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Scope, Sequence & Coordination A National Curriculum Development and Evaluation Project for High School Science Education A Project of the National Science Teachers Association This project was suppported in part by the National Science Foundation. Opinions expressed are those of the authors and not necessarily those of the Foundation. The SS&C Project encourages reproduction of these materials for free distribution. Scope, Sequence & Coordination SS&C Research and Development Center Iowa Coordination Center Bill G. Aldridge, Principal Investigator and Project Director* Dorothy L. Gabel, Co-Principal Investigator Erma M. Anderson, Associate Project Director Nancy Erwin, SS&C Project Editor Rick McGolerick, Project Coordinator Robert Yager, Center Director Keith Lippincott, School Coordinator University of Iowa, 319.335.1189 Evaluation Center Frances Lawrenz, Center Director Doug Huffman, Associate Director Wayne Welch, Consultant University of Minnesota, 612.625.2046 Houston SS&C Materials Development and Coordination Center Linda W. Crow, Center Director Godrej H. Sethna, School Coordinator Martha S. Young, Senior Production Editor Yerga Keflemariam, Administrative Assistant Baylor College of Medicine, 713.798.6880 Houston School Sites and Lead Teachers Jefferson Davis H.S., Lois Range Lee H.S., Thomas Goldsbury Jack Yates H.S., Diane Schranck Iowa School Sites and Lead Teachers Pleasant Valley H.S., William Roberts North Scott H.S., Mike Brown North Carolina Coordination Center Charles Coble, Center Co-Director Jesse Jones, Center Co-Director East Carolina University, 919.328.6172 North Carolina School Sites and Lead Teachers Tarboro H.S., Ernestine Smith Northside H.S., Glenda Burrus Puerto Rico Coordination Center** Manuel Gomez, Center Co-Director Acenet Bernacet, Center Co-Director University of Puerto Rico, 809.765.5170 Puerto Rico School Site UPR Lab H.S. California Coordination Center Tom Hinojosa, Center Coordinator Santa Clara, Calif., 408.244.3080 California School Sites and Lead Teachers Lowell H.S., Marian Gonzales Sherman Indian H.S., Mary Yarger Sacramento H.S., Brian Jacobs Pilot Sites Site Coordinator and Lead Teacher Fox Lane H.S., New York, Arthur Eisenkraft Georgetown Day School, Washington, D.C., William George Flathead H.S., Montana, Gary Freebury Clinton H.S., New York, John Laffan** Advisory Board Dr. Rodney L. Doran (Chairperson), University of Buffalo Dr. Albert V. Baez, Vivamos Mejor/USA Dr. Shirley M. Malcom, American Association for the Advancement of Science Dr. Shirley M. McBay, Quality Education for Minorities Dr. Mary Budd Rowe, Stanford University Dr. Paul Saltman, University of California, San Diego Dr. Kendall N. Starkweather, International * Western NSTA Office, 394 Discovery Court, Henderson, Nevada 89014, 702.436.6685 ** Not part of the NSF-funded SS&C project. Technology Education Association Dr. Kathryn Sullivan, NOAA National Science Education Standard— Physical Science and Earth and Space Teacher Materials Learning Sequence Item: 966 Structure of Atoms The nuclear forces that hold the nucleus of an atom together, at nuclear distances, are usually stronger than the electric forces that would make it fly apart. Nuclear reactions convert a fraction of the mass of interacting particles into energy, and they can release much greater amounts of energy than atomic interactions. Fission is the splitting of a large nucleus into smaller pieces. Fusion is the joining of two nuclei at extremely high temperature and pressure, and is the process responsible for the energy of the sun and other stars. Radioactive isotopes are unstable and undergo spontaneous nuclear reactions, emitting particles and/or wave-like radiation. The decay of any one nucleus cannot be predicted, but a large group of identical nuclei decay at a predictable rate. This predictability can be used to estimate the age of materials that contain radioactive isotopes. Energy in the Earth System Two primary sources of internal heat (as Earth’s sources of energy) are the decay of radioactive isotopes and gravitational energy from the Earth’s original formation. Radioactivity, Time and Age March 1996 Adapted by: Nancy Reclusado, Don Warner, Dorothy Gabel, Thomas Goldsbury and Linda W. Crow The Origin and Evolution of the Universe Early in the history of the universe, matter, primarily the light atoms hydrogen and helium, clumped together by gravitational attraction to form countless trillions of stars. Billions of galaxies, each of which is a gravitationally bound cluster of billions of starts, now form most of the visible mass in the universe. Stars produce energy from nuclear reactions, primarily the fusion of hydrogen to form helium. These and other processes in stars have led to the formation of all the other elements. Radioactivity and its Applications. (a) Students should develop an understanding of average lifetime for a radioactive material expressed in terms of half-life (1.433T1/2). They should use results of such calculations for various radioactive materials to consider implications for radioactive wastes. (Chemistry, A Framework for High School Science Education, p. 81.) Earth’s Internal Energy Sources: Radioactivity and Gravitational Potential Energy. (b) Students should be able to use radioactive count data in a graph to determine half-life and mean lifetime of a radioactive sample. (Earth and Space Sciences, A Framework for