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IB Definitions
IB Definitions

... An exothermic reaction is one in which there is an overall negative enthalpy change (heat is evolved) An endothermic reaction is one in which there is an overall postive enthalpy change (heat is absorbed) The standard enthalpy change of a reaction is the enthalpy change when one mole of reactants is ...
Lecture 20 The Redox Sequence
Lecture 20 The Redox Sequence

... There is an ideal sequence of redox reactions driven by e- rich organic matter that is based on the energy available for the microbes that mediate the reactions. In this sequence organic matter is combusted in order by O2 → NO3 → MnO2 → Fe2O3 → SO42- (decreasing energy yield). Most of these reaction ...
Chapter 11 Chemical Reactions
Chapter 11 Chemical Reactions

... Never change a subscript to balance an equation (You can only change coefficients) – If you change the subscript (formula) you are describing a different chemical. – H2O is a different compound than H2O2  Never put a coefficient in the middle of a formula; they must go only in the front ...
Unit 10
Unit 10

Chemistry: Chemical Reactions Notes STOP
Chemistry: Chemical Reactions Notes STOP

... 1. If  you  are  given  a  word  equation  with  only  reactants  finish  the  word  equation  by  writing  the  chemical  names   of  the  products.    Remember  positive  ions  keep  the  same  name  as  their  neutral  element  ( ...
Gas-Phase Basicity of (CH3)3N
Gas-Phase Basicity of (CH3)3N

... Coulomb interaction, a point-charge Coulomb energy was calculated from the coordinates of the quaternary nitrogen (q1 ) +1) and the midpoint of the two carboxylate oxygen atoms (q2 ) -1). These values, subtracted from the GB of benzoate (solid line), along with the calculated and measured GB values ...
Unit 1: Building Blocks Homework
Unit 1: Building Blocks Homework

... 7) The alkali metals, the halogens and the noble gases are the names of groups of elements in the Periodic Table. Copy and complete the table by circling a word in each box to give correct information about each group. (Two pieces of correct information have already been circled.) ...
Notes
Notes

... If  two  half-­‐reactions  can  be  added  together  to  give  a  REDOX  reaction,  the  voltages  associated  with   the  half-­‐reactions  can  also  be  added.   ...
Chapter 2 Chemical Reactions
Chapter 2 Chemical Reactions

... Cu(s) + AgNO3(aq)  Ag(s) + Cu(NO3)2(aq) ...
chem eng-problems
chem eng-problems

... 1) If I have 340 mL of a 0.5 M NaBr solution, what will the concentration be if you add 560 mL more water to it? ...
Chemistry Final Exam Review 2006-2007
Chemistry Final Exam Review 2006-2007

... 7. a. What is the difference between ionic and covalent bonds? b. How does electronegativity difference determine bond type? 8. Write the electron configurations for a. Al+3 b. O-2 c. Ti+2. 9. Draw Lewis structures for the following; a. K2O b. MgCl2 c. KI d. Na3P 10. Which of the following compounds ...
Carefully detach the last page. It is the Data Sheet.
Carefully detach the last page. It is the Data Sheet.

... incomplete chemical equation for the radioactive decay of 131I is given below. ...
CHM 2045C - State College of Florida
CHM 2045C - State College of Florida

... This course meets Area V for the A.A./A.S. general education requirements. A rigorous study of chemistry principles for students who have already studied basic concepts of chemistry. This course is intended for science and science-related majors. ...
Molar Heat of Reaction
Molar Heat of Reaction

... (which is usually water) Expressed in kilojoules per mole (kJ/mol) of dissolved solute In this reaction heat can be either released or absorbed ...
Chemical Bonding (short)
Chemical Bonding (short)

... We will work more with these graphs later. Activation energy is added to “get over the wall Energy stored in the molecules is on the Y axis ...
Chapter 3
Chapter 3

...  Thus: one mole of N2 plus three moles of H2 react to produce two moles of NH3.  This means our relations can be shortened to moles. LEP #7 ...
C 3 H 8 (g) - Ms Critchley`s Lab
C 3 H 8 (g) - Ms Critchley`s Lab

