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Simple Ions: complete the following table Ion Name 1 chloride 2 fluoride Number of Protons Number of Electrons Cl- 17 18 1 gained 9 10 Ca2 + 3 4 Ion Symbol Number of Electrons gained or lost lost 1 5 16 none 21 36 53 nitride 12 56 13 15 54 gains 3 Al3 + 14 science10 xenon K+ 10 15 18 selenide 9 11 18 H+ 7 8 Argon 20 rubidium 6 Electron Structure same as which Noble gas oxide 10 page 1 Ionic Compounds- complete the following table Ionic Charges e.g. Ba2 + , Cl1. Chemical Formula BaCl2 (s) Name of Compound barium chloride CaCl2(s) 2. magnesium chloride 3. potassium fluoride 4. NaCl (s) 5. CdS (s) lithium nitride 6. 7. GeBr4 (s) 8. K3N(s) 9. strontium phosphide 10. magnesium arsenide 11. 12. In2O3 (s) Ba3As2 (s) 13. scandium oxide 14. calcium oxide 15. Al2O3(s) 16. ZnO (s) 17. silver sulfide 18 beryllium hydride 19. science10 Ga2Se3 (s) page 2 Multivalent Ionic Compounds- complete the following table Ionic Charges e.g. Cr2 + , Cl1. Chemical Formula CrCl2(s) Name of Compound chromium (II) chloride CuCl2(s) 2. manganese (IV) chloride 3. titanium (III) fluoride 4. SnO2(s) 5. FeS(s) 6. copper (I) nitride 7. MoBr6(s) 8. PbO2(s) 9. vanadium (IV) phosphide platinum (II) arsenide 10. 11. Hg2O(s) 12. Ni3As2(s) 13. stannic oxide 14. mercurous oxide 15. Fe2O3(s) 16. Cu3P2(s) 17. gold (III) sulfide 18. tin (II) chloride 19. science10 Co2Se3(s) page 3 Nomenclature involving Polyatomic Ions Chemical Formula 1 2 3 Name of Compound K2CO3(s) (NH4)2S(s) calcium hydroxide magnesium silicate 4 5 Cr(NO3)3 (s) iron (II) chlorate 6 7 8 Sr(NO3)2 (s) NaNO2 (s) 9 ammonium sulfate sodium bicarbonate 10 11 12 K3PO4 (s) (NH4)3PO4 (s) calcium sulphite 13 14 KMnO4 (s) 15 sodium thiosulfate 16 barium chlorate 17 sodium hydrogen sulfide 18 Ca(HS)2 (s) potassium cyanide 19 20 NH4H2PO4(s) sodium thiocynate 21 22 platinum (IV) sulfate zinc iodate 23 mercurous nitrate 24 science10 page 4 Naming Molecular Compounds Molecular Formula 1 CCl4(l) 2 CO2(g) 3 NO2(g) 4 NO(g) 5 SO3(g) 6 P4O10 Name argon 7 8 CH4(g) sucrose 9 10 H2O(l) 11 HCl(g) 12 sulfur 13 methanol 14 hydrogen peroxide 15 ammonia 16 ethanol 17 ozone diphosphorus decaoxide 18 trinitrogen heptachloride 19 20 chlorine 21 phosphorus 22 dinitrogen tetrabromide 23 nitrogen tetraphosphorus hexachloride 24 science10 page 5 Name the following : Acids and Bases 1. HBr (g) ____________________ 2. HNO3 (aq) ____________________ 3. HI(aq) ____________________ 4. HCN (g) 5. H3PO4(aq) __________________ 6. HOOCCOOH(aq) _____________ 7. HIO3(aq) ___________________ 8. HNO2(aq) ___________________ 9. HClO3(aq)___________________ 10. H2SO3(aq)____________________ 11. KOH(aq) ____________________ 12. Ba(OH)2(aq)___________________ 13. Sr(OH)2 (aq)___________________ 14. LiOH (aq) ____________________ ____________________ Write the formula for each of the following: 1. nitric acid ____________________ 2. hydrofluoric acid________________ 3. ammonia ____________________ 4. sodium hydroxide_______________ 5. hypochlorous acid__________________ 6. iron(II) hydroxide_______________ 7. sulfuric acid___________________ 8. hydrogen acetate________________ 9. hydrosulfuric acid_______________ 10. calcium carbonate________________ List three (3) properties of acids. List three (3) properties of bases. science10 page 6 Science 10 Chemistry Write the following formulas. 51. Sodium dichromate 52. Iron metal 53. Hydrogen nitrate 54. Nitrogen gas 55. Magnesium bisulphate 56. Cobalt (II) chlorate 57. Mercury(II) chloride 58. Silicon dioxide 59. Sodium chlorate 60. Hydrogen sulfate 61. Fluorine gas 62. Sodium hydrogen phosphate 63. Aluminum sulfide 64. Chromic oxalate 65. Rubidium nitrite 66. Hydrogen iodide 67. Ammonium hydrogen sulfite 68. Beryllium borate 69. Barium phosphate 70. Xenon gas 71. Carbon tetrachloride 72. Calcium acetate 73. Lithium hydrogen carbonate 74. Water 75. Copper(I) thiocyanate 76. Mercury(I) acetate 77. Silver thiocyanate 78. Sodium oxide 79. Iron(III) carbonate 80. Magnesium hydride 81. Potassium oxalate 82. Gold(III) nitrate 83. Lithium dihydrogen phosphate 84. Iron(III) oxalate 