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physical chemistry - University Science Books
physical chemistry - University Science Books

... 1.1 Nature of Physical Chemistry Physical chemistry can be described as a set of characteristically quantitative approaches to the study of chemical problems. A physical chemist seeks to predict and/ or explain chemical events using certain models and postulates. Because the problems encountered in ...
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... of matter: gases, liquids, solids, etc.; are there more states there? Yes – think of the chicken soup (suspension) you are warming up on the gas flame (plasma) while checking your watch display (liquid crystal), or think of the peanut butter (emulsion)–jam (gel) sandwich you had this morning. You may ...
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... The swarm is ensemble of charged particles travelling through the neutral gas and balancing between the energy and momentum gained from the external (electric) field and dissipating the energy and momentum in collisions with the background gas [13]. Assuming that probability of collisions of swarm p ...
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Chapter 6 - Department of Chemical Engineering
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Ch#1 Introduction - Seattle Central College

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Lecture Slides - School of Chemical Sciences

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Lowering of the L10 ordering temperature of FePt

... a micellar technique on Si substrates. The phase transition of these magnetic particles towards the chemically ordered L10 phase is tracked for 350 kV He+ ion irradiated samples and compared to a nonirradiated reference. Due to the large separation of the magnetically decoupled particles the array c ...
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... In 1897, J. J. Thomson demonstrated in an experiment that cathode rays were deflected by an electric field. This suggested that cathode rays were composed of negatively charged particles found in all atoms. Thomson concluded that the atom was a positively charged sphere of almost uniform density in ...
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Mr Alasdair Ross at Southpointe Academy

... The Vapour Pressure of a liquid is the partial pressure exerted by its vapor in dynamic equilibrium with liquid at a constant temperature. The Vapour Pressure of a liquid increases with temperature. At a higher temperature more molecules have enough kinetic energy to escape from the liquid state. At ...
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Degenerate matter

Degenerate matter in physics is a collection of free, non-interacting particles with a pressure and other physical characteristics determined by quantum mechanical effects. It is the analogue of an ideal gas in classical mechanics. The degenerate state of matter, in the sense of deviant from an ideal gas, arises at extraordinarily high density (in compact stars) or at extremely low temperatures in laboratories. It occurs for matter particles such as electrons, neutrons, protons, and fermions in general and is referred to as electron-degenerate matter, neutron-degenerate matter, etc. In a mixture of particles, such as ions and electrons in white dwarfs or metals, the electrons may be degenerate, while the ions are not.In a quantum mechanical description, free particles limited to a finite volume may take only a discrete set of energies, called quantum states. The Pauli exclusion principle prevents identical fermions from occupying the same quantum state. At lowest total energy (when the thermal energy of the particles is negligible), all the lowest energy quantum states are filled. This state is referred to as full degeneracy. The pressure (called degeneracy pressure or Fermi pressure) remains nonzero even near absolute zero temperature. Adding particles or reducing the volume forces the particles into higher-energy quantum states. This requires a compression force, and is made manifest as a resisting pressure. The key feature is that this degeneracy pressure does not depend on the temperature and only on the density of the fermions. It keeps dense stars in equilibrium independent of the thermal structure of the star.Degenerate matter is also called a Fermi gas or a degenerate gas. A degenerate state with velocities of the fermions close to the speed of light (particle energy larger than its rest mass energy) is called relativistic degenerate matter.Degenerate matter was first described for a mixture of ions and electrons in 1926 by Ralph H. Fowler, showing that at densities observed in white dwarfs the electrons (obeying Fermi–Dirac statistics, the term degenerate was not yet in use) have a pressure much higher than the partial pressure of the ions.
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