High School Science Education, p. 135.) Nuclear Fission and Fusion. (c) Students should create and examine macroscopic analogs to chain reactions, like mousetrap/Ping Pong ball arrangements, to gain the concept of a chain reaction. (Chemistry, A Framework for High School Science Education, p. 79.) Origin and Age of Earth: Rock Sequences, Fossils, and Radioactive Dating: (d) Students should learn to use the concept of geologic time in relationship to fossils. (Earth and Space Sciences, A Framework for High School Science Education, p. 149.) Contents Matrix Suggested Sequence of Events Lab Activities 1. Stand 'Em Up, Knock 'Em Down 2. Snapping Traps 3. Crumpled Paper 4. Light My Fire 5. Radioactivity 6. "Seeing" the Invisible 7. Half-life of Peas 8. Getting Shorter All the Time 9. Rocks with a Past Continued This microunit was adapted by Nancy Reclusado (Sacramento H.S., Sacramento, Calif.), Don Warner (Sacramento H.S., Sacramento), Dorothy Gabel (Indiana Univ., Bloomington), Thomas Goldsbury (Lee H.S., Houston, Texas), and 3 of Medicine, Houston) Linda W. Crow (Baylor College Contents (continued) Lab Activities 10. The Case of the Melting Ice Assessment 1. Bowling 2. Nuclear Weapons 3. Science or Alchemy? 4. Radiation, I 5. Bean Counters 6. Eating the Difference 7. Radioactive Controls 8. Radiation, II 9. Age Correlations, I 10. Age Correlations, II 4 968 Learning Sequence Radioactivity and its Applications. (a) Students should develop an understanding of average lifetime for a radioactive material expressed in terms of half-life (1.433T1/2). They should use results of such calculations for various radioactive materials to consider implications for radioactive wastes. (Chemistry, A Framework for High School Science Education, p. 81.) Earth’s Internal Energy Sources: Radioactivity and Gravitational Potential Energy. (b) Students should be able to use radioactive count data in a graph to determine half-life and mean lifetime of a radioactive sample. (Earth and Space Sciences, A Framework for High School Science Education, p. 135.) Nuclear Fission and Fusion. (c) Students should create and examine macroscopic analogs to chain reactions, like mousetrap/Ping Pong ball arrangements, to gain the concept of a chain reaction. (Chemistry, A Framework for High School Science Education, p. 79.) Origin and Age of Earth: Rock Sequences, Fossils, and Radioactive Dating: (d) Students should learn to use the concept of geologic time in relationship to fossils. (Earth and Space Sciences, A Framework for High School Science Education, p. 149.) Science as Inquiry Stand 'Em Up, Knock 'Em Down Activity 1 Snapping Traps Activity 2 Science in Personal and Social Perspectives Science and Technology Chain Reaction: The First Half-Century Reading 1 The Birth of the Nuclear Age Reading 2 Bowling Assessment 1 Science or Alchemy? Assessment 3 Nuclear Weapons Assessment 2 Marie Curie: A Pioneer in the Study of Radioactivity Reading 3 Crumpled Paper Activity 3 Radiation, II Assessment 8 Light My Fire Activity 4 Chain Reaction: The First Half-Century Reading 1 Radioactivity Activity 5 The Birth of the Nuclear Age Reading 2 "Seeing" the Invisible Activity 6 Half-Life of Peas Activity 7 Getting Shorter All the Time Activity 8 Rocks With A Past Activity 9 The Case of the Melting Ice Activity 10 Radiation, I Assessment 4 Bean Counters Assessment 5 Eating the Difference Assessment 6 Radioactive Controls Assessment 7 Age Correlations, I Assessment 9 Age Correlations, II Assessments 10 The Dating Game Reading 6 5 History and Nature of Science Madame Curie and Radioactivity Reading 5 Modern Alchemy Reading 6 Suggested Sequence of Events Event #1 Lab Activity 1. Stand 'Em Up, Knock 'Em Down Event #2 Lab Activity 2. Snapping Traps Event #3 Lab Activity 3. Crumpled Paper Event #4 Lab Activity 4. Light My Fire Event #5 Lab Activity 5. Radioactivity Event #6 Lab Activity 6. "Seeing the Invisible Event #7 Lab Activity 7. Half-life of Peas Alternative or Additional Activities 8. Getting Shorter All the Time Event #8 Lab Activity 9. Rocks with a Past (55 minutes) Event #9 Lab Activity 10. The Case of the Melting Ice (55 minutes) Event #10 Readings from Science as Inquiry, Science and Technology, Science in Personal and Social Perspectives, and History and Nature of Science Reading 1 Reading 2 Reading 3 Reading 4 Reading 5 Reading 6 Chain Reaction: The First Half-Century The Birth of the Nuclear Age Marie Curie: A Pioneer in the Study of Radioactivity The Dating Game Madame Curie and Radioactivity Modern Alchemy Readings can be found in the student version of this publication. Assessment items are at the back of this volume. 6 Assessment Recommendations This teacher materials packet contains a few items suggested for classroom assessment. Often, three types of items are included. Some have been tested and reviewed, but not all. 1. Multiple choice questions accompanied by short essays, called justification, that allow teachers to find out if students really understand their selections on the multiple choice. 2. Open-ended questions asking for essay responses. 