* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
Download Week 2
Electronegativity wikipedia , lookup
Nuclear binding energy wikipedia , lookup
Metallic bonding wikipedia , lookup
Hypervalent molecule wikipedia , lookup
Nuclear transmutation wikipedia , lookup
Drug discovery wikipedia , lookup
Biochemistry wikipedia , lookup
Abundance of the chemical elements wikipedia , lookup
Organic chemistry wikipedia , lookup
Rutherford backscattering spectrometry wikipedia , lookup
Inorganic chemistry wikipedia , lookup
Periodic table wikipedia , lookup
Chemical bond wikipedia , lookup
Organosulfur compounds wikipedia , lookup
Electron configuration wikipedia , lookup
Homoaromaticity wikipedia , lookup
Gas chromatography–mass spectrometry wikipedia , lookup
Chemical element wikipedia , lookup
Extended periodic table wikipedia , lookup
Isotopic labeling wikipedia , lookup
History of chemistry wikipedia , lookup
Atomic nucleus wikipedia , lookup
History of molecular theory wikipedia , lookup
Chemistry: A Volatile History wikipedia , lookup
IUPAC nomenclature of inorganic chemistry 2005 wikipedia , lookup
Chapter 2 Atoms, Molecules, and Ions Atoms, Molecules, and Ions • The vocabulary of chemistry is specialized. • It includes such terms as atom, ion, molecule, isotope, acid, base, salt, and saturated hydrocarbon. • Chemistry also involves symbolic notation. • Atoms of elements are represented by symbols, such as H, C, N, O, Na, and Cl. These symbols are the alphabet of chemistry. • To represent compounds, symbols are combined into chemical formulas, such as NaCl, and formulas are the words of chemistry. Molecule models S8 C4 Gen. Chem. Chapter2 3 Molecular compounds Gen. Chem. Chapter2 4 Some molecules H2 O2 CH3-CH(OH)-CH3 CH3CH2Cl P4O10 HCOOH Gen. Chem. Chapter2 5 Molecule models Gen. Chem. Chapter2 6 New laws are formulated making use of other laws. BRICKS ON THE WALL!!!! Gen. Chem. Chapter2 7 • Is the mass of the burned match pictured in the photograph the same as, less than, or more than the mass of the burning match? The match loses mass in the reaction. This kind of loss of mass to carbon dioxide during burning greatly confused early chemists who did not measure the mass of the gases produced. The rule of conservation of matter is credited to Lavoisier. Gen. Chem. Chapter2 8 Gen. Chem. Chapter2 Antoine Lavoisier (1743 – 1794) 9 Another of the 18th century chemists to emphasize the importance of experiments was Antoine Lavoisier (1743-1794) Lavoisier studying human respiration. His wife, Marie Anne Paulze, seated at the table on the right, records the experiment. Lavoisier was the first great theoretical chemist. Marie was an accomplished artist and made this drawing herself. Gen. Chem. Chapter2 10 2.1 Laws of Chemical Combination • Data obtained by experiment can often be summarized into laws. Scientific theories are then formulated to explain these laws. Lavoisier: The Law of Conservation of Mass • Modern chemistry dates from the eighteenth century, when scientists began to make quantitative observations. • Antoine Lavoisier made mass measurements precise to about 0.0001 g and established that total mass does not change during a chemical reaction. Gen. Chem. Chapter2 11 • For example, Lavoisier heated the red oxide of mercury, causing it to decompose (break down) to two new products: mercury metal and oxygen gas. • By measuring carefully, he found that the total mass of the products was exactly the same as the mass of the mercury oxide he started with. • Lavoisier summarized his findings through the law of conservation of mass. The total mass remains constant during a chemical reaction. Gen. Chem. Chapter2 12 Proust: The Law of Definite Proportions • By the end of the eighteenth century, Lavoisier and other scientists had succeeded in decomposing many compounds into the elements that form them. • One of these scientists, Joseph Proust (1754–1826), did careful quantitative studies by which he established the Law of Constant Composition • (also called the Law of Definite Proportions). All samples of a compound have the same composition; that is, all samples have the same proportions, by mass, of the elements present in the compound. Gen. Chem. Chapter2 13 Joseph Proust (1754 – 