85. Iron(II) hydroxide 86. Helium gas 87. Ammonia 88. Cadmium acetate 89. Nickel metal 90. Selenium tetrafluoride 91. Hydrogen carbonate 92. Boron trihydride 93. Manganese(II) iodate 94. Strontium sulfite 95. Neon gas 96. Iron(III) cyanide 97. Lithium hydride 98. Ammonium carbonate 99. Xenon hexafluoride 1. Silver chloride 2. Cupric iodide 3. Zinc sulphate 4. Ammonia 5. Strontium fluoride 6. Potassium cyanide 7. Aluminum nitrate 8. Mercury(I) sulphide 9. Sulphur 10. Potassium chromate 11. Potassium nitrite 12. Silver hydroxide 13. Lead (II) nitrate 14. Iron(III) hydroxide 15. Oxygen gas 16. Sulphur trioxide 17. Sodium iodate 18. Aluminum nitrite 19. Sodium hydride 20. Tin(II) bicarbonate 21. Iron (III) sulphate 22. Sodium thiocyanate 23. Cesium borate 24. Mercury 25. Zinc fluoride 26. Barium hydrogen carbonate 27. Tin(IV) sulphate 28. Strontium borate 29. Hydrogen peroxide 30. Nitrogen dioxide 31. Aluminum hydrogen sulfite 32. methane 33. Potassium chlorate 34. Zinc phosphate 35. Lead(IV) iodate 36. Ammonium chlorate 37. Chromium(II) oxide 38. Mercury(I) cyanide 39. Calcium nitrate 40. Bromine liquid 41. Tin(IV) permangante 42. Aluminum oxide 43. Calcium sulphide 44. Iron(III) iodide 45. Magnesium hydroxide 46. Sodium iodate 47. Calcium silicate 48. Glucose 49. Magnesium cyanide 50. Sodium metal science10 page 7 Write the name for each of the following. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. AgI(s) CCl4(l) CuSO4(s) MgO(s) NaCN(s) PCl5(s) Fe(NO3)2(s) (NH4)2SO4(s) SO2(s) Cu2SO4(s) Fe(NO3)3(s) NaBr(s) K2OOCCOO(s) RbSCN(s) AlPO4(s) K2CO3(s) Na3PO4(s) SnSO4(s) Na2CrO4(s) Pb(NO3)2(s) Sn(SO4)2(s) WF6(s) SO3(g) K2Cr2O7(s) Pb(CO3)2(s) Na2HPO4(s) Al2(CO3)3(s) Au(CN)3(s) KMnO4(s) SrH2(s) KHCO3(s) Al2S3(s) Cu(CH3COO)2(s) Ba(SCN)2(s) NaClO3(s) science10 36. 37. 38. 39. 40. 41. 42. 43 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. Fe(OH)2(s) Na3BO3(s) C8H18(l) V2S5(s) Fe(OH)2(s) SnF2(s) CH3OH(l) Zn(NO2)2(s) Ag2CrO4(s) KCH3COO(s) NH4OH(s) O3(g) Cu2S(s) HgCr2O7(s) RbI(s) NH4IO3(s) MoCl6(s) NaHS(s) CsH2PO4(s) NaOH(s) Ni(SCN)2(s) Pb(HSO4)4(s) Hg(NO3)2(s) Na2O(s) RbH(s) C6H12O6(s) NI3 MnS2(s) Li2CrO4(s) Li2O(s) Na2SO3(s) Zn(CH3COO)2(s) H2S(g) C4H10(s) CsHCO3(s) page 8 71. 72. 73. 74. 75. 76. 77. 78. 79. 80. 81. 82. 83. 84. 85. 86. 87. 88. 89. 90. 91. 92. 93. 94. 95. 96. 97. 98. Ca(ClO4)2(s) NH4ClO(s) CrO(s) CsCN(s) H2(g) S8(s) MnO(s) Ca(OH)2(s) CoCl2(s) Zn(IO3)2(s) PtCl4(s) Hg(NO2)2(s) HCl(g) Cr2O3(s) Al(OH)3(s) (NH4)3BO3(s) NaCl(s) KrF4(g) BaCr2O7(s) Sr3(PO4)2(s) Fe2O3(s) (NH4)2HPO4(s) NaCH3COO(s) Fe(CH3COO)2(s) PbCO3(s) BeSiO3(s) XeO2(g) Hg(NO3)(s) A. B. Classification of Matter Types of Matter 1. Identify and define the types of pure substances. 2. Identify and define the two main types of mixtures. Chemical vs Physical Properties 1. Identify the difference between a chemical and a physical change. Periodic Table Patterns 1. Identify the four basic patterns found on the periodic table. a. Classify silicon,rubidium and krypton according to these patterns. 2. Which group numbers are alkali metals, noble gases and halogens? 3. Why is silicon called a metalloid? Atomic Structure Subatomic particles 1. Identify the three major subatomic particles and their charges. 2. Calculate the number of each particle for the following: a. beryllium atom b. bromine atom c. sulfide ion d. barium ion e. tungsten atom f. nitride ion Theories 1. identify the theories and their authors represented by the following: a. atom looks like this b. atom looks like a planetary system c. the electrons move around the nucleus in an unknown path. d. key was the “Gold foil experiment”. Ions 1. Why do ions form? 2. Draw the Bohr diagram for the atom and the ion for each of the following: a. lithium b. oxygen c. carbon d. chlorine e. calcium f. argon science10 page 9 Compounds Binary Ionic 1. consist of a metal and a nonmetal (cation and an anion) 2. charges must balance in the final formula to form a neutral compound 3. List the characteristics of an ionic compound. 