3. Suggestions for performance tasks, usually including laboratory work, questions to be answered, data to be graphed and processed, and inferences to be made. Some tasks include proposals for student design of such tasks. These may sometimes closely resemble a good laboratory task, since the best types of laboratories are assessing student skills and performance at all times. Special assessment tasks will not be needed if measures such as questions, tabulations, graphs, calculations, etc., are incorporated into regular lab activities. Teachers are encouraged to make changes in these items to suit their own classroom situations and to develop further items of their own, hopefully finding inspiration in the models we have provided. We hope you may consider adding your best items to our pool. We also will be very pleased to hear of proposed revisions to our items when you think they are needed. 7 966 Activity 1 Teacher Sheet Science as Inquiry Stand ‘Em Up, Knock ‘Em Down How do dominoes simulate nuclear fission? Overview: Students set up a chain reaction with dominoes. Materials: Per lab group: 25 dominoes per group of four 1 large table or floor space 1 stopwatch or clock with second hand Procedure: Have students set up the dominoes in two different arrangements—a straight line and as shown in the figure below. Students measure how long it takes for the entire arrangement of dominoes to fall over and record their data for each design. They then compare the number of dominoes being knocked over per second according to the design. Finally, have students make a sketch of their design. 8 966 Activity 1 Background: If you gave the flu to two people, they could give the flu to two more people, who would continue to share the flu with others. You would set off a chain reaction. A unique result of fission is the release of two or three neutrons from the nucleus. Neutrons begin the fission process by splitting nuclei, and splitting nuclei keep the reaction going by releasing more neutrons. “Expanding” chain reactions are out of control; “limited” chain reactions are controlled. Expanding chain reactions characterize nuclear weapons, where a lot of energy is released in a short period of time. Limited chain reactions are found in a nuclear plant, where the energy released is under control and released over a longer time period. When you control the rate of fission in a chain reaction, the heat released can be used to generate electricity. Further Variations: Have students design a different way of modeling this process. Adapted from American Chemical Society, "Chemistry in the Community," Chem Com, 2nd edition. Kendall Hunt, 1993. 9 966 Activity 2 Teacher Sheet Science as Inquiry Snapping Traps How do snapping mousetraps simulate a nuclear chain reaction? Overview: Students set up linked mousetraps that simulate a nuclear reaction. Materials: Per lab group: 7 mouse traps 4 ft. of string stop watch or clock with second hand Procedure: Have students attach the mousetraps together with string. The strings from the gate of the first trap can be attached to one or two triggers of one or more traps. Continue until all the mousetraps have been used (see figure). The strings need to be fairly taut, otherwise the first trap may not spring the others. Students should design and set off at least two different arrangements, timing how long each reaction took and the number of traps that sprang. Background: By setting off mousetraps, you can demonstrate how the fission of one nucleus emits neutrons that can cause fission of other nuclei. “Expanding” chain reactions are out of control; “limited’ chain reactions are controlled. Before a chain reaction occurs, a large enough mass of fissionable material must be present in order for sufficient neutrons to be captured to sustain the reaction. This is called the critical mass. Caution: Mousetraps are extremely sensitive. Do not place fingers in the way of the gate. 10 966 Activity 2 Further Variations: The class can work as a whole to demonstrate a dynamic result. Adapted from Wind, Water, Fire and Earth, NSTA,1986. 11 966 Activity 3 Teacher Sheet Science as Inquiry Crumpled Paper How can crumpled paper be used to illustrate a nuclear chain reaction? Overview: Illustrate a chain reaction by having students throw wads of paper in turn as each is hit with a wad. Materials: Per class: two pieces of paper per student Procedure: Each student, and you, has two pieces of paper he or she crumples. Instruct students to stand and shut their eyes. Begin the chain reaction by standing in the same direction as the students and throwing your paper wads over your shoulder in their direction. If hit by a wad, a student must toss his/her paper wads in any direction. It normally takes a few attempts to get this started and dies out before all students are hit by a crumpled paper wad. Repeat the process after students have moved closer together. Relate this to the critical mass needed for a sustained nuclear reaction. Have students diagram the positions of the participants at the beginning of the activity and again at the end. Background: Nuclear fission occurs when a large atom is split into two fragments of about the same mass. A unique result of fission is the release of two or three neutrons from the nucleus. Since neutrons begin the fission process, splitting nuclei keep the reaction going by releasing more neutrons. “Expanding” chain reactions are out of control; “limited” chain reactions are controlled. Expanding chain reactions characterize nuclear weapons, where a lot of energy is released in a short period of time. In order for a chain reaction to begin, enough neutrons must be captured by the surrounding atoms. This is called the critical mass of the substance. Limited chain reactions occur in a nuclear plant, where the energy released is under control and released over a longer time period. When you control the rate of fission in a chain reaction, the heat released can be used to generate electricity. Adapted from American Chemical Society, "Chemistry in the Community," Chem Com, 2nd edition. Kendall Hunt, 1993. 