* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
Download Detecting Non-Abelian Anyons by Charging Spectroscopy
Canonical quantization wikipedia , lookup
Renormalization wikipedia , lookup
Casimir effect wikipedia , lookup
Matter wave wikipedia , lookup
X-ray photoelectron spectroscopy wikipedia , lookup
Relativistic quantum mechanics wikipedia , lookup
Identical particles wikipedia , lookup
Molecular Hamiltonian wikipedia , lookup
Ferromagnetism wikipedia , lookup
Wave–particle duality wikipedia , lookup
Particle in a box wikipedia , lookup
Electron scattering wikipedia , lookup
Introduction to gauge theory wikipedia , lookup
Elementary particle wikipedia , lookup
Theoretical and experimental justification for the Schrödinger equation wikipedia , lookup
PRL 110, 106805 (2013) week ending 8 MARCH 2013 PHYSICAL REVIEW LETTERS Detecting Non-Abelian Anyons by Charging Spectroscopy G. Ben-Shach,1 C. R. Laumann,1 I. Neder,2 A. Yacoby,1 and B. I. Halperin1 1 2 Department of Physics, Harvard University, Cambridge, Massachusetts 02138, USA Raymond and Beverly Sackler School of Physics and Astronomy, Tel-Aviv University, Tel Aviv 69978, Israel (Received 5 December 2012; published 8 March 2013) Observation of non-Abelian statistics for the e=4 quasiparticles in the ¼ 52 fractional quantum Hall state remains an outstanding experimental problem. The non-Abelian statistics are linked to the presence of additional low energy states in a system with localized quasiparticles, and, hence, an additional low temperature entropy. Recent experiments, which detect changes in the number of quasiparticles trapped in a local potential well as a function of an applied gate voltage, VG , provide a possibility for measuring this entropy, if carried out over a suitable range of temperatures, T. We present a microscopic model for quasiparticles in a potential well and study the effects of non-Abelian statistics on the charge stability diagram in the VG T plane, including broadening at finite temperature. We predict a measurable slope for the first quasiparticle charging line and an even-odd effect in the diagram, which is a signature of nonAbelian statistics. DOI: 10.1103/PhysRevLett.110.106805 PACS numbers: 73.43.Cd, 05.30.Pr, 71.10.Pm The unambiguous observation of particles obeying nonAbelian statistics remains an outstanding experimental challenge in condensed matter physics. The Moore-Read fractional quantum Hall state [1], believed to be realized at filling fraction ¼ 5=2, is one of the most promising candidate phases to exhibit such quasiparticles (QPs) [2]. The Moore-Read state is predicted to support QPs of charge e=4; for N such QPs, localized and well separated from each other, there should be a nearly degenerate set of ground states, with multiplicity 2N=21 . For temperature T larger than the splitting of these ground states, but smaller than the gap to higher excited states, this degeneracy contributes an effective entropy to the system, the non-Abelian entropy. Non-Abelian statistics predict that pairs of QPs can interact to form two distinct states, or fusion channels, f, commonly denoted as f ¼ 1, c . In a finite system, the two states have different energies, and the ground state is unique; for T below the splitting between the two, the non-Abelian entropy is lost. There are several recent theoretical proposals for techniques to observe this entropy through bulk measurement of thermodynamic and transport properties [3–6]. Recent measurements in this direction of thermoelectric response at ¼ 5=2 are encouraging [7]. These theoretical proposals assume that all QPs are well separated, such that degeneracy-lifting interactions are weak or nonexistent. However, recent local electronic charge-sensing measurements, using a single-electron transistor (SET) [8], suggest that QPs tend to trap in local potential wells due to electrostatic disorder, which may be tightly confining and contain more than one QP. In this experiment, by comparing the spacing between charging events at ¼ 5=2 with those at 7=3, the QP charge was verified to be e=4 as predicted. Confined QPs split their degeneracy through two means: Majorana exchange [9,10] present even for stationary QPs 0031-9007=13=110(10)=106805(5) and as we show here, an orbital splitting from interchange of the charged QPs, which can dominate in special cases. In this