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HONORS: UNIT 2B: Antacids Below are the class objectives
HONORS: UNIT 2B: Antacids Below are the class objectives

... Below are the class objectives, correlated to the NC Essential Standards and page numbers within your textbook. In the far right column you will see the required vocabulary of the unit as well. At the end of each unit, you should be able to define and apply all the required vocabulary words in order ...
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... These are not actually enantiomers of each other, but rather diastereomers, because the chirality of the C bearing the ethyl is the same in each case ((R)-). For the dihydroxylations, however, they function as the complementary systems to get enantiomeric products; the unofficial term pseudoenantiom ...
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... ‘Aryldiazonium salt involves both in electrophilic and nucleophilic substitutions’. Justify. What is first order asymmetric transformation? Give an example. How do inductive and field effects affect the second substitution in aromatic systems? In 4-t-butylcyclohexanecarboxylic acid, trans form is mo ...
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Asymmetric Synthesis: Substrate and Auxiliary Control

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... the aromatic pyrazole ring. Note the regioselectivity (one could “flip” either substrate horizontally to see the other theoretical product). In the boxes above, draw an arrow to the more nucleophilic nitrogen atom in the hydrazine substrate. In addition, circle the most electrophilic carbonyl in the ...
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Asymmetric induction



Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis.Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist.Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.
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