12 966 Activity 4 Teacher Sheet Science as Inquiry Light My Fire How does a spreading fire simulate nuclear fission? Overview: In this demonstration, students set up and light matches to simulate a chain reaction. Materials: Demonstration per class: 3 or 4 lids from shoe boxes 1 small nail 1 box of wooden matches 1 metal container to extinguish the flames Warning: Make certain the metal container completely covers this demonstration before you start. Procedure: With a small nail, students punch a square pattern of holes about one centimeter apart from one another in a shoe box lid (see figure). They plug the holes with wooden matches and light one corner match. That match will set off the rest (a chain reaction). Make sure that the metal container completely covers the demonstration so the flames can be easily extinguished. Try other arrangements and distances. Further Variations: This should be done as a demonstration. You might want to make a permanent demonstration board out of wood in which you drill holes for the matches. Background : Fission (splitting apart) of one nucleus emits neutrons than can split apart other nuclei—a chain reaction. A critical mass of the fissionable material must be present so that sufficient neutrons are captured to create the sustainable chain reaction. Adapted from Christensen, J.W. Energy Resources and Environment, Iowa: Kendall Hunt, 1981. 13 966 Activity 5 Teacher Sheet Science as Inquiry Radioactivity Materials: Per lab group: 100 pennies shoe box with lid graph paper Procedure: Students place pennies “heads-down” in a shoe box, cover the box with the lid and shake it. They open the box and remove all the “changed” pennies (those that landed “heads-up”). Students count the number of “unchanged” pennies remaining in the box and record this information on a data table. Students repeat the procedure until all the pennies have changed, recording each trial and each result. Background: The nuclei of radioactive atoms break down, releasing particles and radiation. Radioactive decay goes on like clockwork, at an even and continuous pace. As the nuclei of radioactive atoms break down, the radioactive element changes to a stable new element. The rate of radioactive decay is measured by half-life—the time it takes for half of the parent element to change into atoms of the daughter element. The element radium-126, has a half-life of 1,622 years. What happens to 20 grams of radium after 1,622 years? Ten grams of radium remain, and 10 grams have changed into lead. Variations: Use M&Ms or brass fasteners in place of the pennies. 14 966 Activity 6 Teacher Sheet Science as Inquiry "Seeing" the Invisible Can scientists see the particles emitted by radioactive substances? Demonstration Materials: cloud chamber 10 mL isopropyl alcohol 1 lb dry ice ice (thin slab) high intensity light (20+ watt) squeeze bottle (for alcohol) 1 pr disposable gloves crucible tongs radiation source or Colman Lantern mantle flashlight with tape Procedure: In order to see while fog is produced in the cloud chamber, 1) paint the bottom of the chamber black, and 2) prepare a high intensity light source by covering a flashlight with tape—leaving a small hole (pencil-sized) for light to shine through. Wearing heavy gloves and using forceps, wet the felt band encircling the inside top of the chamber with alcohol. Insert the radioactive source into the chamber by placing it on the end of the needle projecting into the chamber. The needle should be supported by a cork stopper inserted into a hole in the wall of the cylinder. (If using the Colman Lantern mantle, rest it on the bottom of the cylinder.) Cover the cylinder. To minimize student contact with the radiation source, place the source in the cloud chamber prior to class. Set the chamber on the smooth block of dry ice. (If block-dry ice is not available, crush the ice pellets so that the surface is even and there is good contact between the cylinder and the surface of the dry ice.) Turn on the light source—from the Sample tracks (in reverse) in side of the chamber—and note the tracks that are emitted from the radioactive a cloud chamber. source. The tracks must be viewed from the top, so only a few students at a time can gather around the chamber to view them. An alternative is to have one cloud chamber for each group of students. Note: students should not handle or touch the radioactive source—these should be in place before class begins. Cloud chamber kits and radiation sources may be purchased from Sargent-Welch. For best observation, the room should be darkened and the light source directed into the side of the chamber. 