Letter, we study the charging spectra of local quasiparticle traps. Such traps may be induced by disorder or defined by gates. Their spectra reflect the QP statistics, just as electronic dot spectra reflect the spin and fermionic statistics of electrons. We show that low frequency SET charge-sensing measurements, which provide only thermally-averaged information regarding the dot spectra, are sufficient for extracting non-Abelian signatures. At low but experimentally accessible T, we predict a robust temperature evolution of the N ¼ 0–1 transition, and an evenodd effect in the evolution of the charging spectrum for several non-Abelian anyons. This effect should be visible for T below the relevant gaps to excited states for N particles, which we calculate for N ¼ 1, 2. The experiments of Venkatachalam et al. [8] measure the change in potential at the SET induced by a change VG in the potential applied to a backgate on the sample. If there is a single disorder-induced well close to the SET, the measured signal is inversely proportional to the compressibility of the well, ¼ @hNi @ , where is the QP chemical potential in the vicinity of the well. For an isolated well, the relation between VG and the change in should be linear, but the constant of proportionality is geometry-dependent, as screening depends on the local environment as well as the distance to the gate [11]. If there are several wells nearby, their signals are weighted according to the strength of their coupling to the SET; in this case, Coulomb interactions between wells also need to be taken into account. At T ¼ 0, the compressibility has a -function peak at a crossing of energy levels between N and N þ 1 QPs in a well. At finite T, the peak broadens and may shift as a function of due to entropy effects. The simplest case to consider is an isolated well at the transition from N ¼ 0 to 106805-1 Ó 2013 American Physical Society PRL 110, 106805 (2013) PHYSICAL REVIEW LETTERS N ¼ 1, or slightly more involved, from one to two. At higher occupation numbers, we give qualitative arguments for the stability diagram. We examine both circular and elliptical traps, and account for temperature effects including broadening and excited states. In our model, e=4 QPs are represented as interacting charged particles in a magnetic field, confined to the lowest Landau level (LLL), with non-Abelian statistics. The interaction is Coulomb, supplemented by an interaction VX ðrÞ due to the exchange of Majorana fermions. Qualitative Picture.—We begin with the charging diagram for Abelian particles in a well to contrast it with the non-Abelian case. For simplicity of presentation, we consider varying only the QP chemical potential, although as discussed below, local gating will be required to access the full charging spectrum. The well sits in a larger quantum Hall state containing other distant wells, which provide a reservoir for QPs. At T ¼ 0, as a function of chemical potential, a series of peaks in the compressibility appear, corresponding to individual charging events in the well. The spacing of these peaks defines the charging energy, UðNÞ. As T increases, the peak centers evolve vertically in the charging diagram (red, dashed lines in Fig. 1), until T reaches the minimum excitation energy, N , set by the excited states within the well. Above this energy, the curve deviates from a straight line due to entropic effects. The peaks broaden linearly with T for both Abelian and non-Abelian QPs. When several non-Abelian QPs occupy a tightly confining well, they uniquely fuse at low energies. This produces a distinct experimental signature-the even-odd effect. As highlighted in Ref. [4], the density dependence of the zerotemperature entropy produces a distinct signature in the inverse compressibility of bulk samples at low T. In local traps with discrete QP number, the difference in zerotemperature entropy S between adjacent number states produces a related low-T signature in the charge stability FIG. 1 (color online). Cartoon charge stability diagram, showing only peak centers (no broadening). Vertical axis is temperature T; horizontal axis is the chemical potential for charged QPs, controlled in experiment by a gate potential. Red, dashed lines are for Abelian particles. Blue, solid lines correspond to non-Abelian QPs in a tightly confining well. N is the gap to excited states for N particles and sets scale for other entropic effects. Notice even-odd effect for non-Abelian anyons. week ending 8 MARCH 2013 diagram: the slope of the charge transition line in the T plane is 1=S. The first QP placed in the well contributes SNA ¼ ln2=2 to the pffiffiffi non-Abelian entropy (kB ¼ 1), or equivalently adds a 2 degeneracy; thus, the N ¼ 0–1 transition line has slope 2= ln2 in the T plane as T ! 