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Honors Unit 5 Practice Test Unit 5 Test Fri 10/29 Multiple Choice Identify the choice that best completes the statement or answers the question. ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ 1. The sequence in which energy sublevels are filled is specified by a. the Pauli exclusion principle. c. Lyman's series. b. the orbital rule. d. the Aufbau principle. 2. The number of electrons in the highest energy level of the argon atom (atomic number 18) is a. 10. c. 6. b. 2. d. 8. 3. The periodic law states that the physical and chemical properties of elements are periodic functions of their atomic a. masses. c. radii. b. numbers. d. charges. 4. Elements in a group or column in the periodic table can be expected to have similar a. atomic masses. c. numbers of neutrons. b. atomic numbers. d. properties. 5. Identify the sublevels in a period that contains 32 elements. a. s, f c. s, p, d b. s, p d. s, p, d, f 6. The period of an element can be determined from its a. reactivity. c. symbol. b. density. d. electron configuration. 7. Elements to the right side of the periodic table (p-block elements) have properties most associated with a. gases. c. metals. b. nonmetals. d. metalloids. 2 6 8. Neutral atoms with an s p electron configuration in the highest energy level belong to which block of the periodic table? a. s block c. d block b. p block d. f block 9. The elements in Group 1 are also known as the a. alkali metals. c. Period 1 elements. b. rare-earth series. d. actinide series. 10. Which represents a neutral atom acquiring an electron in a process where energy is released? a. A + e– + energy A– b. A + e– A– – energy c. A + e– A– + energy d. A– + energy A + e– 11. The energy required to remove an electron from an atom is the atom's a. electron affinity. c. electronegativity. b. electron energy. d. ionization energy. 12. A measure of the ability of an atom in a chemical compound to attract electrons from another atom in the compound is called a. electron affinity. c. electronegativity. b. electron configuration. d. ionization potential. 13. The element that has the greatest electronegativity is ____ 14. ____ 15. ____ 16. ____ 17. ____ 18. ____ 19. ____ 20. ____ 21. ____ 22. ____ 23. ____ 24. ____ 25. a. oxygen. c. chlorine. b. sodium. d. fluorine. A negative ion is known as a(n) a. ionic radius. c. cation. b. valence electron. d. anion. In a row in the periodic table, as the atomic number increases, the atomic radius generally a. decreases. c. increases. b. remains constant. d. becomes immeasurable. In the alkaline-earth group, atoms with the smallest radii a. are the most reactive. b. have the largest volume. c. are all gases. d. have the highest ionization energies. As the atomic number of the metals of Group 1 increases, the ionic radius a. increases. c. remains the same. b. decreases. d. cannot be determined. Across a period in the periodic table, atomic radii a. gradually decrease. b. gradually decrease, then sharply increase. c. gradually increase. d. gradually increase, then sharply decrease. The ionization energies for removing successive electrons from sodium are 496 kJ/mol, 4562 kJ/mol, 6912 kJ/mol, and 9544 kJ/mol. The great jump in ionization energy after the first electron is removed indicates that a. sodium has four or five electrons. b. the atomic radius has increased. c. a d electron has been removed. d. the noble gas configuration has been reached. Which is the best reason that the atomic radius generally increases with atomic number in each group of elements? a. The nuclear charge increases. b. The number of neutrons increases. c. The number of occupied energy levels increases. d. A new octet forms. The ionization energies required to remove successive electrons from one mole of calcium atoms are 590 kJ/mol, 1145 kJ/mol, 4912 kJ/mol, and 6474 kJ/mol. The most common ion of calcium is probably a. Ca+. c. Ca3+. b. Ca2+. d. Ca4+. Valence electrons are those s and p electrons a. closest to the nucleus. c. in the highest energy