15 966 Activity 6 Background: Elements occurring in nature that are radioactive emit alpha, beta and gamma radiation. Alpha particles are actually the nuclei of helium atoms containing two neutrons and two protons. They usually travel only a few centimeters through air before being absorbed. Moving at relatively slow speeds (about 1/10 the speed of light), they ionize the air as they pass through it—but can be stopped by a single sheet of paper or deflected by a magnet. Beta particles are electrons. Because of their negative charge, they also can be deflected by magnets. They move at the speed of light, have a greater penetrating power than alpha particles—but do not readily ionize air. They can be stopped by a thin sheet of aluminum. Gamma radiation is a type of radiation similar to X-rays, but with greater penetrating power than either x-rays, alpha particles or beta particles. Gamma rays ionize atoms they strike, can be stopped by several centimeters of lead—and because they are not charged, are not deflected by magnets. The major source of radioactivity that is seen in the cloud chamber is due to alpha particles, although some beta particles are undoubtedly being emitted. Differences in the intensity of the tracks are due primarily to the difference in the mass of the alpha particles (He nuclei) and, hence, lower speed vs. beta particles (electrons). Differences in direction and length can also be due to variations in temperature and degree of saturation with alcohol vapor. The tracks that form are actually clouds of alcohol that form on the particles being emitted from the radioactive source. As the dry ice sublimes, it absorbs heat from the air in the chamber creating a very cool environment. This allows more alcohol vapor to evaporate forming a supersaturated gaseous solution. As the particles are emitted from the radioactive source, this solution is disturbed and the excess alcohol forms on the particles—and is seen in the form of clouds. Adapted from: Haberschaum, et al., IPS, 4th Ed., Prentice-Hall, 1982. 16 966 Activity 7 Teacher Sheet Science as Inquiry Half-Life of Peas Can the half-life of a radioactive element be illustrated with peas? Materials: Per lab group: 1 cup split peas empty cup tray (or piece of paper) clock with second-hand Procedure: Students first count the number of peas or “atoms” in their cup and record this number as the initial number of radioactive atoms. After noting the time, students pour the cup full of peas into a tray (or onto a piece of paper). They then separate them into two categories, radioactive or decayed (or stable). If the flat side of the pea is up, the “atom” is still radioactive. These radioactive atoms are counted, recorded under “Trial 1” on a data table, and placed back in the now empty cup. If the flat side of the pea is down, then the atom has decayed. These decayed atoms are placed in the other cup. Students repeat the process by emptying the cup of radioactive atoms on the tray, removing the decayed atoms (adding them to the cup of decayed atoms from Trial 1), counting the radioactive atoms, and recording the results under “Trial 2.” This sequence is repeated until no more radioactive atoms remain. The final time and total time are then recorded. The students will need to set up a data table similar to the one below: Trial number Number of Radioactive Atoms 0 1 2 3 4 5 6 [etc.] Initial atoms in cup Initial time: Final time: Total time (in sec.): When the activity is completed students calculate the half-life of their peas by dividing the total time in seconds by the number of trials it took until all of the atoms had decayed (become stable). Students also make a graph of the half-life versus the number of radioactive atoms present at each half-life interval. 17 966 Activity 7 Background: The half-life of a radioactive element is the time it takes for half the nuclei present to decay. The amount of that nucleus remaining is halved after each half-life. The half-life of an isotope of an element is not changed by changes in temperature or pressure, and different isotopes of a given element have different half-lives or may be stable and not disintegrate. For example, Be-10 has a half-life of 1.6 ¥ 106 years whereas B-8 has a half-life of 6.7 ¥ 10-17 seconds. C14 which is used in radiocarbon dating has a half life of 5,730 years, After carbon-14 decays to nitrogen-14, the carbon is not longer present. Hence an analysis of changes of mass of carbon-14 present in a given sample of a substance can be used to calculate the age of the substance. A material containing 1 gram of carbon-14 in the year 2000 will contain 1/2 gram 5,730 years from the year 2000, and 1/2 of 1/2 gram (or 1/4 gram) in 13,460 A.D. graph paper Adapted from: Nancy Russo. 18 966 Activity 8 alternative/extension activity for Event 7 Teacher Sheet Science as Inquiry Getting Shorter All the Time Can the half-life of a radioactive element be illustrated with licorice? Materials: Per lab group: length of licorice (vine type or whip—the longer the better) scissors (or knife—to cut licorice) metric ruler paper towel (to put licorice on) clock with second-hand Procedure: Students measure and record the length of the entire piece of licorice. They also note the beginning time to the nearest second. They then cut the piece of licorice in half and record the trial number and the remaining length. (They may eat the other half or save it and form a licorice graph.) It represents the mass of the radioactive element that has disintegrated. With the remaining piece, students repeat the halving process, recording the length and trial number until the remaining piece is too small to be cut in half. Students then record the final time. Trial number Length of Licorice 0 1 2 3 4 5 6 [etc.] Initial length Initial time: Final time: Total time (in sec.): When the activity is completed the groups calculate the half-life of the licorice by dividing the total time in seconds by the number of trials it took until all of the licorice had become stable (decayed or was eaten). Students also make a graph of the half-life versus the number of radioactive length present at each half-life interval. 