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Transcript
Linfield College: CHEM 322
ORGANIC CHEMISTRY II
Spring 2017
(Tentative)
WEEK Experiment
Begin Grignard
1
Reaction
2
3
Conclude
Grignard
Experiment
Ester Synthesis
5
Individual
Experiment A
6
Individual
Experiment B
7
Identification of a
Single Unknown
9
10
11
12
13
14
15
16
THURS
FRI
2/08
2/10
Handouts & CH 11
Expoxides and 12
Alcohols from
Carbonyl Cmpds
CH 12
Alcohols from
Carbonyl Cmpds
CH 12
Alcohols from
Carbonyl Cmpds
2/13
2/17
CH 13
Conjugated unsat.
systems
Conjugated unsat.
systems
2/20
CH 13
2/22
CH 13
Conjugated unsat.
systems
Conjugated unsat.
systems
2/27
CH 14
Aromatic
Compounds
3/06
CH 15
Reactions of
Aromatic Cmpds
3/13
CH 16
Aldehydes and
Ketones I
3/20
CH 17
3/01
CH 15
Reactions of
Aromatic Cmpds
3/08
3/15
CH 16
Aldehydes and
Ketones I
3/22
CH 17
2/24
CH 14
Aromatic
Compounds
3/03
CH 15
Reactions of
Aromatic Cmpds
3/10
CH 16
Aldehydes and
Ketones I
3/17
CH 16
Aldehydes and
Ketones I
3/24
CH 17
Carboxylic Acids
& derivatives
Carboxylic Acids
& derivatives
Carboxylic Acids
& derivatives
3/29
SPRING BREAK
3/31
SPRING BREAK
4/03
CH 18
α-carbon of
carbonyl cmpds:
enol and enolates
4/10
CH 18
α-carbon of
carbonyl cmpds:
enol and enolates
4/05
CH 18
α-carbon of
carbonyl cmpds:
enol and enolates
4/12
4/07
CH 18
α-carbon of
carbonyl cmpds:
enol and enolates
4/14
CH 19
(CH 16-18)
Condensation and
Conjugated
addition rxns of
carbonyl cmpds
4/17
CH 19
4/19
CH 19
4/21
CH 19
Condensation and
Conjugated
addition rxns of
carbonyl cmpds
Condensation and
Conjugated
addition rxns of
carbonyl cmpds
Condensation and
Conjugated
addition rxns of
carbonyl cmpds
4/24
CH 20
Amines
5/01
CH 20
Amines
4/26
CH 20
Amines
5/03
CH 21
Phenols and Aryl
Halides
4/28
CH 20
Amines
5/05
Symposium Day
No Class
5/08
CH 21
Phenols and Aryl
Halides
5/10
CH 21
Phenols and Aryl
Halides
EXAM III
Wed 5/21
5/15
Practice final
5/17
Practice final
5/19
Reading Day
Final Exam
Week
5/22
10:30-12:30am
Final Exam: 5/22
Wed 8am (sec 1)
Tues 8am (sec 2)
5/26-Final
Sign up for
individual
Experiments
3/27
SPRING BREAK
Must pass lab
quiz prior to
starting double
unknown with
>80%
Identification of a
Double Unknown
Identification of a
Double Unknown
Identification of a
Double Unknown
Identification of a
Double Unknown
Identification of a
Double Unknown
MUST SHOW UP
TO LAB for Clean
UP!
WED
2/15
CH 13
NO CLASS
SPRING BREAK
Identification of a
Single Unknown
Continued
TUES
2/06
CH 12
Alcohols from
Carbonyl Cmpd
Friedel-Crafts
Reaction
4
8
MON
EXAM I
(CH 12-15)
SPRING BREAK
EXAM II
Final Exam: 5/21
Wed 8am (sec 1)
Tues 8am (sec 2)
5/12
(CH 19-21)
CHEM 322
Instructor:
Linfield College
ORGANIC CHEMISTRY II
Dr. Elizabeth J. O. Atkinson
Office: 115 Murdock
E-Mail: [email protected]
Linfield College (Chem 322, 4 Credits)
Campus Phone: (503) 883 - 2621
Office Hours:
MWF 12:00-1:00 or by appt.
Lab Coordinator: Ms. Veronica Siller
Office: 112 Murdock; Phone: 883-2739
Office Hours: open door policy or by appt.
E-Mail: [email protected]
Time and Location:
Lecture:
Discussion:
or
Laboratory:
SPRING 2017
10:00 - 10:50 M W F
11:00-11:50 M W F
10:00-10:50
T
11:00-11:50
T
Section 01
Graf 109
Section 02
Graf 109
Section 01
Graf 109
Section 02
Graf 109
1:30-4:30
1:30-4:30
10:50-1:50
2:00-5:00
Section 01
Section 02
Section 03
Section 04
T
W
R
R
Murdock 110
Murdock 110
Murdock 110
Murdock 110
Required Text and Material:
G. Solomons and C. Fryhle, Organic Chemistry, 10e or 11e ed., Wiley
Study Guide to Accompany Text*(strongly suggested)
Laboratory Notebook, Safety Goggles, (Scientific Calculator, Lab Apron, Model Kit)*(strongly suggested)
Digital (Web) Resources: go to www.linfield.edu/chem/ and click on "current courses". Follow links to
CHE 322. There, in ".pdf" format, you will find this syllabus plus
- protocols for all experiments
- useful lab information
- sample lab report and pre-lab
- copies of old exams
- reaction sheet templates
- other chemistry-related goodies
NOTE: Disability Statement: Students with disabilities are protected by the Americans with Disabilities Act and Section 504 of the Rehabilitation
Act. If you are a student with a disability and feel you may require academic accommodations please contact Learning Support Services (LSS), as
early as possible to request accommodation for your disability. The timeliness of your request will allow LSS to promptly arrange the details of your
support. LSS is located in Melrose Hall 020 (503-883-2562). We also encourage students to communicate with faculty about their accommodations.