level. b. in the lowest energy level. d. combined with protons. In Group 2 elements, the valence electrons are in sublevel a. d. c. s. b. p. d. f. The number of valence electrons in Group 17 elements is a. 7. c. 17. b. 8. d. equal to the period number. Which groups in the main group have lower electronegativity than d-block elements? a. groups 1 and 2 c. groups 17 and 18 b. groups 13 through 18 d. groups 13 through 17 ____ 26. Which of the following BEST describes the purpose of effective nuclear charge? a. It is used to rationalize chemical c. It is a measure of the effect of filled bonding in covalently bonded molecules. b. It is a method to evaluate how much and half-filled subshells on the stability of atoms and ions. d. All the above a,b,c attraction a given electron “feels” from the nucleus so that periodic trends can be predicted and rationalized ____ 27. With respect to chemical bonding, which particles play the most active role? a. neutrons b. protons c. valence elecetrons d. core electrons ____ 28. Which pair of elements is most likely to form an ionic compound? a. Mg and F c. O and Cl b. S and O d. Na and Al ____ 29. Which compound is likely to conduct electricity when in aqueous solution? a. phosphorous trichloride c. calcium chloride b. carbon dioxide d. none of these ____ 30. Compounds which are characterized as covalent are generally made up of elements found in which part of the Periodic Table? a. uuper left b. lower left c. lower right d. upper right ____ 31. Predict the most common ion formed by barium. a. Ba3+ c. Ba2+ b. Bad. Ba+ ____ 32. Which covalent bond is the most polar? a. H S b. H H ____ 33. Draw the Lewis electron dot structure for c. O H d. H N NO3- What is the total number of non-shared electrons a. 16 b. 32 c. 15 d. 36 ____ 34. An atom has 35 protons and 35 electrons.Select the true statement: a. The atom’s size will be larger than the c. The atom will have a large favorable size of Ca. b. The atom will have a low ionization electron affinity d. All the above en-ergy. ____ 35. Rank the following in terms of increasing electronegativity. a. Na, N, O, Mg, F c. F, O, N, Mg, Na b. Na, Mg, N, O, F d. F, O, N, Na, Mg ____ 36. A mutual electrical attraction between the nuclei and valence electrons of different atoms that binds the atoms together is called a(n) ____ 37. ____ 38. ____ 39. ____ 40. ____ 41. ____ 42. ____ 43. ____ 44. ____ 45. ____ 46. ____ 47. ____ 48. ____ 49. a. dipole. c. chemical bond. b. Lewis structure. d. London force. Atoms naturally move a. toward high potential energy. c. toward less stability. b. toward low potential energy. d. away from each other. As atoms bond with each other, they a. increase their potential energy, thus creating less-stable arrangements of matter. b. decrease their potential energy, thus creating less-stable arrangements of matter. c. increase their potential energy, thus creating more-stable arrangements of matter. d. decrease their potential energy, thus creating more-stable arrangements of matter. If two covalently bonded atoms are identical, the bond is a. nonpolar covalent. c. dipole covalent. b. polar covalent. d. coordinate covalent. Most chemical bonds are a. purely ionic. c. partly ionic and partly covalent. b. purely covalent. d. metallic. The greater the electronegativity difference between two bonded atoms, the greater the percentage of ____ in the bond. a. ionic character c. metallic character b. covalent character d. electron sharing A bond that is less than 5% ionic is considered a. polar covalent. c. nonpolar covalent. b. ionic. d. metallic. The B—F bond in BF3 (electronegativity for B is 2.0; electronegativity for F is 4.0) is a. polar covalent. c. nonpolar covalent. b. ionic. d. metallic. When a stable covalent bond forms, the potential energy of the atoms a. increases. c. remains constant. b. decreases. d. becomes zero. What group of elements satisfies the octet rule without forming compounds? a. halogen c. alkali metal b. noble gas d. alkaline-earth metal In drawing a Lewis structure, the central atom is generally