19 966 Activity 8 Background: The half-life of a radioactive element is the time it takes for half the nuclei present to decay. The amount of that nucleus remaining is halved after each half-life. The half-life of an isotope of an element is not changed by changes in temperature or pressure, and different isotopes of a given element have different half-lives or may be stable and not disintegrate. For example, Be-10 has a half-life of 1.6 x 106 years whereas B-8 has a half-life of 6.7 x 10-17 seconds. C-14 which is used in radiocarbon dating has a half life of 5730 years, After carbon-14 decays to nitrogen-14, the carbon is not longer present. Hence an analysis of changes of mass of carbon-14 present in a given sample of a substance can be used to calculate the age of the substance. A material containing 1 gram of carbon-14 in the year 2000, will contain 1/2 gram 5,730 years from the year 2000, and 1/2 of 1/2 gram (or 1/4 gram) in 13,460 AD. Adapted from: SS&C, Bozeman participant Carole Magnussen. 20 966 Activity 9 Teacher Sheet Science as Inquiry Rocks With a Past What do rocks look like that can be radioactive? Overview: This simple, observational activity provides students some direct experiences with rocks that can be used in the radioactive dating process. Materials: Per class: Samples of: charcoal tuff volcanic ash monzonite quartz monzonite granite rhyolite gneiss magnifying glasses (or hand lenses) Procedure: Have students examine these different rocks. Tell them that these are the rocks that can be used in radioactive dating. The students will describe the rocks, determine its density and also used rock keys to identify their component parts. A rock key has been included for your use with these rock types. Also have them associate a rock type with each of these samples . You may want to emphasize the color and texture for igneous rocks. Keep in mind that color is related to the amount of quartz (light-colored) and the amount of the ferromagnesium minerals (dark-colored). Texture refers to the size of the grains and is directly related to cooling time. Please note that igneous and metamorphic rocks are the primary rocks used for this dating process. A good question to pose is why these particular rocks are the ones that can be used in this process? Background: Determining the age of rocks using radioactive dating is simple in theory, but in practice it becomes very difficult. The difficulty lies primarily in measuring the very tiny amounts of the isotopes. When possible, two or more methods of analysis are used on the same rock specimen to crosscheck the results. The potassium-argon method is often used to determine ages of most rocks samples. The rocks used in this lab have the minerals that contain this important combination. 21 966 Activity 9 Variations: Relative time and the use of sedimentary rocks could be added to this lab to connect the use of absolute and relative time techniques. IGNEOUS ROCKS Composition and Color Texture Very coarse-grained Light Intermediate Dark Very Dark 10–20% quartz no quartz no quartz 10% ferromagnesian minerals 25–40% ferromagnesian minerals 50% ferromagnesian minerals 100% ferromagnesian minerals pegmatite — — — Coarse-grained granite diorite gabbro peridotite Fine-grained rhyolite andesite basalt — Glassy obsidian Frothy or cellular pumice — scoria Volcanic tuff (fragments <4 mm) Pyroclastic or fragmental Volcanic breccia (fragments >4 mm) METAMORPHIC ROCKS Foliated Rocks Crystal size Rock name Very fine, not visible Fine grains, not visible Coarse, visible with unaided eye; mostly micaceous minerals slate phyllite Coarse gneiss s c h i s t Comments muscovite schist biotite schist garnet schist staurolite schist kyanite schist sillimanite schist Cleavage crosses sedimentary layers Foliation well developed; rock has “sheen” Types of schist, recognized on mineral content, reflect increasing intensity of metamorphism from top downward Well-developed color banding or streaking Nonfoliated Rocks Precursor rock quartz sandstone limestone conglomerate basalt or gabbro Metamorphic rock name quartzite marble stretched-pebble conglomerate greenstone amphibolite Comments Composed of interlocking quartz grains Composed of interlocking calcite grains Original pebbles distinguishable, but strongly deformed Composed of epidote and chlorite Composed of amphibole and plagioclase Adapted from: Crow, Linda W., "Rock of Ages," Geologic Methods, 1988. 22 13 966 Activity 10 Teacher Sheet Science as Inquiry The Case of the Melting Ice How is the transition of ice to water like the radioactive decay of materials? Materials: Per lab group: ring stand setup funnel graduated cylinder ice Procedure: The following is a creative and memorable way to introduce the concept of decay and mother/daughter relationship (in this case, ice and water) as well as establish an analogy to radiometric dating. It is purely qualitative and introductory—and can be a lot of fun. Set up each lab station as shown and fill the funnel with ice at least 1/2 hour before class starts. Note the time at which this is done, but do not reveal this time to the students until the end of the activity. As soon as students enter the room, have them take note of the time and volume of water in their graduated cylinder. Tell them that they are detectives