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Name: ______________________________________ Quantum Number Practice Worksheet Date: _______________ 1. Summarize: The principal quantum number, n, can have the values of: ___ ___ ___ ___ ___, etc. The angular momentum quantum number, l, can have integer values from ______ to ______. The magnetic quantum number, ml, can have integer values from _____ to _____. 2. When n = 3, l can have values of ___________________________. For the 3d sublevel, l has a value of ___. When n = 4, l can have values of ___________________________. For the 4p sublevel, l has a value of ___. When n = 2, l can have values of ___________________________. For the 2s sublevel, l has a value of ___ 3. Summarize: orbital value of l s p d f 4. There are five 4d orbitals. List the quantum numbers for each orbital. n l ml 5. Rank the following orbitals in order of increasing energy: 3s, 2s, 2p, 4s, 3p, 1s, and 3d. 6. How many orbitals in an atom can have the following quantum number or designation? a) 3p e) 5d b) 4p f) 5f c) 4px g) n=5 d) 6d h) 7s 7. Answer the following questions: a) The quantum number n describes the _____________ of an atomic orbital. b) The shape of an atomic orbital is given by the quantum number ____. c) The maximum number of orbitals that may be associated with the set of quantum numbers n=4 and l =3 is ____. d) The maximum number of orbitals that may be associated with the quantum number set n=3, l =2, and ml = -2 is ___. e) When n=5, the possible values of l are ________. f) The maximum number of orbitals that can be assigned to the n=4 shell is ____. Name: ______________________________________ Quantum Number Practice Worksheet Date: _______________ 8. (a) For n = 4, what are the possible values of l ? (b) For l = 3, what are the possible values of ml ? 9. Give the values of n, l , ml (a) for each orbital in the 4f sublevel, (b) for each orbital in the n = 2 shell. 10. Which of the following sets of quantum numbers are allowed for an electron in an orbital of a hydrogen atom: (a) n = 1, l = 1, ml = 0 (b) n = 3, l = 0, ml = 0 (c) n = 4, l = 1, ml = -1 (d) n = 2, l = 1, ml = 2 Write the designation for the sublevel to which the orbital belongs. 11. What is the maximum number of electrons that can occupy each of the following subshells: (a) 3d (b) 4s (c) 2p (d) 5f 12. What is the maximum number of electrons in an atom that can have the following quantum numbers: (a) n = 3 (b) n = 4, l = 2 (c) n = 4, l = 3, ml = 2 (d) n = 2, l = 1, ml = 0, ms = - ½ 13. The quantum numbers listed below are for four different electrons in the same atom. Arrange them in order of increasing energy. Indicate whether any two have the same energy. (a) n = 4, l = 0, ml = 0, ms = ½ (b) n = 3, l = 2, ml = 1, ms = ½ (c) n = 3, l = 2, ml = -2, ms = -½ (d) n = 3, l = 1, ml = 1, ms = -½