1826) Gen. Chem. Chapter2 14 • Proust based this law in part on his studies of a substance that we now call • basic copper carbonate ; • all samples of this compound have the same composition: • 57.48% copper, • 5.43% carbon, • 0.91% hydrogen, • 36.18% oxygen and by mass. Gen. Chem. Chapter2 15 A substance known as basic copper carbonate occurs in nature as the mineral malachite forms as a patina on copper roofs and bronze statues can be synthesized in the laboratory The law of definite proportions : Regardless of its source, basic copper carbonate Cu2(CO3)(OH)2, always has the same composition. Gen. Chem. Chapter2 16 The Mineral Malachite •Chemistry: Cu2(CO3)(OH)2, Copper Carbonate Hydroxide. •Class: Carbonate Gen. Chem. Chapter2 17 • A compound not only has a constant, or fixed, composition; it also has fixed properties. • For example, under normal atmospheric pressure, pure water always freezes at 0 °C and boils at 100 °C. Gen. Chem. Chapter2 18 • The physical and chemical properties of chemical substances—both elements and compounds—depend on their composition. • A twentieth-century modification of this law, based on the work of Albert Einstein, allows for the possibility of converting mass to energy (and vice versa). • This need not concern us, however, because in chemical rections the amounts of mass converted to energy are too small to detect. Gen. Chem. Chapter2 19 2.2 John Dalton and the Atomic Theory of Matter In 1803, John Dalton proposed a theory to explain the laws of conservation of mass and constant composition. As he developed what would become known as his atomic theory, Dalton found evidence of a scientific law describing the composition of matter. In some cases, atoms of the same two elements are able to combine to form two or more different compounds, and the compositions of the different compounds are related. Gen. Chem. Chapter2 20 John Dalton Gen. Chem. Chapter2 21 • Let's illustrate Dalton's reasoning with a simple example: two compounds composed of the elements carbon and oxygen. • In carbon dioxide (the familiar gas produced in respiration and in the burning of fuels) the two elements combine in the ratio of 8.0 g of oxygen to 3.0 g of carbon. • In carbon monoxide (the poisonous gas formed when a fuel is burned in limited air) the elements combine in the ratio of 4.0 g of oxygen to 3.0 g of carbon. • Based on evidence such as this, Dalton formulated The Law of Multiple Proportions • which we can state in the following way: In two or more compounds of the same two elements, the masses of one element that combine with a fixed mass of the second element are in the ratio of small whole numbers. Gen. Chem. Chapter2 22 Law of Multiple Proportions Ratio of oxygentocarbon in CO2 is exactly twice Gen. Chem. Chapter2 the ratio in CO 23 ANIMATION 1: MULTIPLE PROPORTIONS Gen. Chem. Chapter2 24 Law of Multiple Proportions • Four different oxides of nitrogen can be formed, by combining 28 g of nitrogen with: • 16 g oxygen, forming Compound I • 48 g oxygen, forming Compound II • 64 g oxygen, forming Compound III • 80 g oxygen, forming Compound IV 1:3:4:5 What is the ratio 16:48:64:80 expressed as small whole numbers? • Compounds I–IV are N2O, N2O3, N2O4, N2O5 Gen. Chem. Chapter2 25 • Dalton's Atomic Theory • The atomic model Dalton developed to explain the laws of chemical combination is based on four ideas: - All matter is composed of extremely small, indivisible particles called atoms. - All atoms of a given element are alike in mass and other properties, but the atoms of one element differ from the atoms of every other element. - Compounds are formed when atoms of different elements unite in fixed proportions. That is, one atom of A to one of B in AB, two atoms of A to one of B in A2B and so on. - A chemical reaction involves a rearrangement of atoms to produce new compounds. No atoms are created, destroyed, or broken apart in a chemical reaction. Gen. Chem. Chapter2 26 2.3 The Divisible Atom • However, like most other scientific theories, Dalton's model eventually had to be modified in light of later discoveries. • Toward the end of the nineteenth century, certain experiments began to reveal that atoms are made up of smaller parts. • Of the dozens of subatomic (smaller than