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Physics 30 Unit 4 Review The Nature of Matter and Radioactivity The Nature of Matter Atomic Theories: indivisible part of The Greeks: The atom is the smallest, ____________ an element that can still be called an element. Thomson: negative •Discovered that the electron has a _____________ charge charge to mass and also found the ____________________ ratio of the electron. cathode ray •He performed his experiments with ____________________ tubes. raisin bun •His model of the atom is called the _________________ model. Formulas: CRT x x x x x x Fm = Fc 2 mv qvB = r q v = m Br Remember: F = ma 2 v ac= r mv2 Fc= r Mass Spectrometer: Velocity Selector Perpendicular Electric and Magnetic fields + Charged particles X X X 𝐸=𝐸 1 𝑉𝑞 = 𝑚𝑣 2 2 X X X X X X X X X X X X _ If accelerated by a potential difference then the formulas are: Ion Separator Just a magnetic or electric field If the particles travel through undeflected, then the formulas are: 𝐹𝑚 = 𝐹𝑒 𝑞𝑣𝐵 = 𝐸 𝑞 Formulas are: 𝐹𝑚 = 𝐹𝑐 𝑚𝑣 2 𝑞𝑣𝐵 = 𝑟 Properties of Cathode Rays: •Cathode rays have the same properties no matter which metal type of ____________ is used for the cathode. straight •Cathode rays travel in ______________ lines. electric E •Cathode rays can be bent in both _________________ magnetic B and ___________________ fields. •Cathode rays can cause chemical reactions similar to light _______________ (develop photographic film). •Cathode rays leave a vapour trail when they pass through gas chamber bubble chamber a _________________ as well as a ___________________. electrons •Cathode rays are ________________. Thomson Example: A negatively charged particle is travelling with a speed of 1.43x106 m/s through a magnetic field of 2.50x10-3 T. The particle follows a curved path of radius 3.25x10-3 m. What is the charge to mass ratio of this particle? Fm = Fc mv2 qvB = r 6 m/s q v 1.43x10 = m = Br (2.5x10-3 T) (3.25x10-3 m) = 1.76x1011 C/kg Millikan’s Oil Drop Experiment: negatively charged oil drops between •He balanced ______________ electric plates. When the particles were suspended, the electric gravitational force. ____________ force equaled the _____________ + plate Fe - Oil drop Fg - plate Millikan’s Oil Drop Experiment (Formulas): •If the oil drop is suspended: •If the oil drop accelerates up: Fe = Fg E q = mg •If the oil drop moves with a constant speed up or down: Fe = Fg E q = mg Fe = Fg + Fa E q = mg + ma •If the oil drop accelerates down: Fe = Fg - Fa E q = mg - ma Millikan’s Oil Drop Experiment (Graphing): •Oil drops of different weights are suspended between electric plates requiring different electric field strengths Millikan’s Oil Drop Experiment (Graphing): Line of best fit should: • Average the data points the best • Go through as many points as possible • You can leave some points above and below the line. Weight of Oil Drops (x10?? N) Slope Calculation: Electric Field Strength (x10?? N/C) Fe = Fg E q = mg mg = q = eE • Try not to choose data points • Choose points as far apart as possible Rutherford’s Scattering Experiment: Rutherford’s Planetary Model: scattering •Rutherford performed a ______________ experiment. alpha •____________ particles were aimed at a layer of thin gold. photographic film. •The particles were detected by ______________ •He concluded that the nucleus is: tiny •Very ____________ positive protons •Contains ________________ charges called __________. electrons orbit the nucleus like planets orbit the sun. •__________ Rutherford’s Planetary Model (Formulas): electric •There is