Download Department of Chemistry - The City College of New York

The City College of New York
Department of Chemistry
Syllabus for Physical Chemistry 2
Spring 2010
Course:
Hours:
Location:
Instructor:
Text:
Chemistry 33200/L (Physical Chem. 2); Chemistry 33201/MM (Physical Chem. 2
Workshop)
Spring Semester (Jan. 28, 2010 – May. 17, 2010)
Lecture: M, W: 9:30 A.M. – 10:45 A.M.; Workshop: F: 9:30 A.M. – 10:50 A.M.
Lecture, MR-1; Workshop, MR-1307
Dr. Daniel L. Akins; Phone: (212) 650-6953; Email: [email protected]
Office: MR-1120; Laboratory: MR-1122, -1124 and -1111B
R. J. Silbey, R. A. Alberty and M. G. Bawendi, Physical Chemistry, John Wiley & Sons, Inc.,
4th Edition, 2005.
COURSE DESCRIPTION
Catalog Description:
Spectroscopy, quantum mechanics, and statistical thermodynamics. Students who feel that they would
benefit from workshops should also take Chem. 33201.
33200: Physical Chemistry 2
This course deals with some of the basic principles of quantum mechanics and its supplanting of classical
physics concepts in understanding atomic and molecular spectra as well as providing a means for
calculating thermodynamic functions through application of statistical thermodynamics, which relies on
analytical expression for quantum mechanical energies. Prereq.: Chemistry 33000 (Math 391 highly
recommended).
33201: Physical Chemistry 2 Workshop
(Optional workshop). Coreq.: Chem 33200. 1.5 hr/wk; 0 cr.
CHAPTERS TO BE COVERED
1.
2.
3.
4.
5.
6.
Quantum Theory: Introduction and Principles (Chap. 9)
Rotational and Vibrational Spectroscopy (Chap. 13)
Atomic Structure (Chap. 10)
Molecular Electronic Structure (Chaps. 11)
Electronic Spectroscopy of Molecules (Chap. 14)
Statistical Mechanics (Chap. 16)
Anticipated Exam Dates:
1st Exam (Chaps. 9 & 13):
2nd Exam (Chaps. 10 & 11):
3rd Exam (Chaps. 14 & 16):
Final Exam (Chaps. 9, 10, 11, 13, 14 and 16):
March 10, 2010
April 28, 2010
May 17, 2010
TBA
After completing this course, students should be able to:
1.
2.
Understand what the wavefunction means and how to interpret it.
Understand the concept of quantization and how it emerges as a
natural consequence of solving the Schrödinger equation and
applying boundary conditions.
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Dept outcome
letters
a,d,e
a
Akins, Chem. 33200
3.
4.
5.
6.
7.
Describe the internal states of atoms in terms of quantum
numbers.
Understand the concepts of orbitals and how they apply to both
atoms and molecules.
Become familiar with the concepts of rotational and vibrational
spectra in terms of their origins from solution of the quantum
mechanical wave equation, and also be able to apply selection
rules, which specify allowed transitions between quantum
mechanical states.
Use quantum mechanical energies as energy states in statistical
thermodynamic expressions dealing with the distribution of
particles over available energy states.
Utilize quantum mechanical energies to define partition functions,
which in turn can be used to calculate thermodynamic state
functions, such as entropy, enthalpy, etc.
a,d
a,d
a,d
a,d
Relationship of course to program outcomes:
The outcome of this course contribute to the following departmental educational outcomes:
a.
b.
c.
d.
e.
f.
g.
h.
i.
j.
k.
Demonstrate an understanding of the fundamental principles of
chemistry, including atomic and molecular structure, quantum
chemistry, chemical bonding, stoichiometry, kinetics and
mechanisms, equilibria, thermochemistry and thermodynamics,
molecular structure and function, electrochemistry, and the
periodic chemical properties of the elements.
Apply the fundamental principles of chemistry to life sciences, the
environment, materials, engineering, and emerging technological
fields of chemistry, as well as to everyday situations.
Conduct experiments and learn fundamental laboratory skills.
Analyze and interpret data.
Apply mathematical concepts to chemical problems.
Work as part of a problem-solving team.
Convey facts, theories and results about chemistry in written form.
Use oral presentation to convey facts, theories and results about
chemistry.
Access and utilize chemical information technology.
Design and execute scientific research.
Apply ethical responsibilities and professional conduct.
Course Objective
Numbers
1-7
5-7
5-7
5-7
6,7
Assessment tools:
Homework assignments (~ 3)
Quizzes (0)
Exams (4; including Final)
Course feedback survey (End of Course Survey) to be given randomly to selected students.
Grading:
There will be at least three one-hour exams and a final. Some students may be exempt from the
final based on class performance. One exam will be thrown out. The Final counts as two exams.
Grading is done on a curve defined by natural breaks between performance by students.
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Akins, Chem. 33200
A point basis for assigning grades will be followed. Special Problem sets will contribute about 10%
to the total point score for grading purposes.
Attendance Policy:
Three consecutive absences before the end of February will be grounds for an automatic drop from
the course. Special situations should be brought to my attention as soon as possible.
Office Hours:
I will hold office hours on Tuesdays from 2:00 P.M. until 4:00 P.M. I am, of course, available by
appointment and immediately after class.
References:
See Web materials and numerous Physical Chemistry textbooks.
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