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SCHOOL OF CHEMICAL SCIENCES
SCHOOL OF CHEMICAL SCIENCES

13 CHEMICAL EQUILIBRIUM W MODULE - 5
13 CHEMICAL EQUILIBRIUM W MODULE - 5

... hen reactants are mixed in exact stoichiometric proportion to perform a chemical W reaction, it is believed that all the reactants would be converted into products with the release or absorption of energy. This is not true in all cases. Many chemical reactions proceed only to a certain extent and st ...
One-Pot Catalytic Conversion of Cellulose and of Woody
One-Pot Catalytic Conversion of Cellulose and of Woody

... We applied this procedure to several wood sawdusts, to powdered torrefied wood, and to cellulose fibers and have identified and quantified the major components in the gas and liquid phases in each case. The liquid products fall largely into two groups of monomeric alcohols and ethers: HAE (higher alcoho ...
First Poly(2-oxazoline)s with Pendant Amino Groups
First Poly(2-oxazoline)s with Pendant Amino Groups

... and amphiphilic monomer units via block copolymerization leads to amphiphilic polysoaps that are aggregating into defined micelles at very low critical micelle concentrations (CMC  105 mol/L).[16] An additional introduction of chemical groups into the hydrophobic polymer segment allows the formati ...
Chemistry Worksheets
Chemistry Worksheets

... 1) A block of aluminum occupies a volume of 15.0 mL and weighs 40.5 g. What is its density? 2) Mercury metal is poured into a graduated cylinder that holds exactly 22.5 mL. The mercury used to fill the cylinder weighs 306.0 g. From this information, calculate the density of mercury. 3) What is the w ...
Diversity-oriented synthesis - David Spring
Diversity-oriented synthesis - David Spring

... compound libraries occupy only a small proportion of bioactive chemical space.8,25 Therefore, there may be value in screening compounds that have novel molecular architectures. These libraries should interrogate different areas of chemical space within this bioactive region (and possibly also outsid ...
Efficient Phosphodiester Hydrolysis by
Efficient Phosphodiester Hydrolysis by

... Reactivity. Kinetic experiments for the hydrolysis of the model substrate BDNPP were monitored spectrophotometrically for the absorbance increase at 400 nm due to the formation of 2,4-dinitrophenolate over time, under conditions of excess complex at 25 °C, and the reaction mixtures were monitored un ...
diploma in applied chemistry
diploma in applied chemistry

... The University of Kelaniya has its origin in the historic Vidyalankara Pirivena, founded in 1875 as a centre of learning for Buddhist monks. It was one of the two great national centers of traditional higher learning, heralding the first phase of the national movement and national resurgence. With t ...
2014 Syllabus - Cambridge International Examinations
2014 Syllabus - Cambridge International Examinations

chemistry - Mount Holyoke College Catalog
chemistry - Mount Holyoke College Catalog

the chemistry of life: organic and biological chemistry
the chemistry of life: organic and biological chemistry

... Most reactions with low or moderate activation barriers begin when a region of high electron density on one molecule encounters a region of low electron density on another molecule. The regions of high electron density may be due to the presence of a multiple bond or to the more electronegative atom ...
2 - AQA
2 - AQA

... You often have to work out how many moles are present in a particular volume of a solution of known concentration. The general formula for the number of moles in a solution of concentration c (mol dm−3) and volume V (cm3) is: number of moles in solution n = concentration c (mol dm−3) × volume V (dm− ...
Topic 9 Oxidation and Reduction Answers - slider-dpchemistry-11
Topic 9 Oxidation and Reduction Answers - slider-dpchemistry-11

... can only either remain in the same oxidation state or be oxidised as it is in its lowest oxidation state of –2 and can now only lose electrons (be oxidised). Mn is in a high oxidation state of +7 in MnO4- so is most likely reduced. From other examples you have completed, you may have noticed that Mn ...
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Document

... The value of Kc for the reaction is 1.2 . The reaction is started with [H2 ]0 = 0.76 M, [N2]0 = 0.60 M and [NH3]0= 0.48 M. Which of the following is correct as the reaction comes to equilibrium? A) The concentration of N2will increase B) The concentration of H2will decrease C) The concentration of N ...
Compounds of Chlorine
Compounds of Chlorine