0. A second QP fuses uniquely with the first QP into the 1 or c channel and the non-Abelian entropy is extinguished, S ¼ ln2=2. Thus, as T increases from zero, the N ¼ 1 state becomes entropically more favorable than the N ¼ 2 state, and the transition line has slope þ2= ln2 (blue, solid lines in Fig. 1). This even-odd effect persists as the well charges: odd numbers of particles fuse into the non-Abelian -channel, while even numbers uniquely fuse into either the Abelian 1 or c channels, as long as T remains below the splitting between these two channels. If the splitting between channels is smaller than N , there exists an intermediate regime, in which the degeneracy is preserved and the non-Abelian entropy increases by ln2=2 with every additional particle, and all lines have parallel negative slopes. A similar effect for electrons due to spin degeneracy was predicted and seen in quantum dots at B ¼ 0 [12,13]. For a quantized Hall state in a strong magnetic field, however, if QPs have more than one spin state, we expect their energies to split, due to the Zeeman and/or Coulomb exchange fields, by an amount that is large compared to the temperatures of interest. Moreover, if spin-degeneracy were present, the charging lines would have a different slope than for fusion channel degeneracy because of the factor of two difference in entropy per QP. For wells far apart compared to the magnetic length, the rate, well =@ of Majorana exchange between them falls off exponentially in their separation. We, therefore, consider charging lines for temperatures T well , assumed zero for an isolated well. In this limit there is no fusion-channel splitting between wells and each independently exhibits the even-odd effect. However, the charging spectra are not completely independent due to capacitive coupling. In an experiment sensitive to multiple disorder-induced wells, the charging spectra of the wells appear overlaid with unknown offsets making the even-odd effect more difficult to observe, without first associating the various peaks to their respective wells. Experiments [8,14,15] suggest that determining such associations is possible. Equilibration.—Although QPs are locally trapped, the equilibrium model we present requires that the system explores the degenerate ground-state manifold faster than the measurement time texp of the charge-sensing experiments. This time is determined by the rate of change of the gate voltage, typically texp 0:1 s. We estimate the equilibration time due to thermal excitations as tT 104 s texp , meeting the requirement [11]. Moreover, the observed changes in the charge state of the studied well during experiments [8] imply that QPs hop freely between wells on the time scale texp . Assuming the hopping processes 106805-2 PRL 110, 106805 (2013) PHYSICAL REVIEW LETTERS have a stochastic component, they will naturally lead to braiding of QPs from different wells. Quantitative Picture.—Returning to a single well in a large bath, we present a model for calculating the charging diagram. The partition function is X Z ¼ gðNÞeðFðN;TÞNÞ ; (1) N where ¼ 1=T, the internal free energy of N-particle states in the well is FðN; TÞ, and gðNÞ ¼ 8 pffiffiffi < 2 :1 N odd (2) N even captures the non-Abelian degeneracy associated with net fusion within the well. In a well where QPs are close, such that all other fusion-degeneracies are split by energies larger than T, we take FðN; TÞ FðN; 0Þ for T N , the gap to excitations. In principle, however, for a wide well where electron-electron interactions localize the QPs further apart, an intermediate regime can exist in which the topological degeneracies are not significantly split and FðN; TÞ FðN; 0Þ TbN2 c ln2, where bc denotes the integer part, for temperatures up to the gap N . The compressibility follows from the partition function. To leading order near the N 1 to N charge transition at the critical chemical potential, N 0 FðN; 