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Assignment CHE-04 TMA-01,02 Year 2005
Assignment CHE-04 TMA-01,02 Year 2005

... 7. 50 mol of a monoatomic ideal gas occupies a volume of 0.8314 m3 at 1.50×105 Pa and 3.00×102 K. The gas undergoes expansion and the final pressure is 7.50×104 Pa. Calculate the final volume of the gas, assuming that it proceeds through (i) reversible isothermal process and (ii) reversible adiabat ...
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Department of Chemistry, IIT-Delhi CY110N Tutorial

... 17. Calculate the maximum work and the maximum non-expansion work that can be obtained from the freezing of supercooled water at −5 o C and 1.0 atm. The densities of water and ice are 0.999 and 0.917 g cm−3 , respectively at −5 o C. 18. One mole of He is heated from 200 o C to 400 o C at a constant ...
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Degenerate matter

Degenerate matter in physics is a collection of free, non-interacting particles with a pressure and other physical characteristics determined by quantum mechanical effects. It is the analogue of an ideal gas in classical mechanics. The degenerate state of matter, in the sense of deviant from an ideal gas, arises at extraordinarily high density (in compact stars) or at extremely low temperatures in laboratories. It occurs for matter particles such as electrons, neutrons, protons, and fermions in general and is referred to as electron-degenerate matter, neutron-degenerate matter, etc. In a mixture of particles, such as ions and electrons in white dwarfs or metals, the electrons may be degenerate, while the ions are not.In a quantum mechanical description, free particles limited to a finite volume may take only a discrete set of energies, called quantum states. The Pauli exclusion principle prevents identical fermions from occupying the same quantum state. At lowest total energy (when the thermal energy of the particles is negligible), all the lowest energy quantum states are filled. This state is referred to as full degeneracy. The pressure (called degeneracy pressure or Fermi pressure) remains nonzero even near absolute zero temperature. Adding particles or reducing the volume forces the particles into higher-energy quantum states. This requires a compression force, and is made manifest as a resisting pressure. The key feature is that this degeneracy pressure does not depend on the temperature and only on the density of the fermions. It keeps dense stars in equilibrium independent of the thermal structure of the star.Degenerate matter is also called a Fermi gas or a degenerate gas. A degenerate state with velocities of the fermions close to the speed of light (particle energy larger than its rest mass energy) is called relativistic degenerate matter.Degenerate matter was first described for a mixture of ions and electrons in 1926 by Ralph H. Fowler, showing that at densities observed in white dwarfs the electrons (obeying Fermi–Dirac statistics, the term degenerate was not yet in use) have a pressure much higher than the partial pressure of the ions.
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