atomic) particles now known, three are of special importance in the study of chemistry. • They are the proton, neutron, and electron. Gen. Chem. Chapter2 27 Subatomic Particles • The mass and charge of subatomic particles are so small that they are conveniently expressed in relative units. • The proton has a relative mass of 1. The proton also carries one fundamental unit of positive electric charge, denoted 1+ . • The neutron, as its name implies, is an electrically neutral particle; it has no charge. Although its mass is slightly greater than that of the proton, for many purposes we can consider the neutron also to have a relative mass of 1. • The third particle, the electron, has a mass that is 1/1836 of the mass of a proton. An electron has the same quantity of charge as a proton, but it is a negative charge, denoted as 1- . • Protons, neutrons, and electrons are fundamental particles. • This means that all protons are alike, all neutrons are alike, and all electrons are alike in whatever element they are found. Gen. Chem. Chapter2 28 Subatomic Particles • Protons and neutrons are densely packed into a tiny, positively charged core of the atom known as the nucleus. • The extremely lightweight electrons are widely dispersed around the nucleus. • An atom as a whole is electrically neutral: It has no net charge because the negative and positive charges balance each other. Gen. Chem. Chapter2 Atom like Football Field 29 Nuclear Structure Atomic Diameter 10-8 cm Nuclear diameter 10-13 cm =1Å Gen. Chem. Chapter2 30 Subatomic Particles •Although the numbers differ from one element to another, the atoms of every element have equal numbers of electrons and protons. Gen. Chem. Chapter2 31 • Dalton believed that the identity of an element is determined by the mass of one of its atoms. • We now know that it is not the mass of an atom but rather the number of protons in the nucleus that determines the kind of atom and therefore the identity of an element. • The atomic number (Z) is the number of protons in the nucleus of an atom of a given element, and it is this number of protons that defines the element. • Every atom having two protons in its nucleus has Z = 2 and is an atom of helium. • Every atom with 92 protons has Z = 92 and is an atom of uranium. Gen. Chem. Chapter2 32 Isotopes • Atoms that have the same number of protons but different numbers of neutrons are called isotopes. • The atomic number (Z) is the number of protons in the nucleus of a given atom of a given element. • The mass number (A) is an integral number that is the sum of the numbers of protons and neutrons in an atom. • The number of neutrons = A – Z. Gen. Chem. Chapter2 33 Isotopes • For example, there are three isotopes of hydrogen. • The most abundant isotope, occasionally called protium, has a single proton and no neutrons in its nucleus. • About one in every 6700 hydrogen atoms, however, has a neutron as well as a proton. Because the mass of a neutron is essentially the same as the mass of a proton, the mass of this hydrogen isotope, called deuterium, is about twice that of protium. • A third, very rare isotope of hydrogen, called tritium, has two neutrons and one proton in the nucleus. A tritium atom has about three times the mass of a protium atom. Gen. Chem. Chapter2 34 Isotopes of Hydrogen Atomic number (Z) = number of protons Protium has 1 proton, 0 neutrons : Z=1 Deuterium has 1 proton, 1 neutron : Z=1 Tritium has 1 proton, 2 neutrons : Z=1 Gen. Chem. Chapter2 35 • Some elements have only one naturally occurring isotope; these include fluorine-19, sodium-23, and phosphorus-31. • Most elements, however, have two or more isotopic forms. • Tin has the greatest number of naturally occurring isotopes: 10. • The naturally occurring isotopes are always found in certain precise proportions. In natural sources of chlorine, for example, 75.77% of the atoms are chlorine-35 and 24.23% are chlorine-37. • Chemical symbols for isotopes are commonly written in the form with A being the mass number and Z the atomic number of the element E. A Z E • For the two naturally occurring isotopes of chlorine, we can write 35 Cl 17 and 37 Cl 17 indicating mass numbers of 35 and 37 for chlorine-35 and chlorine-37, respectively. Gen. Chem. Chapter2 