an _______________ force between the negative positive __________electrons and __________protons. This is because opposite ______________ charges attract. •Since this force acts inwardly as the electron travels around centripetal force. the nucleus, it is also equal to the ____________ Example: Calculate the speed of the electron as it orbits the nucleus of a hydrogen atom if it’s orbital radius is 5.29x10-7m. Fe = Fc kqq = mv2 r r2 9 )(1.6 × 10−19 )(1.6 × 10−19 ) (8.99 × 10 v= = 2.19x104m/s −7 −31 5.29 × 10 (9.11 × 10 ) Maxwell’s Problem: •According to Maxwell, any accelerating charge produces light (c) _____________ which travels at the speed of ___________. EMR •This can be shown with symbols: ∆ Ε Δ𝐵 ∆ Ε •Since the electron in an atom is traveling in a circular path (it’s direction _____________ is always changing) it can be considered to be accelerating even though it’s speed is constant. •The electrons within atoms are accelerating charged particles. EMR They should give off _____________ (a form of energy) as they travel. They should thus lose energy and collapse into the atom. Bohr Model of the Atom: •Within certain orbitals (a certain distance from the nucleus), EMR electrons are free to travel without giving off any ___________. energy •These orbitals are also called ___________ levels. The lowest ground energy level (closest to the nucleus) is called a ______________ state. The energy required to free the electron from the atom ionization is called the _______________ energy. EMR •When electrons drop energy levels, they give off ___________. When electrons move up energy levels, they have either been hit by an ___________ electron or an ______________. EMR photon Formulas used with the Bohr Model: ℎ𝑖𝑡 𝑏𝑦 𝑎𝑛 𝑒 − or photon 𝐸𝑀𝑅 𝑔𝑖𝑣𝑒𝑛 𝑜𝑓𝑓 positive negative •Energy levels can be written as ____________ or ____________ numbers. subtract •_____________ the energy levels to find the energy difference between orbitals. EMR Formulas 𝜀= ℎ𝑐 𝜆 𝜀 = ℎ𝑓 e- Formulas 𝜀 = 𝑉𝑞 1 𝜀 = m𝑣 2 2 Hydrogen Atom: •If the electron drops to the first (lowest) orbital, then ultraviolet _______________ is most likely released. •If the electron drops to the second orbital, then visible light _______________ is most likely released. •If the electron drops to the third orbital, then infrared _______________ is most likely released. Continuous Spectra: •Light from a hot glowing solid (like an incandescent light bulb) will produce a continuous spectrum in the visible region. Prism White light Diffraction Grating 𝑟 o y g b i v White light 𝑟 v 𝑣 r Smaller wavelengths (blue) light is refracted more. Longer wavelengths (red) light is diffracted more. Blue bends more. Think of the sky – it’s blue because the red light light is diffracted more. Emmission Spectra: electrons •Light from an excited elemental gas (excited by ___________ passing through it) will emit certain wavelengths of light. If this bright light is passed through a diffraction grating, a ______________ line pattern will be produced. Each element has a unique _____________ pattern. Absorption Spectra: •When light passes through a cool elemental gas, certain wavelengths of light are absorbed. These will appear as ______________ dark _________ lines on a spectrum. Example: What is the wavelength of EMR released when an electron within an atom drops from an energy level of 12.0 eV to 8.5 eV? E= 12.0 eV – 8.5 eV = 3.5 eV 𝐸= ℎ𝑐 𝜆 𝜆= ℎ𝑐 𝐸 (4.14 × 10−15 )(3.00 × 108 ) 𝜆= 3.5𝑒𝑉 𝜆 = 3.55 × 10−7 m Compton Effect: •He performed a scattering experiment where EMR photons (___________) were fired at electrons. He found that the electrons moved off with speed after the collision and that the longer scattered x-rays had a ______________ wavelength. •He concluded that EMR can have a mass property: momentum ___________________. •Momentum formula for masses: •Momentum formula for EMR: •The biggest angle an x-ray can be scattered is straight back 180o _________ 𝑝 = 𝑚𝑣 𝑝= ℎ 𝜆 Δ𝜆 = ℎ (1 𝑚𝑐 𝐸 = 𝑝𝑐 − 𝑐𝑜𝑠𝜃) Example: An X-Ray of wavelength 0.0500 nm scatters at an angle of 300. Calculate the wavelength of the scattered photon. 