Academic Integrity: Please read the section “Academic Integrity” in the college catalog (or at http://www.linfield.edu/academicaffairs/curriculum.html). This class will adhere to the policy as published in the Linfield College Course Catalog. Work presented with your name on it
is assumed to be your own, unless designated otherwise. Students engaging in cheating, plagiarism, fabrication, or aiding in such activities are subject
to disciplinary action.
-----------------------------------------------------------------------------------------------------------------GOALS OF THE COURSE:
This is the second semester of the majors-level organic chemistry course. As in the first semester, its goals are to
- teach foundational principles that underlie the chemical and physical behavior of compounds constructed mainly of
carbon atoms
- foster scientific critical thinking skills
- provide experience in common laboratory techniques and “chemical common sense” in the laboratory
- provide practice in writing related to chemistry
- continue to build student capacity for independent scientific thinking
Course Description and Purpose:
Organic chemistry is the study of compounds containing a carbon atom skeleton. Fundamentals of organic
chemistry, including classification, occurrence, synthesis, analysis, and reaction mechanisms of important classes of
organic compounds are studied. During second semester (CHEM 322), aromatics, organometallics, alcohols, ethers,
aldehydes, ketones, carboxylic acids, acid derivatives, and amines are the classes stressed.
The course is designed to provide a fundamental knowledge of organic chemistry - the study of carbon
compounds. After reviewing basic concepts from general chemistry, certain classes of compounds are studied in terms of
preparation and reaction. Basic concepts involving bonding and structure-property relationships are interwoven in the
language and context of organic chemistry.
The study of organic chemistry requires the grasp and understanding of the structure and reactivity of carbon
containing molecules which follow unifying principles that make seemingly diverse reactions understandable and
predictable. Exploring and learning these principles will allow the student to have a basic understanding of how and why
various classes of carbon-containing compounds react, so that he or she will be scientifically literate with respect to
environmental or economic issues.
Chemistry is all around us and continually influences our daily lives (ie, petroleum products, explosives, rubber,
fragrances, beauty care products, environmental pollutants, paper, wood products, medication, food additives, plastics,
fabrics, detergents, computer components, etc…). The objective of this course is to complete a two semester study of
organic chemistry, providing the necessary background and knowledge for those students pursuing careers in medicine, art
restoration, pharmacy, agriculture, materials, health sciences, biology and chemistry to name a few.
Grading System:
Lecture Exams (see below)
Lab Grade (normalized score)
Attendance/participation
Homework+Reaction Sheets+Quizzes+Participation
Total
500pts
150pts
25pts
125pts
800pts
1. Examinations: There will be 3 chapter exams worth 100 points each and a final exam worth 200 points. Exams
test your ability to a) recall facts and concepts and b) apply those concepts to problem solving situations.
2. Laboratory: See separate Laboratory Syllabus below.
3. Homework: The text problems will be assigned with each chapter and will be checked off the Friday after
completing the chapter, but will not be collected. Each assignment is worth 10pts. Late assignments will receive
a maximum of 5pts. Regular practice in applying new material as it is learned is crucial to success in the course and is
the primary way to study for this course. The answers can be found in the Solomons study guide. Looking through the
study guide is not the same as doing the problems yourself. Also, rewriting your notes is strongly suggested.
4. Quizzes: Short quizzes worth 10pts may be given in class or lab to test the knowledge of reactions and
synthetic methods.
5. Reaction Sheets or Note Cards: On-going collection of all reactions learned in the course to be handed-in at the end
of the semester.
6. Participation: Attendance at lectures and lab is important to help develop a better understanding of the
material. Active participation by students in the form of asking questions and making appropriate comments
in lecture and lab sections is expected. Questions regarding homework and tests should be asked prior to the
due date for full credit.
The course work consists of participation in 1) lectures, where facts and governing principles are discussed and
where problems are worked out; and 2) in laboratory sessions, where common synthetic and analytical techniques are used
to illustrate and expand upon principles taught in lecture.
There is too much material to be covered in the limited lecture time, so USE YOUR BOOK!! Note that you are
responsible for understanding all the reading even if some has not been discussed in class.
Understanding is your goal. It is easy to discover whether or not you “understand” a concept by trying to
explain it verbally to someone else in the course. If your listener grasps the concept easily from your explanation, you have
proven that you understand it. If not, then most likely you need to work on clarifying your own grasp of it.
It is also easy to discover whether or not you know a reaction or reaction mechanism by simply drawing the whole
thing out (with electron flow arrows) with your books and notes closed. Glancing over a list of reactions or using flash
cards isn’t enough.
Hints for doing well: (“A” students usually study organic chemistry ~2 hours per day)
1. Read the assigned text sections BEFORE class (expect about 10-15 pages per lecture).
2. Review your notes and text book before the next lecture, doing the in-chapter problems.
3. Keep a running “Reaction Sheet” of all reactions and be sure to add to it after each lecture. Rewrite the whole
“Reaction Sheet” before each exam.
4. Use my office hours immediately to eliminate confusion or falling behind.
5. To study for exams: a) review each chapter and lecture notes, b) concentrate on the end-of chapter problems, and c)
use old exams for practice (in library test file).
Most importantly: Don’t Fall Behind and Do Lots of Homework Problems. Try to have fun, enjoy the course and
develop an interest in how organic chemistry affects your daily life. Good Luck!