working on the murder of Frosty the Snowman—and that it is crucial to know the exact time of the placement of the ice so alibis can be checked. Students should determine a time interval and record the volume of water at each interval on a chart until the ice is nearly (not completely) melted. They will record this information as points on a “time vs. volume” graph (a reasonably linear plot will emerge after about 45 minutes), and working backwards, determine the exact time the ice was placed in the funnel (time-zero, when the volume was zero)—or the exact time of the crime. Set up a competition among the lab groups to see which group comes closest to time-zero. While waiting for the decay curve to be determined, discuss how any dating system can work by projection of the product vs. time curve back to the time of zero progeny; the assumptions involved in this system (i.e., constant room temperature, closed- or open-system, melting occurring at a constant rate, etc.); and/or what factors in this investigation have direct analogies to radiometric dating. Background: The most important concept for the student to grasp is the ability to project the “decay curve” back to time-zero. The time vs. volume plot of melting ice is linear. There are, however, some factors which will skew the plot. The key factor in determining the rate of melting is the rate of heat transfer from the surroundings through the funnel to the ice. Until the system has reached thermal equilibrium, the “decay” will be non-linear. This is the reason for placing the ice in the funnel at least 1/2 hour before class starts. Only late in the melting process (when too little ice remains to keep the funnel at constant temperature) does the temperature of the funnel rise and the rate of heat transfer to the surroundings drop. Large volume, thin-walled, thermally conductive (metal) funnels work best. It is a good idea to “super-cool” the ice and allow as little time as possible between removing the ice from the freezer and 23 966 Activity 10 filling the funnels. As the students are doing the graph, lead them in choosing a large enough vertical scale to produce a steep slope to facilitate the projection back to time-zero. After the investigation, after the basic discussion of how to use the time vs. progeny plot is completed, the class can be led to the assumptions being made the the analogous assumptions required to date, for example, a uranium mineral having radiogenic lead in it. For example: Parent and progeny represent a direct transition of one form to another. Ice converts to water and uranium238 converts to lead206. This is a closed system. Nothing escaped and nothing was added. Only with this assumption is it possible to calculate time-zero when no progeny were present. All the water in the cylinder came from the melting of the ice. Was there condensation on the outside of the funnel? Did it drop into the graduated cylinder? Was this significant? Evaporation and sublimation of ice and water are negligible. Did the cylinder leak? Did anyone remove any melt water or ice? (In a uranium-bearing rock, this requires that none of the uranium or lead was dissolved or diffused out of the rock.) The rate of change from parent to progeny can be determined. Of course, the rate of change of melting ice is relatively linear whereas that of radioactive decay is exponential. Variations: 24 966 Assessment 1 Science in Personal and Social Perspectives Bowling Item: Bowling is a recreational game for many people and a profession for a few. The ideal object of the game is to knock down all ten pins each time you throw/roll the ball down the lane. There are 10 frames/ times that you get to accomplish this task in one game. You do get a second chance in each frame to knock the pins down if you were not successful with the first ball. A score is kept to acknowledge a winner. (Bowling models a chain reaction.) Explain in writing how bowling could be an “expanding” or “limited” model of a chain reaction. Answer: At specific times bowling is expanding, limited, or both. An expanding chain reaction would be when all 10 pins are knocked down at one time (uncontrolled pin action; the reaction happens in a short period of time). A score of 300 is the expanding chain reaction goal. A limited chain reaction occurs when only a few of the original 10 pins are knocked down. This is a controlled reaction and takes a longer period of time. 25 966 Assessment 2 Science in Personal and Social Perspectives Nuclear Weapons Item: Nuclear weapons have been a controversial worldwide issue. Leaving aside the moral issue of devastation or no devastation, you need to make a plan for the use of an atomic bomb. You will be bombing an imaginary target area (no people) of 100 square miles. Decide how to deliver the bomb and where to detonate it. Outline your plan on paper and explain what will happen. Answer: Firebombing checklist: 1. Airplane—not a taxi; fueled, recent checkup. 2. Pilot—20/20 vision; top gun trained. 3. Map to imaginary target. 4. Strategy a. Size of atomic bomb—determined by area detonation will destroy. b. Time—day and hour. c. Weather forecast. d. Location of drop. 1. Detonate above the ground because you want as much fissionable material available as possible to carry out the chain reaction. 2. Do not detonate on the ground because the ground could stop the chain reaction. 