbons, are used in the manufacture of ammonia Know that for the manufacture of ammonia by the Haber process, the essential conditions are: i) a temperature of about 450°C ii) a pressure of about 200 atmospheres iii) an iron catalyst Discuss the economic reasons for choosing such conditions Know that the cooling of the reaction mixture liquefies the ammonia produced and allows the unused hydrogen and nitrogen to be recirculated Recall the use of ammonia in the manufacture of nitric acid and fertilisers EE7 EE8 4.24 & 4.25 Revision Test Folder checklist All lessons present / titled with lesson code / dated / in correct order Tables drawn with pencil / ruler / column headings correct Diagrams drawn with pencil / ruler Graphs have axis labels / correct scales / title All homeworks completed Topic keywords spelt correctly Strengths Targets TTS iGCSE CHEMISTRY E/G/A/N