... 2 Hydrogen chloride Hydrogen chloride (HCl) is prepared by the reaction of concentrated sulfuric acid (H2 SO4 ) with either NaCl or concentrated HCl solution. Hydrogen chloride is a polar molecule with a dipole of 1.08 D. However, the lower polarity as compared to that of hydrogen uoride (1.91 D) i ...
Harvard University General Chemistry Practice Problems “The
Harvard University General Chemistry Practice Problems “The

... The Ideal Gas Law ...
GCE Chemistry SAMs 2009 onwards pdf
GCE Chemistry SAMs 2009 onwards pdf

... Suggest a method, other than measuring the concentration of hydrogen peroxide, that Alice could have used to follow this reaction. ...
Exam 1
Exam 1

... • Detach the data sheet from the centre of this book during reading time. • Write your student number in the space provided above on this page. • Check that your name and student number as printed on your answer sheet for multiple-choice questions are correct, and sign your name in the space provide ...
Homework Solutions Week 6
Homework Solutions Week 6

... 2So [Ag ] =  Ksp/ [SO4 ] =  1.5x10-5/0.048 = .0177 M this is lower than .0300 M so some of the silver has already precipitated at this level of sulfate. .0177/0.0300 x 100% = 59% so 59% of the original silver is left in solution and 41% has precipitated. What can we learn from this? We can not use ...
File - IB CHEM NINJA
File - IB CHEM NINJA

... If aqueous thiocyanate ions are added to an aqueous solution of an iron(III) salt, then a blood–red colouration is observed owing to the formation of the complex ion shown. If the concentration of either the thiocyanate ion or the iron(III) ion is increased, then the intensity of the colouration inc ...
chapter 3 Questions
chapter 3 Questions

Appendices - Mattson Creighton
Appendices - Mattson Creighton

... corresponds to 0.0050 mol HCl. Because they react !:1, NaHCO3 is the limiting reactant. 11. 64 mL at 25 oC and 1 atm pressure 12. The density of carbon dioxide at 25 oC and 1 atm pressure is 1.80 g/L. 13. Using the “average molar mass of air”, 28.964 g/mol, the density of air is 1.18 g/L. The ratio ...
chemistry sp.indd
chemistry sp.indd

... (ii) Hydrogen sulfide is a gas at room temperature and pressure. In fact, all of the hydrogen compounds of Group 16 elements are gases at room temperature and pressure except for that of oxygen. Explain this observation, referring to the intermolecular forces in hydrogen sulfide and in the hydrogen ...
File
File

File
File

... important molecules, and silicon, found in most of the compounds that make up the earth’s crust. They are important because they are so prevalent in compounds necessary for life and the geologic world. As with Group 3A, Group 4A shows an increase in metallic character as the elements get heavier. Ca ...
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Bioorthogonal chemistry



The term bioorthogonal chemistry refers to any chemical reaction that can occur inside of living systems without interfering with native biochemical processes. The term was coined by Carolyn R. Bertozzi in 2003. Since its introduction, the concept of the bioorthogonal reaction has enabled the study of biomolecules such as glycans, proteins, and lipids in real time in living systems without cellular toxicity. A number of chemical ligation strategies have been developed that fulfill the requirements of bioorthogonality, including the 1,3-dipolar cycloaddition between azides and cyclooctynes (also termed copper-free click chemistry), between nitrones and cyclooctynes, oxime/hydrazone formation from aldehydes and ketones, the tetrazine ligation, the isocyanide-based click reaction, and most recently, the quadricyclane ligation.The use of bioorthogonal chemistry typically proceeds in two steps. First, a cellular substrate is modified with a bioorthogonal functional group (chemical reporter) and introduced to the cell; substrates include metabolites, enzyme inhibitors, etc. The chemical reporter must not alter the structure of the substrate dramatically to avoid affecting its bioactivity. Secondly, a probe containing the complementary functional group is introduced to react and label the substrate.Although effective bioorthogonal reactions such as copper-free click chemistry have been developed, development of new reactions continues to generate orthogonal methods for labeling to allow multiple methods of labeling to be used in the same biosystems.
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