26 966 Assessment 3 History and Nature of Science Science or Alchemy? Item: During the early years of the 20th century, the Curies, Rutherford and many other scientists were working on the nature of radioactivity. At one meeting between these scientists, Rutherford said that he thought that radioactivity was a “nuclear property.” Madame Curie was heard to respond, “Dr. Rutherford, do you believe in science or alchemy?” Noting Madame Curie’s response to Dr. Rutherford, explain what she was saying and why her comment was relative at the time. In terms of what is known today, who was correct? Explain your answer. Answer: 27 966 Assessment 4 Science as Inquiry Radiation, I Item: In 1909 Henri Becquerel left his sample of Uranium with some photographic paper. The Uranium was found to have taken its own picture, in the darkness of the drawer where it was left. From this event and the observations of the cloud chamber, indicate the proof that something from the Uranium caused the film to change. Answer: The tracks in the cloud chamber were proof that something, although not directly seen was present due to the tracks left. The photo film also showed that something was present because normally light is needed to “expose” photographic film. 28 966 Assessment 5 Science as Inquiry Bean Counters Item: C14 is often used to tell the age of formerly living things. C14 has a half-life of about 10,000 years. Now, a cave is discovered with the remains of burned wood from a fire. The wood was found to be approximately 50,000 years old. What percent of the original radioactive C14 remains in the charred wood? For full credit you must indicate the steps of how and why you solved the problem with the methods you used. Answer: 3.125% or 1⁄32 × 100% 29 966 Assessment 6 Science as Inquiry Eating the Difference Item: U238 is a potentially dangerous radioactive element produced for use in nuclear reactors. This element has a half-life of approximately 1,000,000,000 years. If it were to be stored, how long would 1,000 kg need to be stored in order to reduce its radioactive part to less than 10 kg? Be sure to indicate why you used the method you did to solve the problem. Answer: 7 half-lives or 7 billion years 30 966 Assessment 7 Science as Inquiry Radioactive Controls Item: Radioactivity can be detected with use of a Geiger counter—or its presence noted in a cloud chamber. Radioactive substances’ radioactivity are also controlled by their half-life. If this is true, then what is the best statement below? A. The material will stop radiating when it is frozen. B. The radiation will continue until no matter remains. C. The matter changes into new substances over a specific amount of time. D. The time of changing due to radiation depends on what is mixed with the material. Justification: Why did you pick your answer? Give good reasons and use drawings as well as explanations to give proof. 31 966 Assessment 8 Science as Inquiry Radiation, II Item: Iodine131 is a radioactive isotope used in treating abnormal conditions of the thyroid gland in people. The radiation from the decay of the isotope kills hyperactive cells in the thyroid. A normal thyroid gland uses iodine as a basis for the production of a very necessary hormone called thyroxine. Iodine seems to have very little other function in the human body. Based on this information, why do you think the use of the radioactive iodine is so successful in treating abnormal thyroid conditions? Answer. The iodine is extracted by the thyroid for use in making the hormone. Thus it is highly concentrated in the gland and doesn’t concentrate anywhere else. This means only thyroid cells are damaged by the emitted radiation, but not other body cells. This discrimination is highly desirable when using radiation to kill cells. 32 966 Assessment 9 Science as Inquiry Age Correlations, I Item: Uranium 238 decay, rather than carbon14 decay, is used to date the age of the Earth because uranium238 : A. Was more abundant than carbon when the earth was formed. B. Has a longer half-life. C. Decays at a more constant rate. D. Is much easier to measure. Justification: What is measured when a radioactive substance such as U238 is used in determining the age of a rock? Answer: B. C14 has too short a half-life (5730 years) to be useful for billion-year lifetimes needed for the age of the earth. Justification answer should include some idea that it is the amount of daughter product formed that is used to establish how much decay has occurred. 33 966 Assessment 10 Science as Inquiry Age Correlations, II Item: When early humans lived is determined by measuring when the rocks in which their skeletons are found were formed. Why can the skeletons themselves not be “dated”? A. Bones contain no carbon to use the carbon14 method. B. Carbon14 has too short a half-life, so it has all decayed from the bones. C. The materials in rocks follow physical laws more accurately. D. There are more rocks available than there are bones, so the measurement is easier. Justification: Explain what limits the time period over which a radioactive dating method can be used. Answer: B. C14 has too short a half-life (5730 years) to be useful for million-year lifetimes needed for the age of the early humans found. Justification answer should include some idea that it is the amount of daughter product formed relative to the parent present that is used to establish how much time has elapsed. When either of these (too short, or too long) is too small to be measured, then the method is not useful. 34