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Energetics Do Now-QUIZ on separate sheet of paper- do not talk or use notes Place your HW on your desk 1. 2. 3. 4. Analyze why Carbon is unique Define polymer What is the monomer of proteins? Analyze a disaccharide? Carbon Properties • http://www.elementalmatter.info/carbon-properties.htm Carbon has 4 valence electrons; therefore, Carbon can bond to 4 other elements Carbon also readily bonds to other C, forming chains and rings=variety of organic compounds Carbon Bonding • Organic compounds- C attached to H • Inorganic compounds- typically do not have C, but if C, not attached to H Carbon’s 4 valence electrons • 8 valence electrons= stable • C has 4 valence (outer) electrons, so C readily forms 4 covalent bonds with other elements • Straight Chains, Branched Chains, Rings Carbon forms single, double, triple bonds Functional Groups • Influence bonding properties and other properties of molecules. • • • • Hydroxyl -OH Carboxyl -COOH Amino –NH2 Phosphate- POOOOHH Large Carbon Molecules • Start with: monomers • Simple molecules • Monomer+ monomer= polymer • Repeated, linked units • Large polymers= macromolecules Monomers link to form polymers Condensation Reactions • When monomers link to form polymers, a H2O molecule is released Hydrolysis Reactions • When polymers are broken down into monomers, H2O is added Condensation: building polymers Hydrolysis: breaking down polymers Thinking Map • Create a thinking map Do Now • Differentiate between condensation rxns and hydrolysis rxns • Trace the relationship between photosynthesis and cellular respiration Macromolecules 1. 2. 3. 4. Carbohydrates Lipids/Fats Proteins Nucleic Acids Recall: Remember Dust Bowl article? 1. Carbs • Monomer=saccharide • Carbon Hydrogen and Oxygen • 1C:2H:1O • Energy or structure • Monosaccharides, disaccharides, polysaccharides A. Monosaccharides • Simple sugar; monomer • Carbon:Hydrogen:Oxygen 1:2:1 • (CH2O)n n is 3-8 • EX (CH2O)6 C6H12O6 • • • • Most common: glucose, fructose, galactose Glucose= energy for cells Fructose= in fruits; sweetest Galactose= in milk Glucose, fructose, galactose • C6H12O6 • Same chemical formula but different structure= isomers Same chemical formula but different structure= isomers B. Disaccharides • Two monosaccharides combined through a condensation rxn • “double sugar” • Ex: fructose + glucose = sucrose • mono + mono = di C. Polysaccharides • Complex • 3 or more monosaccharides • Ex: animals store glucose as glycogen (chains of glucose in muscles and liver) Polysaccharides cont. • Plants store glucose as STARCH • Plants also have cellulose- strength and rigidity of plant cells 2. Proteins • Made of CHON mostly • Formed by linking amino acids • Enzymes, hair, horns, skin, etc Amino Acids • 20 • Structure: • central C, carboxyl group (-COOH), amino group (-NH2), side R-chain • Main difference is in R group: shape Amino acid Amino Acid Amino acid: note R group Amino acids • http://www.youtube.com/watch?v=9GzR-k7-dZ4 • http://www.youtube.com/watch?v=qBRFIMcxZNM Peptide • Amino acid covalently bound to another amino acid Polypeptide • Long chain of amino acids • protein Polypeptide formation • http://www.youtube.com/watch?v=lijQ3a8yUYQ Enzymes • RNA or protein • Biological catalysts- speed up chemical reactions by lowering activation energy Enzyme-Substrate Complex 1. Enzyme fits like lock and key to substrate at enzyme’s active site 2. Enzyme changes shape so bonds in substrate are weakened 3. Enzyme releases products 4. Enzyme is unchanged and can be used over and over again http://www.youtube.com/watch?v=V4OPO6JQLOE Temp and pH can change enzyme shape and enzyme won’t fit on substrate - no chemical rxn 3. Lipids • Monomer=fatty acid • Large, nonpolar, organic • Include: triglycerides, phospholipids, steroids, waxes, and pigments Fatty Acids • Unbranched Carbon chains • Have a carboxyl group (COOH) at one end • COOH end is hydrophilic-attracted to water • The Hydrocarbon end is nonpolar • Hydrophobic “hates water” Saturated VS Unsaturated Triglycerides (fats) • 3 fatty acids + glycerol Fats • Saturated • High melting points • Solid at room temp • EX: butter, fats in red meat • Unsaturated • Soft at room temp • Inside of seeds-energy and Carbon source for plant embryo (endosperm) Phospholipids • 2 fatty acids attached to a glycerol • Head=glycerol= loves water • Tails=fatty acids = hate water • Make up cell membrane: lipid bilayer Phospolipids Wax • Long fatty acid chain + long alcohol chain • Waterproof • Ex: cuticle; earwax Steroids • Hormones • testosterone • Cholesterol 4. Nucleic Acids • Store and transport information in the cell. • Monomer=nucleotides • Phosphate group, 5-C sugar, ring-shaped Nitrogenous base • 2 types • DNA • Deoxyribonucleic acid • RNA • Ribonucleic acid Phosphate group, 5-C sugar, ring-shaped Nitrogenous base Phosphate group, 5-C sugar, ring-shaped Nitrogenous base Nucleotide DNA • Determines characteristics of organisms and directs cell functions RNA • Stores and transfers information from DNA which is essential to making proteins Thinking Map • Create a thinking map of the 4 macromolecules and their subsets