Chapter 1: The first law of thermodynamics
... and volume we say that the quantity is a function of state. Therefore, for an ideal gas in equilibrium, the system’s temperature is a function of state ( θ = F ( P,V ) ). A quantity, dG, is said to be an exact differential if it only depends on the difference in the function of state between two clo ...
... and volume we say that the quantity is a function of state. Therefore, for an ideal gas in equilibrium, the system’s temperature is a function of state ( θ = F ( P,V ) ). A quantity, dG, is said to be an exact differential if it only depends on the difference in the function of state between two clo ...
Ion Exchange
... Ion Exchange Ion-exchange chromatography retains analyte molecules on the column based on coulombic (ionic) interactions. The stationary phase surface displays ionic functional groups (R-X) that interact with analyte ions of opposite charge. An ion-exchange resin or ion-exchange polymer is an insolu ...
... Ion Exchange Ion-exchange chromatography retains analyte molecules on the column based on coulombic (ionic) interactions. The stationary phase surface displays ionic functional groups (R-X) that interact with analyte ions of opposite charge. An ion-exchange resin or ion-exchange polymer is an insolu ...
Influence of the ambient temperature during heat pipe
... of human error and minimize the impact of inertia radiator. Taking simply the heat pipes and the use thereof, it is obvious that the tube filled with water, even if they have better transport properties such as ethanol, are not suitable for application in the external environment in our geographic a ...
... of human error and minimize the impact of inertia radiator. Taking simply the heat pipes and the use thereof, it is obvious that the tube filled with water, even if they have better transport properties such as ethanol, are not suitable for application in the external environment in our geographic a ...
Chapter 8 Thermochemistry: Chemical Energy
... Standard Heats of Formation Standard Heat of Formation (DHof ): The enthalpy change for the formation of 1 mol of a substance in its standard state from its constituent elements in their ...
... Standard Heats of Formation Standard Heat of Formation (DHof ): The enthalpy change for the formation of 1 mol of a substance in its standard state from its constituent elements in their ...
Body Temperature
... When body temperature drops too low, the hypothalamus decreases the blood flow to the surface of the skin, thereby decreasing heat loss. It also triggers small involuntary contractions of muscles; the biochemical reactions that generate the energy to do this work also generate more heat for the body ...
... When body temperature drops too low, the hypothalamus decreases the blood flow to the surface of the skin, thereby decreasing heat loss. It also triggers small involuntary contractions of muscles; the biochemical reactions that generate the energy to do this work also generate more heat for the body ...
Chapter 15 Lesson 2
... OF THE SECOND LAW OF THERMODYNAMICS No irreversible engine operating between two reservoirs at constant Temperatures can have a greater efficiency than a reversible engine operating between the same temperatures. Furthermore, all reversible engines operating between the same temperatures have the sa ...
... OF THE SECOND LAW OF THERMODYNAMICS No irreversible engine operating between two reservoirs at constant Temperatures can have a greater efficiency than a reversible engine operating between the same temperatures. Furthermore, all reversible engines operating between the same temperatures have the sa ...
Countercurrent exchange
Countercurrent exchange is a mechanism occurring in nature and mimicked in industry and engineering, in which there is a crossover of some property, usually heat or some component, between two flowing bodies flowing in opposite directions to each other. The flowing bodies can be liquids, gases, or even solid powders, or any combination of those. For example, in a distillation column, the vapors bubble up through the downward flowing liquid while exchanging both heat and mass.The maximum amount of heat or mass transfer that can be obtained is higher with countercurrent than co-current (parallel) exchange because countercurrent maintains a slowly declining difference or gradient (usually temperature or concentration difference). In cocurrent exchange the initial gradient is higher but falls off quickly, leading to wasted potential. For example, in the diagram at the right, the fluid being heated (exiting top) has a higher exiting temperature than the cooled fluid (exiting bottom) that was used for heating. With cocurrent or parallel exchange the heated and cooled fluids can only approach one another. The result is that countercurrent exchange can achieve a greater amount of heat or mass transfer than parallel under otherwise similar conditions. See: flow arrangement.Countercurrent exchange when set up in a circuit or loop can be used for building up concentrations, heat, or other properties of flowing liquids. Specifically when set up in a loop with a buffering liquid between the incoming and outgoing fluid running in a circuit, and with active transport pumps on the outgoing fluid's tubes, the system is called a Countercurrent multiplier, enabling a multiplied effect of many small pumps to gradually build up a large concentration in the buffer liquid.Other countercurrent exchange circuits where the incoming and outgoing fluids touch each other are used for retaining a high concentration of a dissolved substance or for retaining heat, or for allowing the external buildup of the heat or concentration at one point in the system.Countercurrent exchange circuits or loops are found extensively in nature, specifically in biologic systems. In vertebrates, they are called a Rete mirabile, originally the name of an organ in fish gills for absorbing oxygen from the water. It is mimicked in industrial systems. Countercurrent exchange is a key concept in chemical engineering thermodynamics and manufacturing processes, for example in extracting sucrose from sugar beet roots.Countercurrent multiplication is a similar but different concept where liquid moves in a loop followed by a long length of movement in opposite directions with an intermediate zone. The tube leading to the loop passively building up a gradient of heat (or cooling) or solvent concentration while the returning tube has a constant small pumping action all along it, so that a gradual intensification of the heat or concentration is created towards the loop. Countercurrent multiplication has been found in the kidneys as well as in many other biological organs.