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8. Molecular Geometry
8. Molecular Geometry

... Bonds are polar when one atom is positive and the other negative. Molecules with many atoms have polarity, with one end positive, the other negatively charged. You can predict the polarity of the molecule by looking at the ends of the molecule to see if it has a positive end and a negative end. Lone ...
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... It turns out that the entropy change of the system, S , is a state property, depending only on the initial and final states. Therefore, even if we do not know or cannot replicate the actual path the system took in order to get to the final state from a given initial state, we can always design any p ...
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Degenerate matter

Degenerate matter in physics is a collection of free, non-interacting particles with a pressure and other physical characteristics determined by quantum mechanical effects. It is the analogue of an ideal gas in classical mechanics. The degenerate state of matter, in the sense of deviant from an ideal gas, arises at extraordinarily high density (in compact stars) or at extremely low temperatures in laboratories. It occurs for matter particles such as electrons, neutrons, protons, and fermions in general and is referred to as electron-degenerate matter, neutron-degenerate matter, etc. In a mixture of particles, such as ions and electrons in white dwarfs or metals, the electrons may be degenerate, while the ions are not.In a quantum mechanical description, free particles limited to a finite volume may take only a discrete set of energies, called quantum states. The Pauli exclusion principle prevents identical fermions from occupying the same quantum state. At lowest total energy (when the thermal energy of the particles is negligible), all the lowest energy quantum states are filled. This state is referred to as full degeneracy. The pressure (called degeneracy pressure or Fermi pressure) remains nonzero even near absolute zero temperature. Adding particles or reducing the volume forces the particles into higher-energy quantum states. This requires a compression force, and is made manifest as a resisting pressure. The key feature is that this degeneracy pressure does not depend on the temperature and only on the density of the fermions. It keeps dense stars in equilibrium independent of the thermal structure of the star.Degenerate matter is also called a Fermi gas or a degenerate gas. A degenerate state with velocities of the fermions close to the speed of light (particle energy larger than its rest mass energy) is called relativistic degenerate matter.Degenerate matter was first described for a mixture of ions and electrons in 1926 by Ralph H. Fowler, showing that at densities observed in white dwarfs the electrons (obeying Fermi–Dirac statistics, the term degenerate was not yet in use) have a pressure much higher than the partial pressure of the ions.
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