36 Chemical Symbol To represent a particular atom we use the symbolism: A= mass number Z = atomic number To represent an ion Gen. Chem. Chapter2 37 Isotopes Atoms can be represented using the element’s symbol and the mass number (A) and atomic number (Z): A E Z 35 Cl 17 37 Cl 17 • How many protons are in chlorine-35? • How many protons are in chlorine-37? • How many neutrons are in chlorine-37? Gen. Chem. Chapter2 38 Other Examples of Isotopes The number of neutrons = A – Z Carbon-12 Carbon-13 Carbon-14 Z=6 Z=6 Z=6 so 6 neutrons so 7 neutrons so 8 neutrons Chlorine-35 Chlorine-37 Z = 17 Z = 17 so 18 neutrons so 20 neutrons Uranium-234 Uranium-235 Uranium-238 Z = 92 Z = 92 Z = 92 so 142 neutrons so 143 neutrons so 146 neutrons Gen. Chem. Chapter2 39 C, H, O Analyser Gen. Chem. Chapter2 40 2.4 Atomic Masses • By international agreement, the current atomic mass standard is the pure isotope carbon-12, which is assigned a mass of exactly 12 atomic mass units (12 u). • Based on this standard, we can define an atomic mass unit, (abbreviated amu and having the unit u) as exactly one-twelfth the mass of a carbon-12 atom. • In more familiar units of mass, 1 u = 1.66054 x 10-24 g. • Because we are interested in the masses of atoms and not their weights, we will now shift to the term atomic mass in place of the older atomic weight, except in a few cases of historical interest. Gen. Chem. Chapter2 41 • The atomic mass of an element is defined as the weighted average of the masses of the naturally occurring isotopes of that element. • Consider carbon, which consists of a mixture of two naturally occurring isotopes. • The much more abundant isotope is carbon-12. The other is carbon-13, with a mass of 13.00335 u. Both isotopes are present in substances containing carbon atoms, and in proportions that generally do not vary from one carbon-containing substance to another. • To describe the atomic mass of carbon, then, we need to use an average value, but not the simple average (12 + 13) / 2 = 12.5. Because carbon-12 is much more abundant than carbon-13, the average we seek lies much closer to the mass of carbon-12 than to that of carbon-13. We say that it is "weighted" toward the mass of carbon-12. Gen. Chem. Chapter2 42 • To calculate the atomic mass of an element, we need two quantities— • (1) the atomic masses of the isotopes of the element and • (2) the naturally occurring fractional abundances of the isotopes. • Let us explain how these quantities are obtained experimentally • To illustrate, let's return to the atomic mass of carbon. Gen. Chem. Chapter2 43 • The percentage abundances and fractional abundances of the carbon isotopes are as follows: To obtain a weighted average atomic mass, we calculate the contribution of each isotope to the weighted average from the relationship The term atomic weight is still widely used, however, as by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry (IUPAC). Gen. Chem. Chapter2 44 Use the data cited below to determine the weighted average atomic mass of carbon. The contribution of each isotope to the weighted average atomic mass is given by Equation. Solution The contributions are Contribution of carbon-12 = 0.98892 x 12.00000 u = 11.867 u Contribution of carbon-13 = 0.01108 x 13.00335 u = 0.1441 u The weighted average atomic mass is the sum of the two contributions. Atomic mass of carbon = 11.867 u + 0.1441 u = 12.011 u Gen. Chem. Chapter2 45 Carbon – 14 ( C-14 Dating ) Gen. Chem. Chapter2 46 2.5 The Periodic Table: Elements Organized • In the nineteenth century, chemists discovered dozens of new elements. • By 1830, 55 elements were recognized, but there was no apparent pattern in their properties. Chemists badly needed a way to organize the growing collection of chemical data. • One way to do this was to arrange the elements in a manner that would establish categories of elements having similar physical and chemical properties. • Dimitri Mendeleev published the first successful arrangement, called a periodic table, in 1869. • In its modern form, the periodic table organizes a vast array of chemical knowledge. Gen. Chem. Chapter2 47 Dimitri Mendeleev Gen. Chem. Chapter2 48 Mendeleev's Periodic Table Mendeleev arranged the elements in order