4. Write the formula for the following: a. lithium chloride b. magnesium fluoride c. scandium sulfide d. calcium nitride e. aluminum phosphide 5. Name the following: a. KBr(s) b. BaI2(s) c. Ga2S3(s) d. MgO(s) e. GeSe2(s) Multivalent Metals 1. metals that can form more than one value of ionic charge 2. named using the Stock system or the Classical system a. describe each naming system 3. Write the formula for the following: a. copper (I) oxide b. nickel (III) sulfide c. manganese (IV) oxide d. yttrium (III) chloride e. titanium (III) nitride 4. Name the following: a. FeO(s) b. CoF2(s) c. V3N5(s) d. Cr3P2(s) e. MgS(s) Complex Ions 1. groups of atoms that remain together in a chemical reaction and contain a charge 2. names usually end in ‘ate’ or ‘ite’ 3. Write the formula for the following: a. sodium nitrate b. iron (II) hydroxide c. barium sulfate d. cuprous chlorate e. ammonium silicate 4. Name the following: a. KClO3(s) b. Ca(OH)2(s) c. Fe2(CrO4)3(s) d. Mn5(P3O10)2 (s) e. NaC6H5COO (s) science10 page 10 5. Use the variations of complex ions. a. NO3- = nitrate, NO2- = nitrite , NO- = hyponitrite , NO4- = pernitrate b. Name the following: i) NaNO2 (s) ii) KClO4 (s) iii) Ca(IO)2 (s) c. Write the formula for the following: i) barium phosphite ii) chromium (II) percarbonate iii) iron (III) hypobromite Molecular Compounds 1. Composed of only nonmetals. 2. Use the prefixes to indicate the number of atoms present in the molecule. 3. Name the following: a) N2O (g) b) P2O6 (g) c) PCl5 (s) 4. Write the formula for each of the following: a) carbon monoxide b) sulfur dibromide c) triphosphorus heptaoxide 5. Write the formula and name the common molecular compounds given in class. Acids and Bases 1. List the characteristics of an acid. 2. List the characteristics of a base. 3. Write the formula for the following: a) hydrochloric acid b) phosphoric acid c) carbonous acid d) hydrofluoric acid e) nitric acid 4. Write the name for each of the following: a) H3N (aq) b) HClO4 (aq) c) HNO2 (aq) d) H2Se (aq) e) C6H5COOH (aq) GOOD LUCK ON THE EXAM science10 page 11 Introduction to Balancing Chemical Reactions For each of the following count the number of moles of atoms of each element on each side of the yield( -->) sign, if they balance fine, if not, put in the correct numbers of moles required. Example : Rocket fuel is burned in a Saturn rocket. 2H2(g) + O2 (g) ---> 2H2O(g) #H = 4 , #O = 2 1. CH4 (g) + --> 2O2(g) #H = 4 , #O = 2 ---> CO2(g) + 2H2O(g) #C = , #H = ,#O = ---> #C = , #H = ,#O = 2. H2(g) ---> + Cl2(g) 2HCl(g) #H = , #Cl = ---> #H = , #Cl = 3. N2(g) ---> 2NH3(g) + 3H2(g) #N = , #H = ---> #N = , #H = Try to balance these. 4. ___H2O2(l) ---> #O = , #H = 5. ___NO (g) #O = , #N = ___H2O(g) + ___O2(g) ---> #O = , #H = + ___O2 (g) ---> ___NO2 (g) ---> #O = , #N = 6. ___Zn (s) + ___S8 (s) ---> ___ZnS (s) #Zn = , #S = ---> #Zn = , #S = science10 page 12 Formation & Decomposition Reactions Balance the following formation reactions by filling in the blanks. 1. ____ C (s) + ____ O2(g) ----> _____ CO2(g) 2. ____ Ba (s) + ____ N2 (g) ----> _____ Ba3N2 (s) 3. ____ Ga (s) + ____ As (s) ----> ____ GaAs (s) 4. ____ K (s) + ____ S8 (s) ----> ____ K2S (s) 5. ____ Na (s) + ____ Cl 2(g) ----> ____ NaCl (s) Balance the following decomposition reactions by filling in the blanks. 1. _____H2O (l) ----> ____H2 (g) + ____ O2 (g) 2. _____ Li3N (s) ----> ____ Li (s) + ____ N2 (g) 3. _____ CO2 (g) ----> ____ C (s) + ____ O2 (g) 4. _____ HCl (aq) ----> ____ H2 (g) + ____ Cl2 (g) 5. _____ TiI4 (s) ----> _____ Ti (s) + ____ I2 (g) science10 page 13 Write and balance the following equations. 1. Aluminum metal plus chlorine gas produces aluminum chloride 2. Magnesium metal plus oxygen gas produces magnesium oxide 3. Sulfur plus oxygen gas produces sulfur dioxide 4. Copper metal reacts with sulfur to form copper (II) sulfide 5. Nitrogen gas reacts with hydrogen gas to form ammonia 6. Methane gas decomposes to its elements 7. Iron (II) bromide decomposes to its elements. 8. Mercury (I) sulfide decomposes to its elements. 9. Tetraphosphorous decaoxide decomposes to its elements. 