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Thermochemistry Review
Thermochemistry Review

... A. The heat required to raise the temperature of one gram of water by one Celsius degree. B. The heat required to raise the temperature of one mole of water by one Celsius degree. C. The heat required to raise the temperature of one gram of substance by one Celsius degree. D. The heat required to ra ...
Chapter 11.1: Describing Chemical Reactions
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... Aqueous solution (dissolved in water) Indicates that heat is supplied to the reaction A formula written above or below a yield sign indicates its use as a catalyst (in tis example, Sulfuric Acid). ...
CST REVIEW Percent Error 1. 2. What is the formula for density?
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... 9.92 The amide ion, NH-2 , is a Bronsted base, Represent the reaction between the amide ion and water. 9.94 The triiodide ion (I-3) in which the I atoms are arranged in a straight line is stable, but the corresponding F-3 ion does not exist. Explain. 9.96 Methyl isocyanate (CH3NCO) is used to make c ...
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... • Explain the effect a catalyst has on a chemical reaction. • Explain chemical equilibrium in terms of equal forward and reverse reaction rates. ...
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... A) Li+ (aq) + SO42-(aq) + Cu+(aq) + NO3-(aq) → CuS(s) + Li+(aq) + NO3-(aq) B) Li+ (aq) + S-(aq) + Cu+(aq) + NO3-(aq) → CuS(s) + LiNO3(aq) C) 2 Li+(aq) + S2-(aq) + Cu2+(aq) + 2 NO3-(aq) → Cu2+(aq) + S2-(aq) + 2 LiNO3(s) D) 2 Li+(aq) + S2-(aq) + Cu2+(aq) + 2 NO3-(aq) → CuS(s) + 2 Li+(aq) + 2 NO3-(aq) ...
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... Some iron wire weighing 5.6 g is placed in a beaker and covered with 15.1 g of hydrochloric acid. The acid reacts with the metal and gives off hydrogen gas, which escapes into the surrounding air. After reaction the contents of the beaker weighs 20.4 g. What is the mass of hydrogen produced? Write t ...
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... ∆H0reaction = Σ n∆H0f products - Σ n∆H0f reactants ∆H0rxn = [6 mol x ∆H0f of H2O(l) + 6 mol x ∆H0f of CO2(g)] – [2 mol x ∆H0f of C3H6(g) + 9 mol x ∆H0f of O2(g)] ∆H0rxn = [ 6 mol x(-285.8 kJ/mol) + 6 mol x (-393.5 kJ/mol) ] – [ 2 mol x (17.8 kJ/mol) + 9 mol x (0 kJ/mol)] ∆H0rxn = [ -1714.8 kJ + -236 ...
SAMPLE PAPER -9 Time Allowed: 3 Hrs
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... chains are arranged side by side in Zig – Zag with alternate R on same side. Two neighbouring chains are held by H bond . Sheets are stacked one above the other like pages of book. ...
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... 58 Determine the total number of electrons in the bonds between the nitrogen atom and the three hydrogen atoms represented in diagram 2. [1] 59 Explain, in terms of distribution of charge, why a molecule of the substance represented in diagram 3 is nonpolar. [1] 60 Draw a Lewis electron-dot diagram ...
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... heat. -----------------------------------------------------------------------------------------------------------(d) is a false statement: production of 6 moles of CO2 will produce 4440 kJ of heat. The reaction is exothermic. Energy would be required if the reaction was endothermic. (a) is true sinc ...
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... of the system, regardless of how that condition was achieved. energy, pressure, volume, temperature ...
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... cation of another compound. AX + BZ  AZ + BX These reactions proceed if one of the ff. is satisfied: 1. An insoluble/slightly soluble product is formed (PRECIPITATE formation) 2. A weakly ionized species is produced. The most common species of this type is water. 3. A gas is produced as a product. ...
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Bioorthogonal chemistry



The term bioorthogonal chemistry refers to any chemical reaction that can occur inside of living systems without interfering with native biochemical processes. The term was coined by Carolyn R. Bertozzi in 2003. Since its introduction, the concept of the bioorthogonal reaction has enabled the study of biomolecules such as glycans, proteins, and lipids in real time in living systems without cellular toxicity. A number of chemical ligation strategies have been developed that fulfill the requirements of bioorthogonality, including the 1,3-dipolar cycloaddition between azides and cyclooctynes (also termed copper-free click chemistry), between nitrones and cyclooctynes, oxime/hydrazone formation from aldehydes and ketones, the tetrazine ligation, the isocyanide-based click reaction, and most recently, the quadricyclane ligation.The use of bioorthogonal chemistry typically proceeds in two steps. First, a cellular substrate is modified with a bioorthogonal functional group (chemical reporter) and introduced to the cell; substrates include metabolites, enzyme inhibitors, etc. The chemical reporter must not alter the structure of the substrate dramatically to avoid affecting its bioactivity. Secondly, a probe containing the complementary functional group is introduced to react and label the substrate.Although effective bioorthogonal reactions such as copper-free click chemistry have been developed, development of new reactions continues to generate orthogonal methods for labeling to allow multiple methods of labeling to be used in the same biosystems.
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