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Course: CHEM114 Processes & Potions Instructor: David Leiberman HOGWARTS ACADEMY Final Exam: Topics & Study Info I. Outline of Topics Matter, Change and Energy: Chemical and physical properties and changes Chemical symbols Ion formulas/charges Conservation of energy and mass Mixtures and Pure Substances Separation of Mixtures Scientific Measurement: Accuracy and Precision Significant Figures and Uncertainty Scientific notation Metric System Using proper units/labels Density (definition and equation) Dimensional analysis Instruments that measure mass, volume, pressure, etc. (lab stuff!) The Scientific Method Atomic Structure: Atomic number Mass number Isotopes Atomic mass (calculation of atomic mass… weighted average of % of each natural isotope) Calculating number of neutrons, electrons, protons in an atom Dalton’s Atomic Theory Nomenclature & The Periodic Table: Be able to write the correct formula or name for any compound (including acids) Polyatomic ions (names, symbols, charges) Groups/Periods of the Periodic Table Metals/Nonmetals/metalloids… (Know where they are.. Know their properties and characteristics) Names of groups Chemical Quantities: Stoichiometry! (Conversions between mass, moles, atoms/molecules, volume) Reaction Stoichiometry (mole/mass/volume/particles) Calculating Percent Composition Calculating Empirical Formula Calculating Molecular Formulas Excess Limiting Problems Percent Yield Problems Chemical Reactions: Writing Chemical Reactions Balancing Chemical Reactions Classification of Chemical Reactions Predicting products of each type of reaction Solubility Rules Acid/Base Reactions & Titrations Heat of reaction (exothermic, endothermic…) Modern Atomic Theory: Rutherford’s Atom, Bohr Model, and Wave Mechanical Model Quantum mechanics (electrons moving between energy levels) Quantum numbers Light and Atomic Spectra (Bright Line Spectrum…where do the lines come from?) Electron configuration Orbital Notation Valence electrons Ions, excited states and ground states Octet theory Chemical Periodicity: Development of the Periodic Table Electron configuration and the Periodic Table (know your blocks!) Periodic Table trends (Ionization energy, atomic radii, ionic radii, electronegativity, electron affinity) Bonding Ionic bonds Covalent bonds Lewis Structures Molecular shapes and VSEPR theory Octet Rule Polarity of Molecules and bonds Resonance Intermolecular attractions States of Matter: Kinetic Molecular Theory and the Nature of Gases Ideal vs. Real Gases Pressure units and conversions (atm, kPa, torr, mmHg) Temperature units and conversions (°C→ K, K → °C) Energy: State functions Enthalpy of chemical reactions Measuring energy changes Hess’s Law The Behavior of Gases: Boyle’s law, Charles’ Law, Avogadro’s principle P, V, T, n changes Ideal Gas Law (PV = nRT) Dalton’s Law of Partial Pressures “Theory” involved in all of the above laws, as well as problems incorporating these laws! Gas Stoichiometry Liquids & Solids: Phase Change Curves Intermolecular Forces Evaporation and Vapor Pressure Bonding in Solids Equilibrium: Causes of (and factor affecting) chemical reactions Dynamic Equilibrium The Equilibrium Constant Heterogenous Equilibria Le Chatelier’s Principle Water and Aqueous Solutions: Factors that affect solubility Concentration (molarity problems) Dilution Colligative properties (FP depression, BP elevation) Acids and Bases: Properties of Acids and Bases Definitions of Acids and Bases (Arrhenius, Bronsted-Lowery, Lewis) Ka, Kb expressions Strengths of acids and bases (Strong vs. Weak) Calculating pH, pOH, Kw Buffers Redox Reactions Balancing redox reactions using the half-reaction method (acidic solutions) Identifying which species is reduced and which is oxidized Identifying the reducing agent and oxidizing agents Batteries, Corrosion & Electrolysis II. How to study -I recommend a study process that gives relatively equal weight to (1) concepts, (2) process and (3) key facts. The following table summarizes suggested resources to consult for a comprehensive study program: Category Resources Concepts •Quizzes and exams •Class notes •Textbook Process •Quizzes and exams •Homework assignments •Labs Key Facts •“Study card” and reference tables (inside back cover) in textbook •iPad applications