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CHE 145-381 – TEST #2 SPRING 2009 CHAPTERS 6, 7, 8 NAME :________________________ DATE: ____________________________ You may use the Periodic Table. Please note that all quantities needed for the successful completion of this test have been given. Feel free to ask questions for clarification. 1. Indicate to which of the following types of chemical reactions each of the statements listed applies: synthesis, decomposition, single replacement, double replacement, or combustion. a. two reactants are required ____________________________________________ b. only one reactant is present __________________________________________ c. two products are required ____________________________________________ d. only one product is present _______________________________________ 2. Balance the following equations, and classify each of the reactions as (i) synthesis (ii) single replacement (iii) double replacement (iv) decomposition of (v) combustion. a. C3H5O9N3 → CO2 + N2 + O2 + H2O __________________ b. C8H18 + O2 → CO2 + H2O ___________________ c. Al2O3 + HNO3 → Al(NO3)3 + H2O ___________________ d. Na2CO3 + H2O + CO2 → NaHCO3 ____________________ e. Co + HCl → CoCl3 + H2 ____________________ 3. Identify the products of, then write a balanced equation for each of the following: a. AlCl3 → ? + ? (decomposition) b. Cu(NO3)2 + c. Al + Ni(NO3)2 d. N2 + H2 e. C8H18 + → Na2CO3 → → O2 ? ? + + ? ? → ? ? (double replacement) (single replacement) (synthesis) + ? (combustion) 4. You have one mole of each of the following substances: cobalt (II) chloride gold (III) chloride ammonium phosphate (a) write the chemical formula for each substance. (b) which sample contains the greatest total number of atoms in one formula unit? (c) which sample has the greatest mass? 5. Give the formula for each of the following: 1. acetic acid ____________ 2. nitrous acid _______________ 3. hypoiodous acid ________________ 4. bromic acid _________________ 5. bromous acid ________________ 6. periodic acid ___________________ 7. potassium hypobromite _________________ 8. sodium perclorate __________________ 9. titanium nitrite _________________ 10. ammonium sulfite ________________ 11. copper (I) phosphite _______________ 12. lead (II) bromite ___________________ 13. potassium hypochlorite _____________ 14. gold (III) cyanide ________________ 15. perbromic acid __________________ 16. tin (IV) sulfide ________________ 17. nitric acid ____________________ 18. hydrochloric acid __________________ 19. lead (IV) phosphate ___________________ 20. iron (III) oxide _______________________ 6. Name the following molecular compounds: N2O5 __________________________________ NO ____________________________________ CBr4 ___________________________________ CO ________________________________________ N2O4 _______________________________________ SO3 ________________________________________ IF7 _____________________________________ NH3 _____________________________________ PH3 ______________________________________ HF (g) _______________________________________ H2S (g) _______________________________________ HBr (g) _______________________________________ 7. How many grams are present in a sample of 5.743 x 1024 molecules of calcium nitrate? 8. Calculate the mass percent of nitrogen in 125g of CO(NH2)2. 8. Potassium thiosulfate, K2S2O3, reacts with chlorine, Cl2, and water in the following manner: K2S2O3 + 4Cl2 + 5H2O → 2KHSO4 + 8HCl a. write the equation in words. ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ ______________________________________________________________________ b. how many moles of each element are in 1 mole of K2S2O3? Write your answers in the form of conversion factors. ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ c. write all of the pertinent conversion factors based on this balanced equation for all of the molar relationships between the reactants and products. ___________________________________________________________________ __________________________________________________________________ _ ___________________________________________________________________ ____________________________________________________________________ ____________________________________________________________________ ____________________________________________________________________ ____________________________________________________________________ ____________________________________________________________________ ____________________________________________________________________ d. how many grams of Cl2 must react to produce 5.6 x 10 24 molecules of HCl? e. how many moles of K2S2O3 must react to produce 25.0g of KHSO4? f. how many grams of H2O must react to produce 20.00g of HCl? g. how many molecules of HCl are produced at the same time that 2.000g of KHSO4 are produced?