10. Sucrose decomposes to its elements. science10 page 14 Fill in the blanks and balance the following formatiom and decomposition reactions. The word equation is on top and the chemical equation is underneath it. 1. nickel metal ___ 2. + _________ _____ + ____ sodium oxide nitric acid S8 (s) ---->____ Ni2S3 (s) ----> sodium ____ ________ 3. ----> ___________________ + ______ ---->____ _____ ----> hydrogen chromium metal 6. N2 (g) + ___ O2 (g) + ____ _______ ----> ____ ____________ manganese (IV) chloride ----> _________ + ___________ ____ ----> ___ + ____ _____________ ____________________ -----> ___ 7. + ___ + __________ + white phosphorous ----> chromium (III) phosphide ____ ________ 5. O2(g) + _________ ____ _________ ---->___ H2 (g) 4. + ___ Pb3N4 (s) ----> ___ Mn (s) lead metal Cl 2(g) + ________ ________ + ___ N2 (g) lead metal + ____________________ ----> plumbous selenide ___ ________ + science10 ____ Se (s) ----> ____ ___________ page 15 8. gold + sulfur ----> ____________ ____ ______ + ____ _____ ----> ____ 9. silver chloride ----> silver metal ____ ________ ---->____ 10. 11. _____ Au2S (s) + chlorine gas + ____ ______ carbon + chlorine gas ----> ____________________ ____ ____ + ____ __________ _______ ---->____ CCl4 (l) ----> iron metal + nitrogen gas + oxygen gas ____Fe(NO3)3 (s) ---->____ ____ + ____ _______ + ____ ________ 12. silver metal + iodine solid -----> ________________ ____ ________ +____ _______ ----> _____ AgI (s) 13. __________ + sulfur ----> _____________ ____Cu (s) +____ ______ -----> _____ Cu2S (s) 14. xenon hexafluoride ----> ________ + _________ ____ ________ 15. -----> ___ ______ + ____ _____ methane gas ----> _______________ + ______________ ____CH4(g) science10 ----> ____C(s) + ____ H2 (g) page 16 Single Replacement Reactions Balance the following equations by writting in the SIMPLEST WHOLE NUMBER coefficients in the space provided. Give the word equation for each (names of elements and compounds involved). 1. _____ K(s) + _____ HNO3(aq) -------> _____ H2(g) + _____ KNO3(aq) word equation: 2. _____ Na(s) + _____ HOH(l) -----> _____ H2(g) + _____ NaOH(aq) word equation: 3. _____ Al(s) + _____ Fe2O3(s) -----> _____ Fe(s) + _____ Al2O3(s) word equation: 4. _____ K(s) + _____ AlCl3(s) -----> _____ Al(s) + _____ KCl(s) word equation: 5. _____ Cl2(g) + _____ MgBr2(aq) -----> _____ Br2(l) + _____ MgCl2(aq) word equation: 6. _____ H2S(g) + _____ Ag(s) ----> _____ Ag2S(s) + _____ H2(g) word equation: 7. _____ Ca(s) + _____ Ag2SO4(aq) ----> _____ CaSO4(s) word equation: + _____ Ag(s) 8. _____ Al(s) + _____ Pb(NO3)2(aq) ----> _____ Al(NO3)3(aq) + _____ Pb(s) word equation: 9. _____ Zn(s) + _____ Cu(NO3)2(aq) ----> _____ Zn(NO3)2(aq) + _____ Cu(s) word equation: science10 page 17 10. _____ Cl2(g) + _____ NaI(aq) ----> _____ NaCl(aq) + _____ I2(s) word equation: 11. _____ Cu(s) + _____ HNO3(aq) ----> _____ Cu(NO3)2(aq) + _____ H2(g) word equation: 12. _____ K(s) + _____ H3PO4(aq) ----> _____ H2(g) + _____ K3PO4(aq) word equation: 13. _____ Mg(s) + _____ Zn3(PO4)2(aq) ---->_____ Zn(s) + _____ Mg3(PO4)2(aq) word equation: 14. _____ Cr2(SO4)3(aq) + _____ Pt(s) ----> _____ Cr(s) + _____ Pt(SO4)2(aq) word equation: 15. _____ __________ word equation: gallium nitrate + _____ _________ ----> _____ HgNO3(aq) + _____ Ga(s) + mercury ---> ______________ + ___________ 16. _____ __________ + _____ ________---->_____ (NH4) 2S(aq)+_____ P4(s) word equation: ammonium phosphide solution + sulphur ----> ____________ + ____________ 17. _____ Sc(MnO4)3(aq) + _____ ________-----> _____ _______________+_____ Sc(s) word equation: ___________ + nickel ---->nickel (II) permanganate + ________ science10 page 18 Balancing Double Replacement Reactions For the following reactions include the formulas, balancing, and phases for all reactions. Balancing using the simplest whole number coefficients. 