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Chemistry Teachable Tidbit Summer Institute Randy, Brandi, Casey, Matt, Teresa Teaching Tidbit Context Our audience consists students in the second semester of a general chemistry course. Typical Units Unit 1 – Intermolecular forces and Solutions Unit 2 – Kinetics and Equilibrium Unit 3 – Thermodynamics Learning Goal Students will understand and appreciate the relationship between kinetics and equilibrium. Learning Objectives 1. Generate a model that describes a dynamic equilibrium system 2. Compare and contrast concentration versus time graphs for an equilibrium system 3. Generate an equilibrium expression for a reaction given the rate law expressions 4. Relate the individual rate constants to the equilibrium constant expression Concentration Change over time Reaction: A t=0 min t=10 min B t=20 min Imagine you are in your chemistry lab completing an experiment. Your reaction has run for 20 minutes and you have the above data. Each beaker above shows the concentrations of A and B. As a Group 1. Draw a correctly formatted graph showing the change in concentration of A and B over time. 2. Predict: Draw the reaction beaker at t = 30 minutes. Concentration Change over time Reaction: A t=0 min t=10 min t=20 min B t=30 min t=100 min You then allow your reaction to go for up to 100 minutes. Modify your graph to include the new data. Discuss the change of concentration of A and B over time. Concentration Change over time Reaction: A t=0 min t=10 min t=20 min B t=30 min t=100 min As the reaction progresses, focus on the black outlined molecule converting between A and B. 4. Discuss within your group whether the reaction has stopped at 20 minutes. At 100 minutes? Dynamic Equilibrium At equilibrium, which of the following statements is true about the rates? Reaction: A A. B. C. D. B Rate of forward rxn > Rate of reverse rxn Rate of forward rxn = Rate of reverse rxn Rate of forward rxn < Rate of reverse rxn Rate of forward rxn =0, rate of reverse rxn = 0 SUMMATIVE ASSESSMENT #1 (High level HOC) Assessing Learning Objective 1 - Generate a model that describes a dynamic equilibrium system 1. Consider the kinetic data produced by monitoring the reversible conversion of Molecule A to Molecule B over time. A B a) Propose a balanced chemical equation to explain these data. b) Generate the equilibrium expression for your proposed chemical reaction. c) What concentrations would you expect for A and B at equilibrium? SUMMATIVE ASSESSMENT #2 (HOC) Assessing Learning Objective 2 - Compare and contrast concentration versus time graphs for an equilibrium system 2. a) For the reaction below, circle the graph that best describes the change in concentration over time where Keq = 2.0 Concentration Time Time Concentration B Concentration A B Concentration Reaction: A Time Time b) Explain the reasoning behind your choice. SUMMATIVE ASSESSMENT #3 (LOC) Assessing Learning Objective 1 - Generate a model that describes a dynamic equilibrium system A B B Concentration Reaction: A 0 10 Time20 1. Using the Graph above: a. What time are the concentrations of A and B equal? b. What time has the reaction reached equilibrium? Inclusive Teaching Strategies 1. Engage more learning styles by: • using visual, auditory and tactile learning opportunities 2. Engage more personality types by: • working in small groups • asking one group member to report out 3. Make material accessible to include more abilities by: • simple diagrams without “scary molecules” • color choices for teaching materials Normal Color Vision Red-Blind/Protanopia Vision http://www.color-blindness.com/coblis-color-blindness-simulator/