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Unit 6: Chemical Equations and Reactions Chemistry 1-2 Mr. Chumbley Describing Chemical Reactions Chapter 8 – Section 1 EQ: How can chemical reactions be identified and described? Chemical Reactions A chemical reaction is a process by which one or more substances change to produce one or more different substances A chemical equation is a representation of a chemical reaction that uses symbols to show the relationship between the reactants and products (NH4 )2 Cr2 O7 s → N2 g + Cr2 O3 s + 4H2 O(g) Indicators of a Chemical Reaction While absolute proof of a chemical change can only be found through chemical analysis, there are certain indicators a chemical reaction has occurred Release of energy as heat and light Color change Production of a gas Formation of a precipitate A precipitate is a solid that is produced as a result of a chemical reaction in a solution Chemical Equations Chemical criteria: equations must satisfy certain The equation must represent all known facts The equation must contain the correct formulas for the reactants and the products The law of conservation of mass must be satisfied Word Equations A word equation is an equation in which the reactants and products in a chemical reaction are represented with words methane + oxygen → carbon dioxide + water An arrow in an equation is read as “reacts to yield” or “yields” The above equation would be read as: Methane and oxygen react to yield carbon dioxide and water Formula Equations A formula equation represents the reactants and products of a chemical reaction by their symbols and formulas CH4 (𝑔) + O2 (𝑔) → CO2 (𝑔) + H2 O(𝑔) The reaction would be read the same as in the word equation: Methane and oxygen react to yield carbon dioxide and water Neither the word equation nor the formula equation give information about the amounts of reactants or products Symbols Used in Chemical Equations (p. 252) “yields”; indicates a reaction indicates a reversible reaction (s) solid state ↓ (l) liquid state (aq) (g) gas state ∆ heat pressure MnO2 reaction requires heat reaction requires pressure catalyst used to alter reaction rate precipitate formed as product in aqueous solution ↑ gas formed as product 0˚C specific temperature at which reaction was carried out 2 atm specific pressure at which reaction was carried out Diatomic Elements (p. 249) Some elements do not exist as individual atoms in nature. These non-metals are found in elemental form as two atoms bonded together Element Molecular Formula State of Matter Hydrogen H2 Gas Nitrogen N2 Gas Oxygen O2 Gas Fluorine F2 Gas Chlorine Cl2 Gas Bromine Br2 Liquid Iodine I2 Liquid Sample Problem A Write word and formula equations for the chemical reaction that occurs when solid sodium oxide is added to water at room temperature and forms sodium hydroxide (dissolved in water) 𝑠𝑜𝑑𝑖𝑢𝑚 𝑜𝑥𝑖𝑑𝑒 + 𝑤𝑎𝑡𝑒𝑟 Na2 O(𝑠) + H2 O(𝑙) 𝑠𝑜𝑑𝑖𝑢𝑚 ℎ𝑦𝑑𝑟𝑜𝑥𝑖𝑑𝑒 NaOH(𝑎𝑞) Homework! p. 260 #2 P. 277 #11 & 12 Balanced Chemical Equations EQ: How can chemical equations satisfy the law of conservation of mass? The Mole Because atoms are so small, they are very difficult to count and measure A mole is the amount of a substance that contains as many particles as there are atoms in exactly 12g of carbon-12 A mole is abbreviated as mol The mole is the base unit of amount in SI Avogadro’s Number Avogadro’s number is the number of particles in exactly one mole of a pure substance This number has been experimentally determined to be 6.022 141 79 × 1023 We will define Avogadro’s number as 6.022 × 1023 This number is named after 19th century scientist, Amedeo Avogadro, who did not actually determine this number Balanced Equations While a formula equations describe the formulas in a reaction, they don’t necessarily describe the correct amounts A balanced equation has all of the chemical formulas in the correct ratios to fully satisfy the law of conservation of mass A coefficient is a small whole number that appears in front of a formula in a chemical equation Balancing Equations CH4 𝑔 + O2 𝑔 → CO2 (𝑔) + H2 O(𝑔) Balancing Equations Lithium metal and aluminum sulfate solution react to yield a lithium sulfate solution and aluminum metal. 𝑙𝑖𝑡ℎ𝑖𝑢𝑚 + 𝑎𝑙𝑢𝑚𝑖𝑛𝑢𝑚 𝑠𝑢𝑙𝑓𝑎𝑡𝑒 → 𝑙𝑖𝑡ℎ𝑖𝑢𝑚 𝑠𝑢𝑙𝑓𝑎𝑡𝑒 + 𝑎𝑙𝑢𝑚𝑖𝑛𝑢𝑚 Li 𝑠 + Al2 SO4 3 𝑎𝑞 → Li2 SO4 (𝑎𝑞) + Al(𝑠) Reflection!!! For MONDAY… Balance the equations from the Describing Chemical Reactions 2 worksheet Section 2: Types of Chemical Reactions EQ: How can chemical equations be used to classify chemical reactions? Synthesis Reaction In a synthesis reaction two or more substances combine to form a new compound 2 Mg 𝑠 + O2 𝑔 NH3 𝑔 + H2 O 𝑙 2MgO(𝑠) pressure NH4 OH(𝑎𝑞) Decomposition Reaction In a decomposition reaction a single compound breaks down into two or more simpler substances CaCO3 𝑠 ∆ CaO 𝑠 + CO2 (𝑔) Single Displacement Reaction In a single displacement one element replaces a similar element in a compound 2Al 𝑠 + 3Pb NO3 2 𝑎𝑞 3Pb(𝑠) + Al NO3 3 (𝑎𝑞) Double Displacement Reaction In a double displacement the ions of two compounds exchange places in an aqueous solution to form two new compounds 2KI 𝑎𝑞 + Pb NO3 2 𝑎𝑞 PbI2 𝑠 + 2KNO3 (𝑎𝑞) Combustion Reaction A combustion reaction is the oxidation reaction of an element or compound in which energy as heat is released C3 H8 𝑔 + 5 O2 𝑔 3 CO2 𝑔 + 4 H2 O (𝑔)