1. _____ CuCl2(aq) + _____ K2S(aq) ---> _____ KCl(aq) + word equation: _____ CuS(s) 2. _____ MnCl4(aq) + _____ NiBr3(aq) ---> _____ MnBr4(aq) + _____ NiCl3(aq) word equation: 3. _____ Au2S3(aq) + word equation: 4. _____ InI3(aq) + word equation: _____ MgF2(aq) ---> _____ AuF3(aq) + _____ FeO(aq) ---> _____ FeI2(aq) + _____ MgS(s) _____ In2O3(aq) 5. _____ PuN2(aq) + _____ VAt5(aq) ---> _____ PuAt6(aq) + word equation: _____ V3N5(aq) 6. _____ _____________+ _____ ______________---> _____ ________+ _____ ______ Word equation: magnesium phosphide (aq) + cobalt (II) sulfide solution ---> magnesium sulfide solid + cobalt (II) phosphide solution 7. _____ ____________+ _____ _______________---> _____ __________+ _____ _____ Word equation: copper (II) bromide (aq) + gold (III) arsenide solution ---> copper (II)arsenide solution + gold (III) bromide (aq) 8. _____ NH4Br(aq) + _____ Hg3N(aq) ---> _____ (NH4)3N(aq) + _____ HgBr(s) Word equation: 9. _____ HgS(aq) + _____ NH4OH(aq) ---> _____ Hg(OH)2(s) + Word equation: science10 page 19 _____ (NH4)2S(aq) 10. __ Zn(CH3COO)2(aq) + __ NH4OH(aq) ---> __Zn(OH)2(s) Word equation: 11. __ Co(IO3)3(aq) + Word equation: __ Na2SO4(aq) ---> __ Co2(SO4)3(aq) + + __ NH4CH3COO(aq) __ NaIO3(aq) 12. __ _______________+ __ ___________---> __ ________+ __ _________ Word equation: solution of lead (IV) nitrate + solution of gold (III) chloride---> aqueous gold (III) nitrate + aqueous lead (IV) chloride 13. __ _______+ __ ________---> __ ________+ ___ _________ Word equation: hydrochloric acid poured into aqueous lead (IV) nitrate to produce aqueous lead (IV) chloride and nitric acid 14. __ ________+ __ _________---> ___ ________+ ___ _________ Word equation: magnesium hydrogen phosphate solution reacts with aqueous sodium iodide to yield magnesium iodide solution and aqueous sodium hydrogen phosphate 15. __ __________+ __ _________---> __ __________+ __ ____________ Word equation: aqueous zinc sulphate is mixed with a solution of ammonium phosphate to produce ammonium sulfate solution and zinc phosphate precipitate 16. __ __________+ __ _________---> __ _________+ ___ ___________ Word equation: solid sodium carbonate is stirred into a solution of iron (III) nitrate to yield sodium nitrate solution and iron (III) carbonate precipitate 17. __ __________+ __ __________---> __ ___________+ ___ ___________ Word equation: aluminum sulphate solution is poured into a barium hydroxide solution to yield two solids: barium sulphate and aluminum hydroxide 18. __ _____________+ __ ____________---> __ __________+ __ ____________ Word equation: solution of ammonium borate reacts with solid palladium (IV) dihydrogen phosphate to produce ammonium dihydrogen phosphate solution and palladium (IV) borate science10 page 20 Hydrocarbon Combustion Hydrocarbons are compounds that contain carbon, hydrogen and sometimes oxygen. When they combust (burn) they are reacting with oxygen and they always produce carbon dioxide gas and water vapour. Balanace in the order of carbons, hydrogens and finally oxygens (CHO). ex. methane is combusted. ___CH4 (g) + ___O2 (g) ---> ___CO2 (g) + ___H2O (g) 1. Propane reacts with oxygen in a barbeque. 2. Butane is combusted in a disposable lighter. 3. Pentane (C5H12) is burned. 4. C6H10 (hexyne) + O2 (g) ---> 5. Methanol is burned as part of automobile fuel ( gasline antifreeze ) 6. Ethanol is part of Mohawk gasoline and is combusted in your automobile engine. 7. C3H7OH (g) (propanol) + O2 (g) ---> 8. C4H9OH (g) (butanol) + O2 (g) ---> 9. Benzene (C6H6) reacts with oxygen. 10. Glucose is metabolized (burned) in the body. Note: The water that is produced will usually be liquid in the body. 11. Sucrose is combusted. Note: The water that is produced will usually be liquid in the body. science10 page 21 Balancing Equations : All Types Balance the following equations and indicate the type of reaction. 