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Atomic Structure: The Quantum Mechanical
Model
Two models of atomic structure are in use today: the Bohr model and the
quantum mechanical model. The quantum mechanical model is based on
mathematics. Although it is more difficult to understand than the Bohr
model, it can be used to explain observations made on complex atoms.
A model is useful because it helps you understand what’s observed in
nature. It’s not unusual to have more than one model represent and help
people understand a particular topic.
The quantum mechanical model is based on quantum theory, which says
matter also has properties associated with waves. According to quantum
theory, it’s impossible to know the exact position and momentum of an
electron at the same time. This is known as the Uncertainty Principle.
The quantum mechanical model of the atom uses complex shapes
of orbitals(sometimes called electron clouds), volumes of space in which
there is likelyto be an electron. So, this model is based on probability rather
than certainty.
Four numbers, called quantum numbers, were introduced to describe the
characteristics of electrons and their orbitals:

Principal quantum number: n

Angular momentum quantum number: l

Magnetic quantum number:

Spin quantum number:
The principal quantum number
The principal quantum number n describes the average distance of the
orbital from the nucleus — and the energy of the electron in an atom. It can
have positive integer (whole number) values: 1, 2, 3, 4, and so on. The
larger the value of n, the higher the energy and the larger the orbital.
Chemists sometimes call the orbitals electron shells.
The angular momentum quantum number
The angular momentum quantum number l describes the shape of the
orbital, and the shape is limited by the principal quantum number n: The
angular momentum quantum number l can have positive integer values
from 0 to n–1. For example, if the n value is 3, three values are allowed
for l: 0, 1, and 2.
The value of l defines the shape of the orbital, and the value of n defines
the size.
Orbitals that have the same value of n but different values of l are
calledsubshells. These subshells are given different letters to help chemists
distinguish them from each other. The following table shows the letters
corresponding to the different values of l.
Letter Designations of the Subshells
Value of l (subshell)
Letter
0
s
1
p
2
d
3
f
4
g
When chemists describe one particular subshell in an atom, they can use
both the n value and the subshell letter — 2p, 3d, and so on. Normally, a
subshell value of 4 is the largest needed to describe a particular subshell. If
chemists ever need a larger value, they can create subshell numbers and
letters.
The following figure shows the shapes of the s, p, and d orbitals.
As shown in the top row of the figure (a), there are two s orbitals — one for
energy level 1 (1s) and the other for energy level 2 (2s). The s orbitals are
spherical with the nucleus at the center. Notice that the 2s orbital is larger
in diameter than the 1s orbital. In large atoms, the 1s orbital is nestled
inside the 2s, just like the 2p is nestled inside the 3p.
The second row of the figure (b) shows the shapes of the p orbitals, and
the last two rows (c) show the shapes of the d orbitals. Notice that the
shapes get progressively more complex.
The magnetic quantum number
The magnetic quantum number is designated as:
This number describes how the various orbitals are oriented in space. The
value of this number depends on the value of l. The values allowed are
integers from –l to 0 to +l. For example, if the value of l = 1 (p orbital), you
can write three values for this number: –1, 0, and +1. This means that there
are three different p subshells for a particular orbital. The subshells have
the same energy but different orientations in space.
The second row (b) of the figure shows how the p orbitals are oriented in
space. Notice that the three p orbitals correspond to magnetic quantum
number values of –1, 0, and +1, oriented along the x, y, and z axes.
The spin quantum number
The fourth and final quantum number is the spin quantum number,
designated as:
This number describes the direction the electron is spinning in a magnetic
field — either clockwise or counterclockwise. Only two values are allowed:
+1/2 or –1/2. For each subshell, there can be only two electrons, one with a
spin of +1/2 and another with a spin of –1/2