Download Atomic Radii Answers File

CHEMISTRY 3.4
WORKSHEET FOUR
1.
2.
RADII OF ATOMS AND IONS
(a)
1.87 x 10-10 m
(b)
(i)
(ii)
Atomic Radii decrease across a group.
The electrons are going into the same shell so the increasing
nuclear change pulls them closer to the nucleus.
(c)
(i)
(ii)
A.R. increases going down a group.
An extra shell is being added in successive elements and the
electrons in the outer shell are “shielded” from the nucleus by the
inner shells. There is a decreasing attractive pull on them from
the nucleus.
(d)
Atomic radii are measured from inter-nuclear distances between
bonded atoms. The inert gases do not form bonds so it is not possible to
make these measurements.
(a)
(d)
smaller
(b) larger
(c) increases
When an atom loses an electron to form a positive ion, the nuclear
charge has not changed. However, now the nucleus is attracting one less
electron so the remaining ones are pulled in closer.
When an atom gains an electron to form a negative ion, the nuclear
charge has not changed. However, now the nucleus is attracting one
more electron so they are not pulled as strongly as before.
The negative ions will all be bigger than Ar and the positive ions will be
smaller. P3- has gained three electrons so its electrons will be held less
strongly than S2- which will be held less strongly than Cl- so I.R. will
decrease ie P3- > S2- > C1- > Ar. Also Ca2+ has lost 2 electrons compared
to K+ which has lost one, so Ar > K+ > Ca2+
(e)
(f)
3.
ANSWERS
1.1 x 10-10 m
1.0 x 10-10 m
1.35 x 10-10 m
(a)
B, Al, Ga
(b)
Cs, Cs+
(c)
P3-, S2-, Cl-
(d)
Li+, N3-, O2-
(e)
F, Cl, Br, I.
(f)
S, S2-
(g)
Cl, Cl-
(h)
Mg, Mg2+
(i)
Na+, Mg2+, Al3+