1. __Ca(OH)2 (aq) + __H3PO4 (aq) --> __HOH(l) + __Ca3(PO4)2 (s) Reaction type _____ 2. ___Al(OH)3 (s) + __HCl (aq) --> __AlCl3 (aq) + __HOH(l) Reaction type _____ 3. ___AgNO3 (aq) + __H2SO4 (aq) --> __Ag2SO4 (s) + __HNO3 (aq) Reaction type _____ 4. ___Cr (s) + __S8 (s) --> __Cr2S3(s) Reaction type _____ 5. ___KClO3 (s) --> __KCl(s) +___O2(g) Reaction type _____ 6. ___Zn(s) + __HCl(aq) --> __ZnCl2(aq) + __H2 (g) Reaction type _____ 7. ___Au2S3 (aq) + __H2(g) --> __Au(s) + __H2S(aq) Reaction type _____ 8. ___Ca(s) + __HOH(l) --> __Ca(OH)2 (aq) + __H2 (g) Reaction type _____ 9. ___Pb(NO3)2(aq) + __H3AsO4(aq) --> __PbHAsO4 (s) +__HNO3(aq) Reaction type _____ 10. ___NaCl (aq) + __HOH (l) --> __Cl2(g) + __H2(g) + __NaOH(aq) Reaction type _____ 11. ___Fe2O3 (s) + ___Al(s) --> ___Fe (s) + ___Al2O3 (s) Reaction type _____ 12. ___Al(s) + __NH4ClO4(s)--> __Al2O3(s) + __AlCl3(s) + __NO(g) + __HOH(l) Reaction type _____ 13. ___NO2 (g) + ____HOH(l) --> ____HNO3(aq) + ____NO(g) Reaction type _____ 14. ___Ca3(PO4)2 (s) +____ H2SO4 (aq) --> ___CaSO4 (s) +__ H3PO4 (aq) Reaction type _____ science10 page 22 More Practice on Balancing Equations Balance the following equations by filling the simplest whole number coefficient in the space provided. Identify the reaction type as formation (f), decomposition (d), single replacement (sr), double replacement (dr), hydrocarbon combustion (hc) or other (o). Reaction Equation Reaction Type 1. ___ Al (s) + ___ O2 (g) ---> ___ Al2O3 (s) ____ 2. ___HCl (aq) + ___ Ca(OH)2 (aq) ---> ___ HOH(l) + ___CaCl2 (aq) ____ 3. ___CH4 (g) + ___O2 (g) ---> ___ CO2 (g) + ___H2O(l) ____ 4. ___Zn(s) + ___Pb(CH3COO)2 (aq) ---> ___Pb(s) + ___Zn(CH3COO)2 (aq) ____ 5. ___SO3 (g) + ___H2O(l) ---> ___H2SO4 (aq) ____ 6. ___HgO(s) ---> ___Hg(s) + ___O2 (g) ____ 7. ___CaCO3 (s) ---> ___ CaO(s) + ___CO2 (g) ____ 8. ___NaI (aq) + ___Pb(NO3)2 (aq) ---> ___PbI2 (s) + ___ NaNO3 (aq) ____ 9. ___Cl2 (g) + ___NaI (aq) ---> ___I2 (aq) + ___ NaCl (aq) ____ 10. ___Al2(SO4)3 (aq) + ___Ca(OH)2 (aq) ---> ___Al(OH)3 (s) +___CaSO4 (s) ____ 11. __Al2(SO4)3 (aq) + ___Ca(HCO3)2 (aq) ---> __Al(OH)3 (s) + __CaSO4 (s) +__CO2 (g) ____ Predict the Products of the following reactions and balance the equations. 12. ___C8H18 (l) + ___ O2 (g) ---> 13. H2O (l) ---> 14. ___Na(s) + ___ Cl2 (g) ---> 15. ___Ca (s) + ___HOH(l) ---> 16. ___H2SO4 (aq) + ___Al(OH)3 (s) ---> 17. ___Cl2 (aq) + ___KBr (aq) ---> 18. ___Na2CO3 (aq) + ___ Ca(OH)2 (aq) ---> science10 page 23 Still More Practice Write the balanced equation, including phase symbols, and identify the reaction type for each of the following. 1. Hydrosulfuric acid reacts with the iron in pipes to produce iron (II) sulfide and hydrogen gas. Equation: Type: 2. Iron reacts with the water and oxygen in the air to produce rust (iron(III)hydroxide) Equation: Type: 3. Coal (C9H6) is combusted in a stove. Equation: Type: 4. Iron is added to sulfuric acid to release hydrogen gas and iron (II) sulfate. Equation: Type: 5. Hydrogen is burned as a fuel in experimental vehicles. Equation: Type: 6. Sodium benzoate solution reacts with magnesium sulfate solution to produce sodium sulfate and magnesium benzoate Equation: Type: 7. Mercury (II) sulfide (cinnabar) is decomposed. Equation: Type: 8. Every year people around the house fall victim to dangerous fumes produced when products such as Sani-Flush (NaHSO4) and chlorine bleach solution (NaClO) are mixed. These two react in salt water (NaCl (aq))to produce chlorine gas,sodium sulfate and water. Equation: Type: 9. Rock salt is reacted with sulfuric acid to produce sodium sulfate and hydrochloric acid. Equation: Type: science10 page 24 10. The sodium sulfate above is reacted with charcoal (carbon) and limestone (calcium carbonate) to produce sodium carbonate(soda ash), calcium sulfide and carbon dioxide. Equation: Type: 11. The soda ash from above is then dissolved and reacted with slaked lime (calcium hydroxide) to produce caustic soda (sodium hydroxide) and calcium carbonate. Equation: Type: 12. Potassium was discovered in 1807 by electrically decomposing potash (potassium chloride) Equation: Type: 13. Boric acid is used in laboratory eye washes to neutralize a sodium hydroxide solution that was accidentally splashed into an eye. Equation: Type: 14. Bread dough rises because carbon dioxide is produced when cream of tartar (KHC4H4O6) reacts with sodium bicarbonate (baking soda). Other products are water and KNaC4H4O6. Equation: Type: 15. A deadly gas (hydrogen cyanide) is produced when hydrochloric acid is added to a potassium cyanide solution. Equation: Type: 16. Lead was produced by the ancient Romans in two steps. a) Lead (II) sulfide is found in silver ore. The lead (II) sulfide is heated in air (oxygen) to produce lead (II) oxide and sulfur dioxide gas. Equation: Type: b) The lead(II) oxide is then heated with charcoal (carbon) to produce lead and carbon dioxide. Equation: Type: science10 page 25 Calculating Molar Mass In each of the following determine the molar mass of the compound given. Your answer should be to two decimal points. 