0Þ FðN 1; 0Þ, ¼ ð1 gðNÞ ðFÞ gðN1Þ e gðNÞ þ gðN1Þ eðFÞ Þ2 ; (3) where ¼ N 0 and F ¼ FðN;TÞ FðN 1;TÞ . We differentiate with respect to to find the center N 0 of the peak: max ¼ T lnðgðN 1Þ=gðNÞÞ þ F. For a tightly confining circular well at low T, for which F ¼ 0, this gives max ¼ ðT=2Þ ln2, which confirms that the charging line slopes alternate sign as a function of the parity of N. In the intermediate regime, the slope is negative for all N. The peak height decreases with T as max 1=4T, while the full-width-half-max (FWHM) increases with pffiffiffi T due to number fluctuations as FWHM 2T lnð3 þ 2 2Þ, roughly ten times as fast as the shift in position. Nevertheless, tracing the peak should be possible if measurements are sufficiently accurate. In the experimental regime of interest, N1 the charging energy UðNÞ ¼ N T, so the 0 0 peaks remain distinguishable. The key input to the above statistical model is the microcanonical low-energy spectra of fixed numbers of QPs in a well, which we now calculate for N ¼ 1, 2. One Particle.—For a particle in an elliptical harmonic well, 1 Vtrap ¼ kðx2 þ y2 Þ; 2 (4) week ending 8 MARCH 2013 where k is the spring constant, and controls the eccentricity ( ¼ 1 defines a circular trap), the level spacing is pffiffiffiffiffiffiffiffiffiffiffiffiffi pffiffiffiffi 1 ¼ k l2 B , where lB ¼ @=e B is the effective magnetic length for QPs in a magnetic field B. At finite T, this produces an internal free energy, Fð1; TÞ ¼ T lnð1 e1 =T Þ: (5) This free energy decreases weakly with T for T < 1 , only significantly correcting the linear charging curve for T 1 , as shown in Fig. 1. Two Particles.—As the fusion channel, f, of two orbiting non-Abelian anyons is conserved, the orbital dynamics may be treated separately in each f-sector. This reduces to the dynamics of Abelian anyons whose statistical angle depends on the fusion sector. For Ising anyons, 1 ¼ 0 and c ¼ =2 [16]. To model two such anyons in a well, each with charge e ¼ e=4, we write the Hamiltonian for a pair of bosons with a statistical gauge field as H¼ 2 1 X ðp~ @a~ fi e A~ i Þ2 þ Vtrap ðr~i Þ þ VI ðr~1 r~2 Þ 2m i¼1 i þ VXf ð~r1 r~2 Þ: (6) The first term contains the electromagnetic vector potential A~ i , corresponding to a uniform external B-field, as well as a statistical gauge field ðafx ; afy Þ ¼ rf2 ðy; xÞ, which binds a flux tube of strength f to each quasiparticle, and m is the effective QP mass. We project into the LLL, taking m ! 0. The coordinates in a~ i are relative to the other particle. We assume that the QPs interact via a Coulomb interaction, e2 VI ¼ 4 r , where r 0 is the electric permittivity of the material. This approximation is valid assuming that QPs do not come within lB of each other. VX is the direct energy splitting of the fusion channels due to virtual exchange of Majorana fermions. It is related to the fusion channel splitting discussed in Refs. [9,10] and should consist of an exponential decay and oscillations, each on the order of several lB . For circular wells, the behavior of Abelian anyons has been treated previously [17–20]. We summarize key results and include corrections due to eccentricity. In the symmetric gauge for harmonic traps, the centerof-mass (c.m.) and relative (REL) coordinates decouple. In the c.m. coordinate, the statistical gauge field a~ f falls out, leaving a single particle projected into the LLL in a harmonic well. For the REL coordinate, the particle is confined to a half-plane with the origin removed, and a~ f remains [18]. We change the gauge, so that a~ f ¼ 0, giving a twisted boundary condition, c REL ðr; Þ ¼ eif c REL ðr; 0Þ. The potential landscape in the half-plane is defined by strong Coulomb repulsion near the origin together with the harmonic trap, Vtrap þ VI , for VX ¼ 0. The twisted periodic boundary conditions allow only angular momenta ‘ ¼ 2n þ =, for n integer. 106805-3 PRL 110, 106805 (2013) PHYSICAL REVIEW LETTERS The REL-coordinate wave functions in the LLL have a basis given by j‘i, hzj‘i ¼ N‘ð1=2Þ z‘ ejzj 2 =4ð2l2 Þ B ; (7) where z ¼ x þ iy and N‘ is a normalization constant on the half-plane. In this basis, we can diagonalize to find the twoparticle spectrum. The potential has diagonal terms, as well as an off-diagonal term only when circular symmetry is broken [11]. Circular Well.