of increasing atomic weight, from left to right in rows and from top to bottom in columns (or groups). In this arrangement, elements that most closely resemble one another in physical and chemical properties tend to fall in the same vertical group. This group similarity repeats periodically, hence the name periodic table. • There would be no exceptions to the principle that all the elements in a group display similar properties, therefore Mendeleev placed some elements out of order, that is, not in the strict order of increasing atomic weight. Gen. Chem. Chapter2 49 For example, he correctly placed tellurium (atomic weight 127.6) before iodine (atomic weight 126.9) so that tellurium would be in the same column as the similar elements sulfur and selenium. Gen. Chem. Chapter2 50 • When Mendeleev placed elements with similar properties in the same vertical group, a few gaps were created in his table. Instead of seeing these gaps as defects, he boldly predicted the existence of undiscovered elements to fill the gaps. • Furthermore, because the table was based on patterns of properties, he was able to predict some properties of the missing elements. Gen. Chem. Chapter2 51 Mendeleev’s Table Mendeleev’s Table Dimitri Mendeleev created this, the original periodic table. Stowe's table Spiral form Triangular form Mendeleevs’s early table was published in 1872. • Using his table he was able to correct several values of atomic masses. Folded Table • Because of its obvious usefullness his periodic table was almost universally adopted, and it remains one of the most valuable tools at the chemist’s use. • The only fundemantal difference between todays table and that of his Periodic Table is that in the current table the elements are ordered by atomic number rather than by atomic mass. Gen. Chem. Chapter2 52 • For example, he left a blank space for an undiscovered element that he called "ekasilicon" and used its location between silicon and tin to predict an atomic weight of 72 and other properties. Gen. Chem. Chapter2 53 • Table 2.2 shows just how accurate his predictions were, when compared to the properties of the actual element germanium discovered 15 years later. • The predictive nature of Mendeleev's periodic table led to its wide acceptance as a tremendous scientific accomplishment. Gen. Chem. Chapter2 54 Alkali Metals The Periodic table Alkaline Earths Halogens Noble Gases Main Group Transition Metals Main Group Lanthanides and Actinides Gen. Chem. Chapter2 55 (2) PERIODIC PROPERTIES ANIMATION Gen. Chem. Chapter2 56 Empirical and Molecular Formulas Empirical formula: the simplest whole number ratio of elements in a compound Example: Molecular formula of glucose – C6H12O6 The elemental ratio C:H:O is 1:2:1, so the empirical formula is CH2O Gen. Chem. Chapter2 57 Molecular compounds Gen. Chem. Chapter2 58 Introduction to Compounds A molecule is a group of two or more atoms held together by covalent bonds. A chemical formula is a symbolic representation of the composition of a compound in terms of its constituent elements. Gen. Chem. Chapter2 59 Structural Formulas Shows how atoms are attached to one another. Gen. Chem. Chapter2 60 Molecular Compounds Ball-and-stick model vs. Spacefilling model Gen. Chem. Chapter2 61 Binary Molecular Compounds Molecular formulas are usually written with the more “metallic” first – “metallic” means farther left in the period and lower in the group e.g., NaCl, KBr Compounds that are typically comprised of two nonmetallic elements: e.g., CO, NO, HF Gen. Chem. Chapter2 62 Formulas and Subscripts Subscripts are used when a given atom is used more than once e.g., H2O, CO2, N2O, HF, B2O3 The presence of subscripts is reflected in the names of compounds Gen. Chem. Chapter2 63 Names of Binary Compounds Consider the compounds CO and CO2 The compound name consists of two words, one for each element in the compound Name the element that appears first in the formula: CARBON The second element has an altered name: retain the stem of the element name and replace the ending by -ide OXYGEN OXIDE However, both compounds cannot be carbon oxide Gen. Chem. Chapter2 64 Names of Binary Compounds The names are further modified by adding prefixes to denote the numbers of atoms: CO (Carbon Mon-oxide), CO2 (Carbon Di-oxide) Gen. Chem. Chapter2 65 2.7 Ions and Ionic Compounds In an isolated atom, the number of protons equals the number of electrons, and the atom is therefore electrically neutral. In some chemical reactions, however, an individual atom or a group of bonded atoms may lose or gain one or more electrons, thereby acquiring a net electric charge and becoming an ion. Ions are formed only through the loss or gain of electrons; there is no change in the number of protons in the nucleus of the atom(s). If electrons are lost, there are more protons than electrons in the resulting ion and so it has a positive charge. If electrons are gained, there are more electrons than protons in the resulting ion and so it has a negative charge. Gen. Chem. Chapter2 66 Ions and Ionic Compounds Atoms that gain or lose electrons are called ions Positive ions: CATIONS Atoms that lose electrons form cations Na Na+ + e– Negative ions: ANIONS Atoms that gain electrons form anions Cl + e– Cl– Gen. Chem. Chapter2 67 Monatomic Ions Group A metals usually lose the number of electrons equal to their Group number. Nonmetal atoms usually gain electrons and have a charge equal to their Group number minus eight. The periodic table cannot be used to determine the charge on Group B metals. For naming, Group B metals capable of multiple charges have the corresponding Roman numeral in parentheses added after the element name. Gen. Chem. Chapter2 68 Common Monatomic Ions FIGURE 2.10 Symbols and periodic table locations of some monatomic ions Three general observations can be made of these data: (1) Aluminum and the metals of groups 1A and 2A form just one cation, which carries a positive charge equal in magnitude to the A-group number. (2) Most of the metals of the B groups form two or more cations of different charges, though in some cases only one of these cations is commonly encountered. (3) The nonmetals of groups 7A and 6A, along with nitrogen and phosphorus of group 5A, form anions that have a charge equal to the group number minus 8. Gen. Chem. Chapter2 69 Formulas and Names for Ionic Compounds Ionic compounds form when oppositely charged ions are attracted to each other NaCl Resulting compound is electrically neutral Na+ Cl– (+1) + (–1) = 0 Ionic compound names use the cation name followed by the anion name Sodium chloride Gen. Chem. Chapter2 70 Now consider the formula for aluminum oxide. We cannot simply combine one Al3+ and one O2- , because this would produce a formula unit with a net charge of 1+. The combination of two Al3+ ions and three O2- ions, though, is an electrically neutral formula unit: 2 (3+) + 3 (2-) = + 6 - 6 = 0 Therefore, the formula for aluminum oxide is Al2O3 . Gen. Chem. Chapter2 71 Polyatomic Ions Polyatomic ions are charged groups of covalently bonded atoms Gen. Chem. Chapter2 72 Hydrates A hydrate is an ionic compound in which the formula unit includes a fixed number of water molecules associated with cations and anions Examples: BaCl2 . 2 H2O CuSO4 . 5 H2O Gen. Chem. Chapter2 73 Acids • Taste sour • Turn blue litmus paper red • React with metals to form hydrogen gas • Neutralize a base IntroToAcids Gen. Chem. Chapter2 74 Bases • Taste bitter • Turn red litmus paper blue • Feel slippery on skin • Neutralize an acid IntroToBases Gen. Chem. Chapter2 75 Arrhenius Concepts Acids are compounds that ionize in water to form a solution of H+ ions and anions Bases are compounds that ionize in water to – form solutions of OH and cations Gen. Chem. Chapter2 76 Arrhenius Concepts Acids and bases react to form a salt and water = neutralization HCl + NaOH “Salt” + Water Acid Base NaCl HOH cation/anion Gen. Chem. Chapter2 77 Animation (3) & (4) : Acids, Bases Gen. Chem. Chapter2 78 Formulas and Names for Acids Binary acids start with hydro and end with “ic” plus the word acid Ternary acids simply use the polyatomic anion name with “ate” changing to “ic” plus the word acid Gen. Chem. Chapter2 79 Formulas and Names for Bases Arrhenius bases always have hydroxide ions The name follows ionic compound convention e.g., NaOH – sodium hydroxide Molecular bases form OH– after reacting with water NH3 + HOH NH4OH Ammonia ammonium hydroxide Gen. Chem. Chapter2 80 Formulas and Names