1. FeSO4 (s) 2. magnesium sulfate 3. MgSiO3 (s) 4. sodium hypochlorite 5. Al(OH)3 (s) 6. sodium chloride 7. calcium carbonate 8. dinitrogen monoxide 9. NH4H2PO4 (s) {115.04 g} 10. Ca(HCO3)2 (s) {162.12 g} 11. ammonium acetate 12. lead (II) nitrate 13. mercury (II) permanganate science10 {151.91 g} {120.37 g} {100.40 g} {74.44 g} {78.01 g} {58.44 g} {100.09 g} {44.02 g} {77.10 g} {331.21 g} {438.47 g} page 26 Calculating Mass to Moles In each of the following determine the number of moles for the quantity of the compound given. Your answer should be to the correct number of significant digits. Remember to determine the amount of one mole of the compound and then use the formula n= m to determine the number of moles M 1. 120 g of sodium phosphate {163.94 g/mole, 0.732 moles} 2. 5.00 g of NaHCO3 (s) {84.01 g/mole, 0.0595 moles} 3. 85.0 g of calcium carbonate {100.09 g/mole, 0.849 moles} 4. 1600 g of carbon dioxide {44.01 g/mole, 36.36 moles} 5. 3.00 kg of water {18.02 g/mole, 166 moles} 6. 78.6 g of methane gas {16.05 g/mole, 4.90 moles} 7. 123 g of sulfuric acid {98.08 g/mole, 1.25 moles} 8. 964 g of ferrous chromate {171.85 g/mole, 5.61 moles} 9. 456 g of mercury (I) borate {660.58 g/mole, 0.690 moles} science10 page 27 Marvin says, “Show all of your work when completing the open boxes. Remember to watch for significant digits!” formula 1. C12H22O11 2. NaOH(s) 5. science10 molar mass given mass number of moles 1000 g 0.641 mol ammonium phosphate 3. 4. name of substance 10.0 kg CO2 (s) 5.00 mol sulfuric acid 5000 g page 28 Marvin says, “If you smell an odorless gas, it is probably carbon monoxide!” formula 6. name of substance given mass CaCO3 (s) aluminum oxide 8. ethanol 9. NaHSO3 (s) 10. Mg(OH)2 (s) number of moles 2.378 mol 7. science10 molar mass 6.0 g 30.48 mol 250 mol 15 g page 29 Marvin says, “Water is composed of two gins, oxygin and hydrogin. Oxygin is pure gin and hydrogin is gin and water” formula name of substance molar mass ammonium benzoate 11. given mass 350 g phosphoric acid 50 mol 12. 13. 14. 15. science10 number of moles Al2(HPO4)3 (s) 10 g ammonium carbonate 0.50 g magnesium dichromate 5.00 mol page 30 Chemistry Final Review Fill in the following blanks to BEST complete the statement. a) A __________________ is considered to be consistent throughout. This type of matter can be of two types ______________ or ________________ of which there are 109 of these on a ______________ table. b) A mixture can be of two types ____________________ or ____________________. c) Ice tea in a pitcher is known as a ____________________ because it is dissolved in water. The ice tea mix is known as the ____________________ the water is called the ____________________ and any mixture dissolved in water is given a symbol of ___________. d) ____________________ are a combination of two or more elements. The rearrangement of electrons determines whether they are ionic or molecular. When elements lose electrons they become ____________________ charged and are called ___________ ; these elements are ____________ which are found on the ________ side of the periodic table. Elements that gain electrons become __________________charged and are called ______________; these elements are ____________________which are found on the ________________ side of the periodic table. The name given to the formula where these two elements combined is called an ____________________ formula. e) When 2 non-metallic elements ____________________ electrons, the result is a ____________________ compound. The naming of this type of compound uses a __________________ which determines the number of elements in this compound and a _____________ which is usually “ide”. f) The ____________________ refers to the number of this positively charged