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General Physics (PHY 2140) Lecture 31 ¾ Modern Physics 9Quantum Physics 9Wave function 9Uncertainty relation http://www.physics.wayne.edu/~apetrov/PHY2140/ Chapter 27 11/19/2003 1 If you want to know your progress so far, please send me an email request at [email protected] 11/19/2003 2 Lightning Review Last lecture: 1. Quantum physics 9 Photons and E/M waves 9 The wave properties of particles λmin = ∆λ = hc e ( ∆V ) h (1 − cos θ ) me c Review Problem: Cathode rays are beams of electrons, but the electrons are not deflected downward by gravity because 1. the effect of gravity on electrons is negligible. 2. the electrons go so fast there’s no time to fall. 3. of air resistance. 4. the electrons are quantum particles and not classical particles. 5. the electric charge prevents electrons from feeling gravity. 6. other 11/19/2003 3 QUICK QUIZ 1 An x-ray photon is scattered by an electron. The frequency of the scattered photon relative to that of the incident photon (a) increases, (b) decreases, or (c) remains the same. (b). Some energy is transferred to the electron in the scattering process. Therefore, the scattered photon must have less energy (and hence, lower frequency) than the incident photon. 11/19/2003 4 27.9 Wave Properties of Particles In 1924, Louis de Broglie postulated that because photons have wave and particle characteristics, perhaps all forms of matter have both properties For instance, for a photon: E = hf = hc λ thus E hc h p= = = c cλ λ or h λ= p De Broglie suggested that this formula is true for any particle! Thus, the frequency and wavelength of matter waves can be determined. I.e. de Broglie wavelength of a particle is h λ= mv 11/19/2003 5 Wave Properties of Particles The frequency of matter waves can also be determined De Broglie postulated that all particles satisfy Einstein’s relation E = hf Or, in other words, E ƒ= h 11/19/2003 6 The Davisson-Germer Experiment They scattered low-energy electrons from a nickel target They followed this with extensive diffraction measurements from various materials The wavelength of the electrons calculated from the diffraction data agreed with the expected de Broglie wavelength This confirmed the wave nature of electrons Other experimenters have confirmed the wave nature of other particles 11/19/2003 7 Problem: the wavelength of a proton Calculate the de Broglie wavelength for a proton (mp=1.67x10-27 kg ) moving with a speed of 1.00 x 107 m/s. 11/19/2003 8 Calculate the de Broglie wavelength for a proton (mp=1.67x10-27 kg ) moving with a speed of 1.00 x 107 m/s. Given: Given the velocity and a mass of the proton we can compute its wavelength h λp = mpv v = 1.0 x 107m/s Or numerically, Find: λp = ? 11/19/2003 6.63 ×10 J ⋅ s ) ( = (1.67 ×10 kg )(1.00 ×10 −34 λps −31 7 ms ) = 3.97 ×10−14 m 9 QUICK QUIZ 2 A non-relativistic electron and a non-relativistic proton are moving and have the same de Broglie wavelength. Which of the following are also the same for the two particles: (a) speed, (b) kinetic energy, (c) momentum, (d) frequency? (c). Two particles with the same de Broglie wavelength will have the same momentum p = mv. If the electron and proton have the same momentum, they cannot have the same speed because of the difference in their masses. For the same reason, remembering that KE = p2/2m, they cannot have the same kinetic energy. Because the kinetic energy is the only type of energy an isolated particle can have, and we have argued that the particles have different energies, Equation 27.15 tells us that the particles do not have the same frequency. 11/19/2003 10 The Electron Microscope The electron microscope depends on the wave characteristics of electrons Microscopes can only resolve details that are slightly smaller than the wavelength of the radiation used to illuminate the object The electrons can be accelerated to high energies and have small wavelengths 11/19/2003 11 27.10 The Wave Function In 1926 Schrödinger proposed a wave equation that describes the manner in which matter waves change in space and time Schrödinger’s wave equation is a key element in quantum mechanics ∆Ψ i = HΨ ∆t Schrödinger’s wave equation is generally solved for the wave function, Ψ 11/19/2003 12 The Wave Function The wave function depends on the particle’s position and the time The value of |Ψ|2 at some location at a given time is proportional to the probability of finding the particle at that location at that time 11/19/2003 13 27.11 The Uncertainty Principle When measurements are made, the experimenter is always faced with experimental uncertainties in the measurements 11/19/2003 Classical mechanics offers no fundamental barrier to ultimate refinements in measurements Classical mechanics would allow for measurements with arbitrarily small uncertainties 14 The Uncertainty Principle Quantum mechanics predicts that a barrier to measurements with ultimately small uncertainties does exist In 1927 Heisenberg introduced the uncertainty principle If a measurement of position of a particle is made with precision ∆x and a simultaneous measurement of linear momentum is made with precision ∆p, then the product of the two uncertainties can never be smaller than h/4π 11/19/2003 15 The Uncertainty Principle Mathematically, h ∆x∆p x ≥ 4π It is physically impossible to measure simultaneously the exact position and the exact linear momentum of a particle Another form of the principle deals with energy and time: h ∆E∆t ≥ 4π 11/19/2003 16 Thought Experiment – the Uncertainty Principle A thought experiment for viewing an electron with a powerful microscope In order to see the electron, at least one photon must bounce off it During this interaction, momentum is transferred from the photon to the electron Therefore, the light that allows you to accurately locate the electron changes the momentum of the electron 11/19/2003 17 Problem: macroscopic uncertainty A 50.0-g ball moves at 30.0 m/s. If its speed is measured to an accuracy of 0.10%, what is the minimum uncertainty in its position? 11/19/2003 18 A 50.0-g ball moves at 30.0 m/s. If its speed is measured to an accuracy of 0.10%, what is the minimum uncertainty in its position? Given: v = 30 m/s δv = 0.10% m = 50.0 g Notice that the ball is non-relativistic. Thus, p = mv, and uncertainty in measuring momentum is ∆p = m ( ∆v ) = m (δ v ⋅ v ) ( )( ) = 50.0 ×10−2 kg 1.0 ×10−3 ⋅ 30 m s = 1.5 ×10−2 kg ⋅ m s Thus, uncertainty relation implies Find: δx = ? 11/19/2003 6.63 ×10−24 J ⋅ s h −32 ∆x ≥ = = 3.5 × 10 m −3 4π ( ∆p ) 4π 1.5 ×10 kg ⋅ m s ( ) 19 Problem: Macroscopic measurement A 0.50-kg block rests on the icy surface of a frozen pond, which we can assume to be frictionless. If the location of the block is measured to a precision of 0.50 cm, what speed must the block acquire because of the measurement process? 11/19/2003 20