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Significant Figures The Numbers Are Speaking to Me 5.689 cm 6.02 x 1023 bananas 45,000 L Significant Figures Numbers give two pieces of information • The numerical value • The degree of certainty (more certainty = more digits) Example: 5g 5 g measured to the ones place (could be between 4.5 g and 5.5 g) 5.000g 5 g measured to the thousandths place (could be between 4.9995 g and 5.0005 g) Measurement Measure as far as you can be certain and then estimate one place further We are certain that the reading is between 30 and 40oC. 3_ oC We estimate that it is a little less than half way. 34oC 50 40 30 20 Decimal place depends on instrument used Measure (in cm) to the correct number of significant figures. 5 6 7 8 7 8 6.83 cm 5 6 6.8 cm We read the thermometer at the right as 34oC. It is marked to the tens place, so we estimate to the ones. 50 40 How about now? 34.3oC (marked to ones, estimate tenths) 30 How about now? 40.0oC (marked to ones, estimate tenths) 20 Numbers Significant does not mean important. Significant means measured. Rules 1) Non-zero numbers are significant. 95.357 g 5 SF 84.1 mL 3 SF 7 kg 1 SF 2) Zeroes between significant figures are significant. 308 m 3 SF 1.000004 g 7 SF 400.02 L 5 SF 3) Zeroes used for spacing are NOT significant. Initial Zeros 0.0000567 g 3 SF First Measured Number Zeros Holding Decimal Place Purely Decorative Final Zeroes 150 Last Measured Number 2 SF Zero Holding Decimal Place 1,000,730,000 Zeros Between Sigfigs 6 SF Zeros Holding Decimal Place 4) Final zeroes after a decimal point are significant. 7.300 4 SF 4.0 2 SF 150.00 5 SF Zero between Sigfigs Final Zeroes after Decimal 5) Zeroes between a sigfig and a decimal point are significant. 150 2 SF 150. 3 SF Lazy Principle – if it doesn’t change the mathematical value, then it must have another purpose 6) Exact numbers (not measured) DO NOT AFFECT sigfigs. Counting 41 cars 23 students 45 tons of cars infinite SF (Ø) infinite SF (Ø) 2 SF Conversions (by definition) 1 yard = 3 feet infinite SF (Ø) 100 cm = 1 m infinite SF (Ø) Practice 456.01 mL 9,002 g 4,500 m 0.05 mg 25 lbs 17 pencils 0.000410 mol 4,000. yd 5 SF 4 SF 2 SF 1 SF 2 SF infinite SF (Ø) 3 SF 4 SF Scientific Notation 4.975 x 1041 m Measured Digits Decimal Place The same as: 497,500,000,000,000,000,000,000,000,000,000,000,000,000 4 SF Only the measured digits affect sigfigs.