30o Δ𝜆 = ℎ (1 𝑚𝑐 Δ𝜆 = 6.63×10−34 (9.11×10−31 )(3.00×108 ) − 𝑐𝑜𝑠𝜃) (1 − 𝑐𝑜𝑠30) Δ𝜆 = 3.25 × 10−13 m 𝜆𝑓 = 𝜆𝑖 + Δ𝜆 = 0.0500 × 10−9 + 3.25× 10−13 = 5.03× 10−11 𝑚 de Broglie Wavelength: •Proposed that masses can have an EMR property: wavelength ___________. •Objects with mass and speed travel with a ______________. wavelength The effect is only detectable for very small masses traveling at high speed. The formula below should be given to you on a diploma exam. 𝑝𝑚𝑎𝑠𝑠𝑒𝑠 = 𝑝𝐸𝑀𝑅 𝑚𝑣 = 𝜆= ℎ 𝜆 6.63 × 10−34 ℎ 𝑚𝑣 𝑚𝑎𝑠𝑠 𝑎𝑛𝑑 𝑠𝑝𝑒𝑒𝑑 𝑜𝑓 𝑡ℎ𝑒 𝑝𝑎𝑟𝑡𝑖𝑐𝑙𝑒 Example: Calculate the wavelength of an electron that has been accelerated through a potential difference of 2 000 V using the de Broglie wavelength formula 𝜆 = ℎ 𝑚𝑣 𝜆= 6.63×10−34 9.11×10−31 (??) 𝜀= 𝜀 1 𝑚𝑣 2 = 𝑉𝑞 2 𝜆 = 2.75 × 10−11 𝑚 𝑣= 𝑣= 2𝑉𝑞 𝑚 2(2000𝑉)(1.6 × 10−19 ) 9.11 × 10−31 𝑣 = 2.65 × 107 Electron Orbitals: •Electrons really travel in a ____________ pattern as they wave travel around the nucleus of the atom. •There must be a whole number multiple of wavelengths as nucleus the electron orbits the ___________. 𝑛𝜆 = 2𝜋𝑟 You do not have to memorize this formula for the diploma. The Standard Model of the Atom: •Particles responsible for Forces are called boson ______________ particles. Boson •______________ particles responsible for the following Forces (listed from strongest to weakest): •The strong nuclear force: __________________ gluons •The electromagnetic force: __________________ photons •The weak nuclear force: __________________ W+ W- Zo graviton •The gravitational force: __________________ (undetected) The Standard Model of the Atom: •Particles that make up matter are called ______________. fermions •Very small particles that are elementary particles are leptons called ___________________. The electron and it’s leptons neutrino are _________________. •Larger particles, like neutrons and protons are called hadrons ___________________. They are made up of quarks ___________________. •_____________ are made up of 2 quarks. Mesons •_____________ baryons are made up of 3 quarks. The Standard Model of the Atom: uud •Protons are made up of the following quarks: _____________ 1 n 0 1 + p 1 0𝛽 -1 + 𝜐 udd •neutrons are made up of the following quarks: _____________ 1 p 1 1 + n 0 0𝛽 1 + 𝜐 Radioactivity: half •Particles that undergo radioactive decay, lose __________ their mass over a certain period of time. This time is called half life _________________. •During this process, a radioactive element changes into another element, giving off particles or EMR. This is called __________________. transmutation •Formulas: Graphing Radioactivity: Bq •Radioactivity has lots of different units: __________, Bq/s rads decays / s ___________, ____________, ______________ to list a few. Terms: neutron or a proton Nucleon: __________________________ number of protons (bottom number) Atomic Number: _______________ The atomic number identifies the element. number of protons and neutrons (top number) Mass Number: _______________ the sum of the top numbers on both Conservation of Nucleons: _____________________________ ___________________________________________________ sides of an equation must be equal. the sum of the bottom numbers on Conservation of Charge: _____________________________ ___________________________________________________ both sides of an equation must be equal. 