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The Atom Structure of the Atom Atom Vocabulary 1. • • • • 2. • • • 3. • • • • 4. • • • • Nucleus Located in the center of the atom Made up of protons and neutrons Carries a positive charge Makes up nearly the entire mass of the atom. Protons Located within the nucleus Have a positive charge Determine the atomic number of the atom Neutrons Located within the nucleus Carry no charge (neutral) Composed of a proton bound to an electron Determines the atomic mass when their number is added to the number of protons. Electrons Surround the nucleus Carry a negative charge Play a major role in determining the chemical properties of the atom When taken from or added to the atom they cause the atom to carry a charge Scale of the Atom Atomic Number The total number of protons Atomic Mass Protons plus Neutrons = Atomic Mass Electrons The number of electrons will always be the same as the number of protons in a neutral atom! A.P.E M.A.N. Atomic # = Protons = Electrons - Atomic Mass Atomic # _________ #Neutrons Isotope A variety of an element that has a different number of neutrons Isotopes are just atoms of an element that have different numbers of neutrons. Since all elements occur in more than one variation, all atoms are isotopes. They don't become an isotope, any more than an atom becomes an atom, they just are. Ion An atom that has gained or lost electrons and carries a charge Quarks The fractionally charged particles that protons and neutrons are made of. Strong Nuclear Force The strong nuclear force is the force that binds the positively charged protons together in the nucleus. The force is caused by an exchange of particles called gluons. String Theory Recent research suggests that all atomic particles are fundamentally composed of vibrating strings. The way in which the string vibrates determines the properties of the particle. Video: Atomic Structure Video: Quantum Theory Radioactivity Alpha Decay Alpha decay occurs is because the nucleus has too many protons which cause excessive repulsion. In an attempt to reduce the repulsion, a Helium nucleus is emitted. Beta Decay Beta decay occurs when the neutron to proton ratio is too great in the nucleus and causes instability. In basic beta decay, a neutron is turned into a proton and an electron. The electron is then emitted. Gamma Decay Gamma decay occurs because the nucleus is at too high an energy. The nucleus falls down to a lower energy state and, in the process, emits a high energy photon known as a gamma particle. Half-Life The amount of time required for half the amount of a radioactive substance to decay into a stable daughter product Video: Radioactive Decay How did we get here? http://www.youtube.com/watch?v=vUzTQWn-wfE The Influence of Democritus circa 460 B.C.E. Teachings • Was not the first to propose an atomic theory. He was the first to write about it, however. • Formally developed the idea that matter could not be divided infinitely and that there must be some smallest particle which he called “atomos” which means indivisible. • All matter is composed of atoms, which are bits of matter too small to be seen. These atoms CANNOT be further split into smaller portions. The Influence of Aristotle circa 400 B.C.E. Earth, Air, Fire, and Water Aristotle’s Thoughts on the composition of Matter • According to Aristotle's theory all physical objects in the world are composed of earth, air, fire, and water in different proportions. The varying amount of each element in the composition accounts for the infinite variety of things in the world. • Although the idea of the atom never died, Aristotle’s ideas were considered authoritative until the early 1800’s. Atomism and Aristotle • The idea of the atom was strongly opposed by Aristotle and others. • Because of this, “atomism” faded into the background. John Dalton: The Father of Modern Chemistry 1766-1844 Dalton’s Image of the Atom Dalton’s Influence • Unlike Democritus, Dalton based his idea of the atom on experimental evidence. Dalton’s Atomic Theory • All matter is composed of small particles called atoms that are hard, solid, and spherical. • Atoms are the smallest particles that make up matter. They cannot be divided, created, or destroyed. • The atoms of a specific element are identical in size, mass, and all other properties. • The atoms of different elements differ in size, mass, and other properties. Cathode Ray Tube In the Mid 1800’s is was discovered that when a current of electricity passes through a glass tube a display of colorful lights gradually appears as the gas inside it is evacuated. Research with the tube gave evidence that charged rays of some kind are traversing the tube. . These were called cathode rays. Cathode Ray Tube Sir William Crookes 1832-1919 Crookes Tube William Crookes, an English physicist, creates a greatly improved version of the vacuum tube (the "Crookes tube") and shows that cathode rays travel in straight lines, cast sharp shadows, and carry an electric charge. He even puts a little paddle wheel into one tube and shows that the cathode rays can turn the wheel when they hit it, just like a stream of water! J.J. Thompson 1897 Using a modified Crookes Tube J.J. Thompson showed that all cathode rays were the same, regardless of what material the cathode was made of. Based on the results of his experiments he concluded that the cathode rays were a stream of small, electrically charged particles which have a mass over a thousand times less than that of an atom. Thomson had discovered the electron. The Plum Pudding Model Thompson developed the first basic modern model of the atom. His model was called the “plum pudding" model, since it resembled plum pudding, which is a dessert common in England. Thompson's model featured the negatively charged electrons randomly "stuck" into a ball of positively charged matter. Ernest Rutherford 1906 The Gold Foil Experiment Rutherford and his students pass a beam of alpha particles through paper thin gold foil. The expectation was that the particles would pass straight through since the atom was thought to have its differently charged particles spread evenly throughout as represented by Thompson’s plum pudding model. Top: Expected results of Rutherford's gold foil experiment: alpha particles passing through the plum pudding model of the atom undisturbed. Bottom: Observed results: Some of the particles were deflected, and some by very large angles. Rutherford concluded that the positive charge of the atom must be concentrated into a very small location: the atomic nucleus. Rutherford’s Solar System Model of the Atom Rutherford pictured the atom as having a massive, positively charged nucleus that was surrounded by orbiting electrons at a great distance. The atom was mostly empty space! Niels Bohr 1922 Electron Energy Levels Bohr and Electron Energy Levels • The electron travels in a circular path around the nucleus. This path is called an orbit. • At normal living conditions, room temperature, the electron resides in the orbit which is closest to the nucleus. This is the position of lowest energy content for the electron. • If energy is added to an electron, the electron will move to a new orbit. This orbit will be farther from the nucleus, and is a position of higher energy content. This new position is known as an excited state. • When an electron moves from one orbit to another orbit, it does so without ever passing through the space between the orbits. Known as a quantum jump. • When an electron is in an excited state, it will always drop down to a lower energy state, ultimately returning to ground state. Electron Transition If an electron moves from a low energy level to a higher energy level it does so by gaining energy. If it moves from a higher energy level to a lower energy level, it does so by releasing energy. The released energy is in the form of electromagnetic radiation. This transition is known as a quantum leap. Bohr Model Erwin Schrodinger 1930 Viewed electrons as continuous clouds and introduced "wave mechanics" as a mathematical model of the atom. James Chadwick 1932 Using alpha particles discovered a neutral atomic particle with a mass close to a proton. Thus was discovered the neutron.