—We assume VX ¼ 0 initially, and note that the c.m. coordinate behaves just like the single particle case with c:m: ¼ 1 . The lowest energy gap fR in the relative coordinate within a fusion channel f can be found by taking differences between adjacent ‘-states near the minimum, obtained by diagonalizing the Hamiltonian. We define the parameter r0 ¼ ðe2 =2 kÞ1=3 , the radial position of the minimum of the potential. This splitting fR oscillates with r0 at fixed magnetic field with an amplitude that decays in the large well limit, r0 lB , as fR & 121 r20 e2 l4 B ¼ 24 : 4 r50 l2 B (8) The other relevant gap for the relative coordinate is the energy difference E1 c ¼ jE10 E0c j between lowest energy states in the 1 and c channels. With VX ¼ 0, the splitting between fusion channels is an interchange effect, which follows from the allowed angular momenta in each channel; in particular, E1c behaves similarly to fR with a 4 9 e2 lB 2 4 r50 , of fR . For maximum oscillation bounded by the power law which is approximately 20% of the amplitude T < E1 c and fR , the slope of the 1–2 transition in the T plane is positive, exhibiting the even-odd effect. Clearly, intra-channel entropy washes out the effect for T > fR . As r0 varies, E1 c will oscillate in sign, and can be arbitrarily small if r0 is close to a zero-crossing. If E1 c < T < fR , the 0–1 and 1–2 charging lines are parallel with negative slope 2= ln2 [11]. Non-Abelian QPs at finite separation can exchange Majorana fermions, leading to an additional fusion channel splitting. Unlike the orbital contribution, this splitting occurs even when QPs are localized. Using a variational method to calculate this energy splitting for particles on a sphere, it was found to decay exponentially on the order of several magnetic lengths, up to a numerical prefactor of Oð1Þ [10]. VX in the Hamiltonian accounts for a splitting of this form. We do not calculate VX explicitly, but note that while it dominates the shift between fusion channel spectra in tightly confining wells, it oscillates and decays exponentially as the well widens and particle separation increases. In general, VX increases E1 c , promoting the even-odd effect over a larger T-range, and making a regime of parallel charging lines less likely. week ending 8 MARCH 2013 Anisotropic Well.—For anisotropic wells, again taking VX ¼ 0 initially, consider the relative coordinate for two QPs. Starting from the circular well where QP orbits encircle the origin in the half-plane, as the eccentricity increases, the effective potential acquires a minimum on the x-axis, at x ¼ r0 , and a saddle point on the y-axis at y ¼ r0 =1=3 . For any given > 1, the wave function becomes effectivelypffiffiffiffiffiffiffi localized near the potential minimum ffi 1 ðÞ. This is when the lowest for ðr0 =lB Þ2 > p2ffiffi3 ð1=3 1Þ energy state near the minimum has energy lower than the saddle point potential. As ! 1, ðÞ diverges as ð 1Þ1=2 , confirming that for a circular well QPs are not localized. Eccentricity breaks any accidental degeneracies which arise in the circular potential near r0 , and modifies the spectrum of the well. For low eccentricities, the degeneracy breaking can increase or decrease the orbital splitting. For large enough , the QPs are trapped at opposite ends of the well and no longer orbit each other except for quantum tunneling across the saddle point. In a saddle point tunneling model, the orbital exchange rate, R, in the large well limit is Gaussian in the well size, R 1=2 ðÞ1 cðÞðr0 =lB Þ2 , where cðÞ depends kl2 B exp½ weakly on and goes to a constant of order unity as ! 1 [11]. This expression may be obtained by estimating the potential as Harmonic near the minimum, and using a WKB-type calculation of the tunneling of a particle near a quadratic saddle point in the LLL, as in Ref. [21]. Increasing also has the effect of raising the energy of the ground state by increasing the harmonic frequency of the trap. For anisotropic wells with VX 0, the exchange effect naturally dominates the splitting at large r0 , since the exchange of neutral Majorana fermions decays exponentially while the interchange of localized charged particles in a magnetic field decays as a Gaussian. We recover the even-odd effect for T below this splitting, regardless of QP localization. Energy Estimates.