Download CHEMISTRY CHAPTER 4 – QUANTUM MECHANICS

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Transcript
CHEMISTRY CHAPTER 4 – QUANTUM THEORY
VOCABULARY (26)
angular momentum quantum number
Aufbau principle
continuous spectrum
electromagnetic radiation
electromagnetic spectrum
electron configuration
excited state
frequency
ground state
Heisenberg uncertainty principle
Hund’s rule
inner shell electrons
line-emission spectrum
magnetic quantum number
noble gas
noble gas configuration
orbital
Pauli exclusion principle
photoelectric effect
photon
principal quantum number
quantum
quantum numbers
quantum theory
spin quantum number
wavelength
LEARNING OBJECTIVES
1. Explain the mathematical relationship among the speed, wavelength, and frequency of
electromagnetic radiation.
2. Discuss the dual wave-particle nature of light.
3. Discuss the significance of the photoelectric effect and the line-emission spectrum of
hydrogen to the development of the atomic model.
4. Describe the Bohr model of the hydrogen atom.
5. Discuss Louis de Broglie’s role in the development of the quantum model of the atom.
6. Compare and contrast the Bohr model and the quantum model of the atom.
7. Explain how the Heisenberg uncertainty principle and the Schrödinger wave equation led to the
idea of atomic orbitals.
8. List the four quantum numbers and describe their significance.
9. Relate the number of sublevels corresponding to each of an atom’s main energy levels, the
number of orbitals per sublevel, and the number of orbitals per main energy level.
10. List the total number of electrons needed to fully occupy each main energy level.
11. State the Aufbau principle, the Pauli exclusion principle, and Hund’s rule.
12. Describe the electron configurations for the atoms of any element using orbital notation,
electron configuration notation, and noble gas notation.