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Chemistry B1A CRN:________ Name:_______________________ Date:________________________ I. Choose the correct answer(s) for the following questions: 1. The following are examples of physical and chemical changes. Circle the physical changes. a. sugar dissolving in water b. iron rusting c. melting of sodium chloride d. wood decaying 2. Following are properties of substances. Circle the properties that are chemical properties. a. Salt substitute , potassium chloride, dissolving in water b. Pure water freezing at 0oC. c. Steel wool burning in air d. Limestone fizzing when it is dissolved in vinegar e. Bread cooking in the oven 3. Following are some pure substances and some mixtures. Which are pure substances? a. a sugar solution with crystals of sugar at the bottom b. ink containing a liquid solution with fine carbon particles c. liquid water and steam at 100oC d. a sand containing quartz and calcite 4. Which of the following temperatures might be a good day to go to the beach? a. 0 K b. 100 K c. 100 oF d. 100 oC e. 35 oC 5. Which of the following are metals? a. Si b. Ar c. K d. Ba e. Br The correct formula mass of CaCO3 is: a. 40 g b. 100 g c. 100 amu d.56 amu e. none of these The oxidation number of Cl in HClO3 is: a. –1 b. +1 c. +3 d. +5 e. +7 6. 7. 8. Which of the following compounds will evolve a gas when reacted with a strong acid? a. CaCO3 b. Na2S c. CaSO4 d. Na3PO4 e. Na2SO3 9. Oxidation and reduction are said to; a. never occur b. involve neutrons c. always occur together d. always involves oxygen 10. Page 1 was: a. easy b. not so easy c. impossible d. torturous II. Solve discuss or answer with explanation the following questions. Show all calculations and use appropriate significant figures. 10. A mineral has a mass of 31.5 g and a volume of 7.9 cm3. The mineral is either sphalerite (density = 4.0 g/cm3), casserite (density = 6.99 g/cm3) or cinnabar (density 8.10 g/cm3).. Which is it? 11. How many significant figures are there in each of the following numbers? a. 73,000 g_______ 12. b. 73.0000 g________ c. 0.0120 g _________ Consider the following compounds and their densities. Substance Density (g/mL) Isopropyl alcohol 0.785 n-butyl alcohol 0.810 Substance Toluene Ethylene glycol Density (g/mL) 0.866 1.114 You create a column of the liquids in a glass cylinder. Draw a sketch and indicate which liquid is at which level in the column. Then explain what would happen if you did the following: a. First you drop a plastic bead that has a density of 0.24 g/cm3 into the column. b. You drop a bead in that makes it all the way to the bottom. What can you say about the density of this bead? c. You drop a bead with a volume of 0.043 mL and a mass of 3.92 x 10-2 g into the column. What happens? 13. Some iron wire weighing 5.6 g is placed in a beaker and covered with 15.1 g of hydrochloric acid. The acid reacts with the metal and gives off hydrogen gas, which escapes into the surrounding air. After reaction the contents of the beaker weighs 20.4 g. What is the mass of hydrogen produced? Write the reaction. What law do you use to solve this problem? 14. The label on a soda can indicates that the can contains 12 fluid ounces and 355 mL. How could you determine the conversion from ounces to mL from this information? 15. Which of the following models represent a(n) a. Element__________________ b. Compound_______________ c. Mixture_________________ d. Ionic Solid_______________ e. Mixture of elements_______ f. Solid element_____________ g. Solid___________________ h. Liquid__________________ i. Gas containing an element and a compound____________ 16. Dalton explained elements atoms compounds and reactions with his atomic theory. What were the four postulates of the atomic theory and how does his theory explain chemical reactions? 17. An element has two naturally occurring isotopes. The following data was determined for the element: Isotopic Mass (amu) 63.390 64.928 Fractional Abundance 0.6909 0.3091 What is the elements atomic weight and what is the element? 18. In the following equation (unbalanced), (a) give the oxidation state of each element in the equation, (b) tell what is oxidized and what is reduced, and (c) give the name of each substance in the equation. MnO2 + 19. 20. HCl MnCl2 + Cl2 + H2O Give the systematic names of the following binary compounds: a. N2O ______________________ b. CCl4 ______________________ c. Na2O______________________ d. CaS_______________________ Write the formula from the following names: a. dichlorine pentoxide _____________ b. oxygen difluoride_____________ c. copper (I) hydroxide_____________ d. ammonium bromide___________ 21. Write the nuclide symbol for and element containing 12 protons, 12 neutrons and 12 electrons. What would be the nuclide symbol if the element lost two electrons? 22. You have in your hand 35.6 g of BaCr2O7. Calculate the following for this quantity of substance. a. Moles of BaCr2O7 b. Formula Units of BaCr2O7 c. Total number of atoms present 23. What six evidences might be observed when two substances are combined? 24. Potassium superoxide, K2O, is used in rebreathing gas masks to generate oxygen. If a reaction vessel contains 0.20 mol K2O and 0.25 moles of H2O, what is the limiting reactant and how much oxygen can be produced? 4 K2O (s) + 2 H2O (l) 4 KOH (s) + 3 H2O (g) 25. Using the half reaction method, balance the following redox equation. CuCl2 (aq) + Al (s) AlCl3 (aq) + Cu (s) 26. Using your solubility chart, determine if a reaction occurs when the following set of substances are combined. If there is a reaction complete it and if none occurs write NR. Write the total ionic equation and the net ionic equation for each reaction. AgNO3 + NaI Na2SO4 + Ba(NO3) 27. Explain the difference between a weak acid and a strong acid and describe how you could identify each. 28. A moth repellent, p-dichlorobenzene, has the composition 49.1% C, 2.7% H, and 48.2 % Cl. Its molecular weight is 112 amu. What is the molecular formula? 29. Explain the mole concept in chemistry? Why is it important? 30. Describe the development of the periodic table, how it was originally arranged, how it is currently arranged, what standard is used to determine the atomic weight and what information can be determine from the table. III. Match the following Definitions a. ____ Precise 1. Equal protons but unequal neutrons b. ____ Mixture 2. Mixture that is the same throughout c. ____ Matter 3. Smallest whole number ratio d. ____ Metal 4. Sum of atomic masses in grams e. ____Isotope 5. Exact quantity calculated from an equation f. ____ Atomic number 6. Substance having luster and usually conducts heat g. ____Theoretical yield 7. Combination of two or more substances h. ____Empirical Formula 8. All the substances around us i. ____ Homegenous mixture 9. Mixture in which components can be identified j. ____ Heterogeneous mixture 10. Product that should be recovered k. ____Stoichiometric quantity 11. Data that is reproducible l. ____ Molar mass 12. Data that is near theoretical number m. ___ Accurate 13. Number of protons in the nucleus n. ____ Carbon-12 14. Simplest form of matter o. ____ Atom 15. Mass standard for the periodic chart