—A simple model producing a charge trap is provided by considering a pointlike gate, a distance d above the two dimensional electron gas. A charge þjej on this gate produces an effective circular harmonic trap in jee j the plane with spring constant k ¼ 4 d 3 . Using r ¼ 13 for GaAs=AlGaAs quantum wells, B ¼ 3:5 T and d ¼ 100 nm, we find r0 ¼ 63 nm. The charging energy is 1.6 K, and the gap to single particle excited states in the well is 1 0:24 K, preserving the slope of 2= ln2 throughout the accessible experimental range 20 mK & T & 80 mK. The 1-channel ground state has lower energy than the c -channel by E1 c 29 mK in the absence of VX , and the intra-channel gap 1R 220 mK, above the accessible range. As r0 =lB 2:3, we expect the contribution of VX to enhance the even-odd effect. Since the calculated charging energy is larger than the energy gap for the ¼ 5=2 plateau, it is probably impossible to observe multiple transitions in a single well simply by changing the voltage 106805-4 PRL 110, 106805 (2013) PHYSICAL REVIEW LETTERS on a backgate. However, applying a voltage to a pointlike gate on top of the sample can change the depth of a well by a large amount without inducing QPs in the surrounding 5=2-state. To further enhance the even-odd effect, all energy gaps need to be increased. Increasing the charge on a point gate or reducing the setback distance d makes the confining trap tighter. Increasing the magnetic length—by lowering B while maintaining the filling fraction—increases all of the relevant splittings in a fixed trap geometry. Conclusion.—The detection of non-Abelian QPs through local charge-sensing measurements falls within realistic experimental parameters. A sensitive compressibility measurement could extract slopes reflecting the degeneracies of the ground state. Additional control over confinement potentials will allow for even more conclusive experiments. We thank B. Feldman, G. Gervais, S. Hart, V. Lahtinen, A. Stern, and V. Ventakachalam for useful discussions. G. B. supported by NSERC and FQRNT. C. R. L. supported by a Lawrence Gollub Fellowship and the NSF through a grant for ITAMP at Harvard University. I. N. supported by the Tel Aviv University Center for Nanoscience and Nanotechnology. This work was supported in part by a grant from the Microsoft Corporation, and by NSF Grants No. DMR-0906475 and No. DMR1206016. [1] G. Moore and N. Read, Nucl. Phys. B360, 362 (1991). [2] C. Nayak, S. H. Simon, A. Stern, M. Freedman, and S. Das Sarma, Rev. Mod. Phys. 80, 1083 (2008). [3] K. Yang and B. I. Halperin, Phys. Rev. B 79, 115317 (2009). [4] N. R. Cooper and A. Stern, Phys. Rev. Lett. 102, 176807 (2009). week ending 8 MARCH 2013 [5] G. Gervais and K. Yang, Phys. Rev. Lett. 105, 086801 (2010). [6] C. R. Laumann, A. W. W. Ludwig, D. A. Huse, and S. Trebst, Phys. Rev. B 85, 161301 (2012). [7] W. Chickering, J. Eisenstein, L. Pfeiffer, and K. West, arXiv:1211.3672. [8] V. Venkatachalam, A. Yacoby, L. Pfeiffer, and K. West, Nature (London) 469, 185 (2011). [9] M. Cheng, R. M. Lutchyn, V. Galitski, and S. Das Sarma, Phys. Rev. Lett. 103, 107001 (2009). [10] M. Baraban, G. Zikos, N. Bonesteel, and S. H. Simon, Phys. Rev. Lett. 103, 076801 (2009). [11] See Supplemental Material at http://link.aps.org/ supplemental/10.1103/PhysRevLett.110.106805 for additional details of some calculations and a description of the relation between the SET signal and the local incompressibility. [12] S. D. Bennett, L. Cockins, Y. Miyahara, P. Grütter, and A. A. Clerk, Phys. Rev. Lett. 104, 017203 (2010). [13] L. Cockins, Y. Miyahara, S. D. Bennett, A. A. Clerk, S. Studenikin, P. Poole, A. Sachrajda, and P. Grutter, Proc. Natl. Acad. Sci. U.S.A. 107, 9496 (2010). [14] S. Ilani, J. Martin, E. Teitelbaum, J. Smet, D. Mahalu, V. Umansky, and A. Yacoby, Nature (London) 427, 328 (2004). [15] J. Martin, S. Ilani, B. Verdene, J. Smet, V. Umansky, D. Mahalu, D. Schuh, G. Abstreiter, and A. Yacoby, Science 305, 980 (2004). [16] P. H. Bonderson, Ph.D. thesis, CalTech, 2007. [17] N. Sivan and S. Levit, Phys. Rev. B 46, 3953 (1992). [18] X. Wen, Quantum Field Theory of Many-Body Systems: From the Origin of Sound to an Origin of Light and Electrons (Oxford University, New York, 2004). [19] M. D. Johnson and G. S. Canright, Phys. Rev. B 41, 6870 (1990). [20] A. Stern, B. Rosenow, R. Ilan, and B. I. Halperin, Phys. Rev. B 82, 085321 (2010). [21] H. A. Fertig and B. I. Halperin, Phys. Rev. B 36, 7969 (1987). 106805-5