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carbonyl chemistry 1
carbonyl chemistry 1

... Thus, the carbonyl group of an aldehyde or a ketone can be protected in the form of an acetal or ketal. Deprotection following reaction on other regions of the molecule then yields the carbonyl group again – this then is the first protection/deprotection protocol we have encountered. In general, sim ...
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... Cl). More bromines can be added to the ring by heating. The tube warms up and the liquid turns pale brown, before forming two layers, green and ochre. Upon the addition of water (removing the H+ from the HSO3­-­ group), there is a milky ppt. A solution of fuming sulphuric acid is used here to provid ...
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PowerPoint 簡報 - Solon City Schools

... oxygen atom, which in turn is bonded to the carbon skeleton of the organic molecule. (Do not confuse this functional group with the hydroxide ion, OH–). Hydroxyl groups are not highly reactive, but they readily form hydrogen bonds and contribute to making molecules soluble in water. Alcohols and sug ...
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< 1 ... 290 291 292 293 294 295 296 297 298 ... 359 >

Hydroformylation



Hydroformylation, also known as oxo synthesis or oxo process, is an important homogeneously catalyzed industrial process for the production of aldehydes from alkenes. This chemical reaction entails the addition of a formyl group (CHO) and a hydrogen atom to a carbon-carbon double bond. This process has undergone continuous growth since its invention in 1938: Production capacity reached 6.6×106 tons in 1995. It is important because the resulting aldehydes are easily converted into many secondary products. For example, the resulting aldehydes are hydrogenated to alcohols that are converted to plasticizers or detergents. Hydroformylation is also used in specialty chemicals, relevant to the organic synthesis of fragrances and natural products. The development of hydroformylation, which originated within the German coal-based industry, is considered one of the premier achievements of 20th-century industrial chemistry.The process typically entails treatment of an alkene with high pressures (between 10 to 100 atmospheres) of carbon monoxide and hydrogen at temperatures between 40 and 200 °C. Transition metal catalysts are required.
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