particle. It is called a ________ and is found in the____________________ of an atom. The ____________________mass of any element is a combination of ____________________ and ____________________ only because ____________________ are considered to have no mass. g) ____________________ are vertical columns and ____________________ are horizontal rows on the periodic table. h) Group number ____________________ the ____________________family consists of the most reactive metal in existence. That metal is ____________________. i) Group number ____________________ the ____________________ family is known as the science10 page 31 “____________________” because it combines with group IA and IIA metals to form crystals called ‘salts’. k) ____________________ are solid at room temperature with the exception of mercury. Other properties include ____________________, ____________________, and ___________________ l) Some non-metals exist in pairs. These elements are known as ____________________ molecules and are oxygen, nitrogen and ____________________. Two elements are poly atomic. They are ____________________ which has a symbol of ____________________ and ____________________ having a symbol of ____________________. m) ____________________ was responsible for the Orbits model of the Atom. Rutherford was responsible for ____________________model, Thompson developed the ____________________ model and the currently accepted model is____________________. It has electrons moving in an unpredictable path around the nucleus. n) In ____________________ reactions ____________________ is needed in order to burn a hydrocarbon. When balancing these reactions, balance ____________________ first ____________________second and ____________________ last. o) Isotopes occur when ____________________ are lost or gained. The result is a change in the atomic ____________________ of the substance. p) ____________________ is a name given to a metal that can have more than one charge. The charges of the metal are represented by ____________________. This is called the _______________naming system. q) In forming an ionic compound it is essential that charges ____________________ to form a ____________________ compound (having no charge). r) In order for a compound to be an acid the substance must contain a ____________________ion and be ____________________in ____________________ s) Bases usually contain the ____________________ ion. t) A reaction that releases energy is known as a(n) ____________________ reaction. You usually can feel the temperature rise because heat is being released. The opposite is a(n) ____________________ reaction. It absorbs ____________________ and the temperature feels cool. science10 page 32 u) A mole represents ____________________particles and this number is credited to the Scientist ____________________. Fill in the following chart. science10 page 33 a, i, or m Formula Name silver bromide magnesium nitrate hydrochloric acid tin (IV) chloride sucrose methanol ammonium sulphide cobalt (II) nitrate acetic acid ammonium sulphate Co(OH)2(s) P4Br6(s) Ni3(PO4)2(s) Pb(NO2)2(s) H2O2(l) NH3(g) AgSCN(s) Mn(HPO4)2(s) CH4(g) List the differences between the following: 1. metals and nonmetals.(4) science10 2. Atoms and Ions. (3) page 34 3. molecular and ionic bonds.(3) 4. acids and bases.(2) Balance the following reactions. Include the phases and the type of reaction. 1. A solution of iron (II) sulphate is combined with solid ammonium hydroxide to produce a solution of ammonium sulphate and a iron (II) hydroxide precipitate. 2. Carbonic acid is poured on a sheet of aluminum foil. The resulting reaction begins to release a hydrogen gas and a precipitate of aluminum carbonate. 3. Octane combusts. 4. Titanium (IV) permanganate decomposes into its elements. 5. White phosphorus and vanadium combine in a synthesis reaction. Complete the following chart. science10 page 35 Formula Name of Substance Molar Mass glucose Mass 10.5 g (NH4)2CO3(s) 357 g calcium benzoate 0.389 moles carbonic acid 5.07 moles potassium 157 g dichromate Good Luck on the Final! science10 Moles page 36