... • Using a calorimeter for a combustion reaction or or other reaction can often give the ΔHr directly (think about the spirit burners and copper sulphate experiments you have done). • Bond enthalpies can also be used to estimate ΔHr ...
Chapter 6
Chapter 6

... chemical reaction, the total mass of the reactants is always equal to the total mass of the products. Experiments show that atoms in a chemical reaction are not changed themselves, and the number of atoms has to stay the same from before the reaction to after. ...
College Chemistry I PHS 1025 Fall 2012 Practice Exam 3A
College Chemistry I PHS 1025 Fall 2012 Practice Exam 3A

... Cr(OH)4-(aq) → CrO42-(aq) + 4 H+(aq) + 3eD) Cr(OH)4-(aq) + 4 OH-(aq) → CrO42-(aq) + 4 H2O(l) + 3e46) If 100. mL of 0.100 M Na2SO4 is added to 200. mL of 0.150 M NaCl, what is the concentration of Na+ ions in the final solution? Assume that the volumes are additive. A) 0.167 M ...
Measuring and Calculating
Measuring and Calculating

...  atoms are held together by the sharing of a pair of electrons, which involves an overlap of the electron clouds and thus forms a strong bond and forms individual molecules. Occurs between nonmetal atoms.  Nonpolar covalent bond – very low electronegativity difference, results in a nearly equal sh ...
File
File

... It’s time to practice what you have already learned about moles, chemical reactions and dimensional analysis. We will learn one new conversion factor and then combine it with other concepts. Molar Volume is the volume of one mole of gas. Since the space between molecules in a gas is very great compa ...
AP Chemistry Unit 3 Test Review Topics Covered: Gases Liquids
AP Chemistry Unit 3 Test Review Topics Covered: Gases Liquids

An Efficient Synthetic Route to Glycoamino Acid Building Blocks for
An Efficient Synthetic Route to Glycoamino Acid Building Blocks for

... During previous work on the synthesis of glycopeptides, two strategies have been employed. One approach introduces the carbohydrate as part of a glycoamino acid building block during solid-phase synthesis of the polypeptide chain.5 Alternatively, the carbohydrate can be attached to a selectively dep ...
Balancing Chemical Equations
Balancing Chemical Equations

... the numbers of oxygen on the right side. You cannot add a subscript number in a reaction to change the amount of atoms, you can only change the amount of compounds. Therefore you add another to the front of the compound. Since the compounds cannot be separated, you cannot just add a two in front of ...
Sections 6.4 - 6.5
Sections 6.4 - 6.5

... → These pairs show a similar balance of covalent/electrostatic bonding to more electronegative partners and therefore similar reactivity patterns. ...
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Bioorthogonal chemistry



The term bioorthogonal chemistry refers to any chemical reaction that can occur inside of living systems without interfering with native biochemical processes. The term was coined by Carolyn R. Bertozzi in 2003. Since its introduction, the concept of the bioorthogonal reaction has enabled the study of biomolecules such as glycans, proteins, and lipids in real time in living systems without cellular toxicity. A number of chemical ligation strategies have been developed that fulfill the requirements of bioorthogonality, including the 1,3-dipolar cycloaddition between azides and cyclooctynes (also termed copper-free click chemistry), between nitrones and cyclooctynes, oxime/hydrazone formation from aldehydes and ketones, the tetrazine ligation, the isocyanide-based click reaction, and most recently, the quadricyclane ligation.The use of bioorthogonal chemistry typically proceeds in two steps. First, a cellular substrate is modified with a bioorthogonal functional group (chemical reporter) and introduced to the cell; substrates include metabolites, enzyme inhibitors, etc. The chemical reporter must not alter the structure of the substrate dramatically to avoid affecting its bioactivity. Secondly, a probe containing the complementary functional group is introduced to react and label the substrate.Although effective bioorthogonal reactions such as copper-free click chemistry have been developed, development of new reactions continues to generate orthogonal methods for labeling to allow multiple methods of labeling to be used in the same biosystems.
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