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Transcript
Review for Exam #1-Chemistry 139
This is a guide for study. There may be additional material not listed here that will appear on the
exam. Also study your text notes, lecture notes, and problems.
Classification of Matter: Mixtures (Homogeneous and Heterogeneous) and Pure Substances
(Compounds and Elements)
Physical and Chemical Properties of Matter
Uncertainty: Accuracy vs. Precision, Significant Figures in Calculations and Measurements
Metric Prefixes
Unit or Dimensional Analysis
The Laws of Conservation of Mass and Energy
The Law of Definite Proportion (or Constant Composition)-Originally based on mass ratios not
atomic ratio
Dalton’s Theory of the Atom
The Law of Multiple Proportions-Predicted by Dalton’s Theory
The Nuclear Atom: proton (+), electron (-), neutron (0)
Isotopes (Neutral and Ionic): Atomic Number, Mass Number, Symbol
Weighted Average Mass
Electrostatics
Energy-Potential and Kinetic and Thermal
Transfer of Energy-work and heat
Exothermic-chemical system loses heat to the surroundings
Endothermic-chemical system gains energy from the surroundings
Electrons have Both Wave Characteristics (Electrons can be Diffracted by Crystals) and Particle
Characteristics (Electrons have Mass and Momentum)
Electromagnetic Radiation (Light) has Both Wave Characteristics (Waves can be Diffracted by
Crystals) and Particle Characteristics (Photons have Momentum, but No Mass)
Emission spectra of elements demonstrate that the energy of electrons is quantized-discrete bands of
light relate directly to discrete jumps of electrons from high energy to low energy.
The Bohr Model of the Nuclear Atom (1 electron atoms only)
Traveling Waves Transfer Energy, Standing Waves Store Energy
If Electrons have Wave Characteristics and Their Energy is Quantized then Electrons can be
described as Standing Waves Containing Discrete Amounts of Energy.
The Energy is Stored until the Electron Absorbs a Photon of Particular Energy OR until the
Electron Emits a Photon of Particular Energy.
Absorption or Emission Results in the Electron Moving to a New Energy Level.
The Heisenberg Uncertainty Principle
A Solution for the Energy/Position of an Electron in an Atom is a Wavefunction (Ψ). There are
Many Solutions for an Electron’s Energy/Position. These Solutions are called Orbitals.
Ψ2 (The Electron Probability Density) is More Physically Comprehendible than Ψ: This allows us to
see where the Electron Density at a Given Point is the Greatest OR where we are Most Likely to Find
an Electron of a Particular Energy Around its Nucleus.
Know the Shapes of the s, p, and d Orbitals
The Principle Quantum Numbers: n, l, ml, ms
Electron Configurations for Groundstate Atoms or Ions (longhand and core notations)
Orbital Energy Filling Diagrams for Groundstate Atoms or Ions
A Periodic Trend is Based on a Similar Number of Valence Electrons
The Periodic Table: Groups and Periods, metals, non-metals, metalloids, alkali metals, alkaline
earth metals, chalgogens, halogens, noble gases