for Salts Binary salts use the “ide” ending on the anion name e.g., sodium chloride Polyatomic salts use “ate” ending on the anion name e.g., sodium sulfate Gen. Chem. Chapter2 81 Gen. Chem. Chapter2 82 Organic Compounds • Organic Chemistry is the study of carbon and its compounds • Carbon compounds containing one or more of the elements H, O, N, or S are especially common • Most organic compounds are molecular compounds • Can exist as acids, bases, and salts • Compounds have systematic names AND common names Gen. Chem. Chapter2 83 Representations of Molecules Condensed Structural Formula CH3CH2CH3 Structural Formula Ball and Stick Gen. Chem. Chapter2 84 Saturated Hydrocarbons Hydrocarbons have only hydrogen and carbon atoms Saturated hydrocarbon: has the maximum number of hydrogen atoms possible for each carbon atom Alkanes are saturated hydrocarbons Methane (CH4) is the first molecule in the alkane series Gen. Chem. Chapter2 85 Prefixes for Number of Carbon Used for simple organic molecules Combined with alkane ending “ane” e.g., propane is a 3-carbon alkane Gen. Chem. Chapter2 86 Isomers Compounds with the same molecular formula but different structural formulas Gen. Chem. Chapter2 87 FIGURE 2.14 Butane and isobutane Ball-and-stick and structural models illustrate the difference between the two isomers of butane. Gen. Chem. Chapter2 88 Cyclic Alkanes Alkane compounds that have carbons arranged in a ring structure are called cycloalkanes. use the prefix cyclo- methylcyclopropane cyclohexane Gen. Chem. Chapter2 89 FIGURE 2.15 Cyclohexane The molecular and line-angle formulas for cyclohexane indicate the bonding of atoms within the molecule. The ball-and-stick model further indicates that all of the carbon atoms of the cyclohexane molecule do not lie in the same plane. Rather, it can assume several different arrangements or conformations. The most stable arrangement, shown here, is called the chair conformation because the six carbon atoms outline a structure that somewhat resembles a reclining chair. Gen. Chem. Chapter2 90 Functional Groups Specific groupings of atoms attached to a carbon chain that give the compound unique properties Most-common functional groups include: • • • • • Alcohols Ethers Carboxylic Acids Esters Amines Gen. Chem. Chapter2 91 Alcohols Alcohols are molecules that contain a hydroxyl group (OH) Gen. Chem. Chapter2 92 Alcohols Gen. Chem. Chapter2 93 Ethers Ethers are molecules in which two alkane groups (R-) are attached to a central oxygen atom The general formula is R-O-R´ R and R´ may be the same or different groups CH3CH2OCH2CH3 CH3CH2OCH2CH2CH3 Gen. Chem. Chapter2 94 Carboxylic Acids Carboxylic acids are alkanes that also contain a carboxyl group and are weak acids Acts like an Arrhenius acid, loses a hydrogen ion HCOO– + H+ Gen. Chem. Chapter2 95 Gen. Chem. Chapter2 96 Esters Esters are molecules in which two alkanes are attached to each side of a carboxyl group (R’-COO-R) Gen. Chem. Chapter2 97 Amines Amines are molecules in which alkanes and hydrogen(s) are attached to a central nitrogen Amines are weak bases NH2(CH2)4NH2 Gen. Chem. Chapter2 98 Summary of Concepts • The basic laws of chemical combination are the laws of conservation of mass, constant composition, and multiple proportions. • The three main subatomic particles are the protons, neutrons, and electrons. • Atoms with the same number of protons but different numbers of neutrons are called isotopes. • A chemical formula indicates the relative numbers of atoms of each type in a compound. Gen. Chem. Chapter2 99 Summary (cont.) • The periodic table is an arrangement of the elements by atomic number that places elements with similar properties into the same vertical group. • Ions are formed by the gain or loss of electrons. Positive ions are cations and negative ions are anions. • Many compounds are classified as either acids (H+), bases (OH–), or salts (neutralization of acid and base). • Organic compounds are based on the element carbon. • Functional groups confer distinctive properties on an organic molecule. Gen. Chem. Chapter2 100 Arrhenius Concepts Acids and bases react to form a salt and water = neutralization HCl + NaOH “Salt” + Water Acid Base NaCl HOH cation/anion Gen. Chem. Chapter2 101