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Chapter 5 | Molecular Orbitals
Chapter 5 | Molecular Orbitals

OPTICAL ISOMERISM
OPTICAL ISOMERISM

Section 2 Simple Molecular Orbital Theory
Section 2 Simple Molecular Orbital Theory

... than atomic orbitals and states (e.g., p orbitals or states are 3-fold degenerate, d's are 5fold, etc.). Increased orbital degeneracy, in turn, gives rise to more states that can arise from a given orbital occupancy (e.g., the 2p2 configuration of the C atom yields fifteen states, the π 2 configurat ...
Scanning angle total internal reflection Raman spectroscopy and
Scanning angle total internal reflection Raman spectroscopy and

Technical description of GLYDE-II 1 Supplemental Information
Technical description of GLYDE-II 1 Supplemental Information

SPECTROSCOPIC STUDIES OF SYNTHETIC AND
SPECTROSCOPIC STUDIES OF SYNTHETIC AND

... length/truncated edge length). Details of the experimental procedures and set up are given in Deon et al. (2008). As starting material, we used either oxide mixtures (FeO, MgO and SiO2) or synthetic fayalite, or a mixture of fayalite and oxides (MgO, SiO2). To produce different oxygen fugacities, ex ...
Quantum Dynamics and Statistical Mechanics of
Quantum Dynamics and Statistical Mechanics of

... followed second-order kinetics which is consistent with bimolecular models for the spin conversion, although the exact mechanism for such a process remains unclear. In another NMR study, they were able to observe level splitting in the ortho ground state, as well as an anisotropic interaction that d ...
Molecular Structure and Orbitals - Blackboard
Molecular Structure and Orbitals - Blackboard

Dynamic force spectroscopy and folding kinetics in molecular systems
Dynamic force spectroscopy and folding kinetics in molecular systems

... 5.3 Dynamic properties of intermediate states . . . . . . . . . . . . . . . . 5.3.1 A single intermediate state . . . . . . . . . . . . . . . . . . . . 5.3.2 Several molecular intermediate states . . . . . . . . . . . . . . . 5.4 Specific binding of a peptide intercalating DNA . . . . . . . . . . . ...
Optical Properties of Semiconductor Nanocrystals
Optical Properties of Semiconductor Nanocrystals

Ab initio Calculations of Optical Rotation
Ab initio Calculations of Optical Rotation

Computer simulation of the dynamics of aqueous solvation
Computer simulation of the dynamics of aqueous solvation

THEORETICAL DESCRIPTION OF ELECTRONIC EXCITATIONS IN
THEORETICAL DESCRIPTION OF ELECTRONIC EXCITATIONS IN

theories of intramolecular vibrational energy transfer
theories of intramolecular vibrational energy transfer

Optical Spectroscopy of Spin Ladders
Optical Spectroscopy of Spin Ladders

Matrix Isolation Spectroscopic and Theoretical Study of Carbon
Matrix Isolation Spectroscopic and Theoretical Study of Carbon

Fluorescence of coumarins and xanthenes after two
Fluorescence of coumarins and xanthenes after two

Quantum Wavepacket Dynamics in Molecular and Trapped Ion Systems  Dong Wang
Quantum Wavepacket Dynamics in Molecular and Trapped Ion Systems Dong Wang

Raman spectroscopy of graphite - Institut für Festkörperphysik
Raman spectroscopy of graphite - Institut für Festkörperphysik

Get cached PDF
Get cached PDF

Liquid Mixtures Involving Hydrogenated and Fluorinated Alcohols
Liquid Mixtures Involving Hydrogenated and Fluorinated Alcohols

Rydberg-Stark deceleration of atoms and
Rydberg-Stark deceleration of atoms and

Competing Intramolecular vs. Intermolecular Hydrogen Bonds in
Competing Intramolecular vs. Intermolecular Hydrogen Bonds in

Quasiclassical and semiclassical calculations on reactions with oriented molecules cos β
Quasiclassical and semiclassical calculations on reactions with oriented molecules cos β

Introduction - St. Olaf College
Introduction - St. Olaf College

1 2 3 4 5 ... 53 >

Rotational spectroscopy



Rotational spectroscopy is concerned with the measurement of the energies of transitions between quantized rotational states of molecules in the gas phase. The spectra of polar molecules can be measured in absorption or emission by microwave spectroscopy or by far infrared spectroscopy. The rotational spectra of non-polar molecules cannot be observed by those methods, but can be observed and measured by Raman spectroscopy. Rotational spectroscopy is sometimes referred to as pure rotational spectroscopy to distinguish it from rotational-vibrational spectroscopy where changes in rotational energy occur together with changes in vibrational energy, and also from ro-vibronic spectroscopy (or just vibronic spectroscopy) where rotational, vibrational and electronic energy changes occur simultaneously.For rotational spectroscopy, molecules are classified according to symmetry into spherical top, linear and symmetric top; analytical expressions can be derived for the rotational energy terms of these molecules. Analytical expressions can be derived for the fourth category, asymmetric top, for rotational levels up to J=3, but higher energy levels need to be determined using numerical methods. The rotational energies are derived theoretically by considering the molecules to be rigid rotors and then applying extra terms to account for centrifugal distortion, fine structure, hyperfine structure and Coriolis coupling. Fitting the spectra to the theoretical expressions gives numerical values of the angular moments of inertia from which very precise values of molecular bond lengths and angles can be derived in favorable cases. In the presence of an electrostatic field there is Stark splitting which allows molecular electric dipole moments to be determined.An important application of rotational spectroscopy is in exploration of the chemical composition of the interstellar medium using radio telescopes.
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