the a. atom with the greatest mass. b. atom with the highest atomic number. c. atom with the fewest electrons. d. least electronegative atom. Multiple covalent bonds may occur in atoms that contain carbon, nitrogen, or a. chlorine. c. oxygen. b. hydrogen. d. helium. The substance whose Lewis structure shows three covalent bonds is a. H2O. c. NH3. b. CH2Cl2. d. CCl4. What is the correct Lewis structure for hydrogen chloride, HCl? a. A c. C ____ 50. ____ 51. ____ 52. ____ 53. ____ 54. ____ 55. ____ 56. ____ 57. ____ 58. ____ 59. ____ 60. ____ 61. ____ 62. ____ 63. ____ 64. b. B d. D A formula that shows only the types and numbers of atoms combined in a single molecule is called a(n) a. molecular formula. c. Lewis structure. b. ionic formula. d. covalent formula. + – In the NaCl crystal, each Na and Cl ion has how many oppositely charged ions clustered around it? a. 1 c. 4 b. 2 d. 6 The ions in most ionic compounds are organized into a a. molecule. c. polyatomic ion. b. Lewis structure. d. crystal. The lattice energy is a measure of the a. strength of an ionic bond. c. strength of a covalent bond. b. strength of a metallic bond. d. net charge on a crystal. Compared with energies of neutral atoms, a crystal lattice has a. higher potential energy. c. equal potential energy. b. lower potential energy. d. less stability. Compared with ionic compounds, molecular compounds a. have higher boiling points. c. have lower melting points. b. are brittle. d. are harder. The forces of attraction between molecules in a molecular compound are a. stronger than the forces among formula units in ionic bonding. b. weaker than the forces among formula units in ionic bonding. c. approximately equal to the forces among formula units in ionic bonding. d. zero. Compared with nonmetals, the number of valence electrons in metals is generally a. smaller. c. about the same. b. greater. d. almost triple. According to VSEPR theory, an AB2 molecule is a. trigonal-planar. c. linear. b. tetrahedral. d. octahedral. According to VSEPR theory, the shape of an AB3 molecule is a. trigonal-planar. c. linear. b. tetrahedral. d. bent. According to VSEPR theory, the structure of the ammonia molecule, NH3, is a. trigonal-planar. c. trigonal-pyramidal. b. bent. d. tetrahedral. Use VSEPR theory to predict the shape of the hydrogen chloride molecule, HCl. a. tetrahedral c. bent b. linear d. trigonal-planar Use VSEPR theory to predict the shape of the magnesium hydride molecule, MgH2. a. tetrahedral c. bent b. linear d. octahedral Use VSEPR theory to predict the shape of the carbon tetraiodide molecule, CI4. a. tetrahedral c. bent b. linear d. trigonal-planar Use VSEPR theory to predict the shape of carbon dioxide, CO2. a. tetrahedral c. bent b. linear d. octahedral ____ 65. The strength of London dispersion forces between molecules depends on a. only the number of electrons in the molecule. b. only the number of protons in the molecule. c. both the number of electrons in the molecule and the mass of the molecule. d. both the number of electrons and the number of neutrons in the molecule. ____ 66. The strong forces of attraction between the positive and negative regions of molecules are called a. dipole-dipole forces. c. lattice forces. b. London forces. d. orbital forces. ____ 67. Compared with molecular bonds, the strength of intermolecular forces is a. weaker. c. about the same. b. stronger. d. too variable to compare. ____ 68. The equal but opposite charges present in the two regions of a polar molecule create a(n) a. electron sea. c. crystal lattice. b. dipole. d. ionic bond. ____ 69. The reason the boiling point of water (H2O) is higher than the boiling point of hydrogen sulfide (H2S) is partially explained by a. London forces. c. ionic bonding. b. covalent bonding. d. hydrogen bonding. ____ 70. The following molecules contain polar bonds. The only polar molecule is a. CCl4. c. NH3. b. CO2. d. CH4. ____ 71. A polar molecule contains a. ions. b. a region of positive charge and a region of negative charge. c. only London forces. d. no bonds.