3 Types of Radioactivity: 1. Beta Decay: assume beta negative for just “beta decay” Beta Negative Decay: is an _________________. electron 0𝛽 𝑒-1 -1 symbols are: __________________ 𝜐 an antin-eutrino is also released _________. Example: Write the decay equation for carbon 14 emitting a beta negative particle. 14 c 6 14 + N 7 0𝛽 -1 + 𝜐 3 Types of Radioactivity: Beta Positive Decay: is an _____________________________. antimater electron (positron) 0 1𝛽 symbols are: __________________ 𝜐 a neutrino is also released __________. Example: Write the decay equation for carbon 14 emitting a beta positive particle. 14 c 6 14 + B 5 0𝛽 1 + 𝜐 3 Types of Radioactivity: 2. Alpha decay: is the nucleus of a ____________ helium atom. 4 2+ 4 2+ Symbols are: ___________________ 2𝛼 2𝐻𝑒 Example: Write the decay equation for nitrogen 15 emitting an alpha particle. 15 7𝑁 4 2+ 2𝛼 + 11 5𝐵 3 Types of Radioactivity: 3. Gamma decay: is a high energy, high ____________, frequency small wavelength ______________ EMR photon. 0 𝛾 Symbol is: __________________ 0𝛾 Example: Write the decay equation for cobalt 56 emitting a gamma ray. 56 27𝐶𝑜 𝛾 + 56 27𝐶𝑜 Penetrating Ability: In order of increasing ability to penetrate objects: thick paper or cardboard Alpha particles: ___________________ Beta particles: ___________________ thin metal lead (dense metal) Gamma Rays: __________________________ Ability to Ionize (danger / risk): In order of increasing risk: higher energy due to increased speed Beta particles: __________________________ higher energy due to larger mass Alpha particles: __________________________ higher energy due to larger frequency Gamma Rays: __________________________ or smaller wavelength Binding Energy: neutrons of an atom to hold •Is the energy exerted by the ___________ the ______________ charged protons tightly in the nucleus. positively •Some mass of the ___________ neutrons is converted into energy. •Formula: Example: The mass of a lithium-7 nucleus is 7.015989 u. What’s the binding energy? 7 Li 3 3𝑝+ = 3(1.6726 × 10−27 𝑘𝑔) 4𝑛 = 4(1.6749 × 10−27 𝑘𝑔) 1.17174 × 10−26 𝑘𝑔 7.015989𝑢 (1.66 × 10−27 𝑘𝑔/𝑢) = 1.16465417× 10−26 𝑘𝑔 1.17174 × 10−26 − 1.16465417 × 10−26 = 7.08583 × 10−29 𝐸 = 𝑚𝑐 2 = 7.08585 × 10−29 3.00 × 108 2 = 6.38 × 10−12 𝐽 Nuclear Fission: splitting •Is the ____________ of an atom into other elements. nuclear •Is the process used in ________________ power plants. •Formula: Example: Calculate the energy produced in the following fission reaction. 235 1 U + 0n 235 140 U=3.9029x10-25 kg 1 -27 0n =1.6749x10 kg 140 Xe=2.3234x10-25 kg 94 Sr =1.5595x10-25 kg Xe + 94 Sr 1 + 2 0n Mass of reactants 3.919649 × 10−25 Mass of products 3.916398 × 10−25 Mass difference 3.251 × 10−28 Binding Energy E=mc2 3.251 × 10−28 (3.00 × 108 )2 2.9259 × 10−11 𝐽 Nuclear Fusion: •Is the ____________ fusing of simpler atoms into heavier elements. sun •Is the process going on inside the ________________. •Formula: Example: Calculate the energy produced in the following fusion reaction. 2 1 3 H + 1H 4 2 2 -27 kg 1 H=3.4444x10 1 -27 kg 0n =1.6749x10 4 He =6.6463x10-27 kg 3 H 1 =5.0082x10-27 kg 1 He + 0n Mass of reactants 8.4526 × 10−27 Mass of products 8.3212 × 10−27 Mass difference 1.314 × 10−28 Binding Energy E=mc2 1.314 × 10−28 (3.00 × 108 )2 1.1826 × 10−11 𝐽