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CHM 134 General Chemistry I Exam 1, Fall 2014 – Dr. Foresman Name 1. (11 points) Provide the lowest, whole-number coefficients needed to properly balance each equation. A blank will be assumed to be a coefficient of 1. ——— ——— HCl(aq) C6H14(l) + + ——— Fe2O3(s) → ——— H2O(l) + ——— FeCl3(s) ——— H2O2(aq) → ——— H2O(l) + ——— O2(g) ——— O2(g) → ——— CO2(g) + ——— H2O(l) 2. (4 points) Complete and balance these gas forming reactions, include (aq) and (g): KHCO3 (s) + HNO3 (aq) Ca(OH)2 (s) + NH4Br (aq) 3. (6 points) What is the oxidation state of the element indicated in each case? As in H3AsO4 Ni in NiO2 Cr in CrCl3 P in P4 C in CH2O S in H2SO4 4. (10 points) According to the following reaction, how many grams of hydrochloric acid (HCl) are produced from the complete reaction of 15.7 grams of Cl2 gas? 3 Cl2(g) + 3 H2O(l) 5 HCl(aq) + HClO3(aq) 5. (10 points) For the following reaction, 30.8 grams of carbon disulfide are allowed to react with 98.4 grams of chlorine gas. CS2(s) + 4 Cl2(g) CCl4(l) + 2 SCl2(s) What is the maximum mass of carbon tetrachloride that can be formed? 6. (6 points) In the redox reaction below, use oxidation numbers to identify the element oxidized, the element reduced, and the number of electrons transferred in the redox process. 3 Cu + 2 HNO3 + 6 H+ 2 NO + 3 Cu2+ + 4 H2O 7. (6 points) In the redox reaction below, use oxidation numbers to identify the oxidizing agent, the reducing agent, and the number of electrons transferred in the redox process. 3 ClO2 + NO3- + H2O NO + 3 ClO3- + 2 H+ 8. (12 points) Write the products for each of these reactions. You must include the state of matter and balance the overall equation. K2SO3(aq) + NaOH(aq) + HBr(aq) → HNO3(aq) → CuSO4(aq) + AgNO3(aq) → NaI(aq) + Pb(NO3)2(aq) → LiOH(aq) + H2SO4(aq) → (NH4)2SO4(aq) + Ca(NO3)2(aq) → 9. (9 points) If 6.67 grams of CuCl2 are mixed with excess AgNO3. The reaction yields 9.83 grams of AgCl. What is the percent yield of silver chloride? 2 AgNO3(aq) + CuCl2(s) 2 AgCl(s) + Cu(NO3)2(aq) 10. (8 points) In the laboratory you dissolve 19.8 g of zinc sulfate in a volumetric flask and add water to a total volume of 125 mL. What is the molarity of the solution? 11. (8 points) What volume of a 0.100 M NaOH solution is required to neutralize 25.0 mL of a 0.400 M H2SO4 solution? 2 NaOH(aq) + H2SO4(aq) Na2SO4(aq) + 2H2O(l) 12. (10 points) Potassium hydrogen phthalate (KC8H5O4) is a solid, monoprotic acid frequently used in the laboratory to standardize strong base solutions. How many grams of KC8H5O4 are needed to exactly neutralize 35.0 mL of a 0.482 M potassium hydroxide solution?