Class notes
... The concept of free energy comes from the need to simultaneously deal with the enthalpy energy and entropy of a system G = H -TS G = U+PV - TS dG= dU + PdV + VdP -TdS -SdT dH = dU +pdV at const temp and pressure G= H -TS ...
... The concept of free energy comes from the need to simultaneously deal with the enthalpy energy and entropy of a system G = H -TS G = U+PV - TS dG= dU + PdV + VdP -TdS -SdT dH = dU +pdV at const temp and pressure G= H -TS ...
heat engine
... In general, irreversible processes cause us to lose some, but not necessarily all, of the ability to do work. This partial loss can be expressed in terms of a concept called entropy. ...
... In general, irreversible processes cause us to lose some, but not necessarily all, of the ability to do work. This partial loss can be expressed in terms of a concept called entropy. ...
thermodynamic study of solvation and complex formation in system
... The important problem of solutions chemistry concerns determination of comprehensive thermodynamic characteristics of the processes in multicomponent liquid systems. In real biological systems there are complex interactions between amino acids, peptides, "metals of life» and aqueous solvent. The rol ...
... The important problem of solutions chemistry concerns determination of comprehensive thermodynamic characteristics of the processes in multicomponent liquid systems. In real biological systems there are complex interactions between amino acids, peptides, "metals of life» and aqueous solvent. The rol ...
Filtration
... Chloramines (NH2Cl or NHCl2) Ozone (O3) Chlorine Dioxide (ClO2) Others: Bromine, UV light ...
... Chloramines (NH2Cl or NHCl2) Ozone (O3) Chlorine Dioxide (ClO2) Others: Bromine, UV light ...
Energy - Montana State University Billings
... Changes in density drive vertical motion in the atmosphere and ocean. • Lower density air rises when it is surrounded by denser air. -Think of a hollow plastic ball submerged under water. What happens when you release it? ...
... Changes in density drive vertical motion in the atmosphere and ocean. • Lower density air rises when it is surrounded by denser air. -Think of a hollow plastic ball submerged under water. What happens when you release it? ...
Lecture 5: Heat transmission
... rest of the room and eventually heat the entire room. How do convection currents work? The hot radiator warms the air that is closest to the radiator. The warm air expands, becomes less dense and rises to the top of the room. When the air reaches the top of the room it is pushed sideways towards the ...
... rest of the room and eventually heat the entire room. How do convection currents work? The hot radiator warms the air that is closest to the radiator. The warm air expands, becomes less dense and rises to the top of the room. When the air reaches the top of the room it is pushed sideways towards the ...
Thermoregulation contributes to homeostasis and involves anatomy
... a cold morning, just as a lizard does. Endothermy has several important advantages. Being able to generate a large amount of metabolic heat enables endotherms to perform vigorous activity for much longer than is possible for most ectotherms. Sustained intense exercise, such as long-distance running ...
... a cold morning, just as a lizard does. Endothermy has several important advantages. Being able to generate a large amount of metabolic heat enables endotherms to perform vigorous activity for much longer than is possible for most ectotherms. Sustained intense exercise, such as long-distance running ...
Exam 1
... 11. The standard molar enthalpy of formation of NH3(g) is -45.9 kJ/mol. What is the enthalpy change if 5.38 g N2(s) and 3.32 g H2(g) react to produce NH3(g)? 12. The lid is tightly sealed on a rigid flask containing 3.50 L H2 at 17 °C and 0.913 atm. If the flask is heated to 71 °C, what is the press ...
... 11. The standard molar enthalpy of formation of NH3(g) is -45.9 kJ/mol. What is the enthalpy change if 5.38 g N2(s) and 3.32 g H2(g) react to produce NH3(g)? 12. The lid is tightly sealed on a rigid flask containing 3.50 L H2 at 17 °C and 0.913 atm. If the flask is heated to 71 °C, what is the press ...
17 Oct 08 - Seattle Central College
... • Add 100 J of heat to a collection of 100 water molecules. • Add 100 J of heat to a collection of 1,000,000 water molecules. • Which system will exhibit the greatest increase in T? – The collection of 100 water molecules. – Same amount of heat delivered, different average velocities, different ...
... • Add 100 J of heat to a collection of 100 water molecules. • Add 100 J of heat to a collection of 1,000,000 water molecules. • Which system will exhibit the greatest increase in T? – The collection of 100 water molecules. – Same amount of heat delivered, different average velocities, different ...
Countercurrent exchange
Countercurrent exchange is a mechanism occurring in nature and mimicked in industry and engineering, in which there is a crossover of some property, usually heat or some component, between two flowing bodies flowing in opposite directions to each other. The flowing bodies can be liquids, gases, or even solid powders, or any combination of those. For example, in a distillation column, the vapors bubble up through the downward flowing liquid while exchanging both heat and mass.The maximum amount of heat or mass transfer that can be obtained is higher with countercurrent than co-current (parallel) exchange because countercurrent maintains a slowly declining difference or gradient (usually temperature or concentration difference). In cocurrent exchange the initial gradient is higher but falls off quickly, leading to wasted potential. For example, in the diagram at the right, the fluid being heated (exiting top) has a higher exiting temperature than the cooled fluid (exiting bottom) that was used for heating. With cocurrent or parallel exchange the heated and cooled fluids can only approach one another. The result is that countercurrent exchange can achieve a greater amount of heat or mass transfer than parallel under otherwise similar conditions. See: flow arrangement.Countercurrent exchange when set up in a circuit or loop can be used for building up concentrations, heat, or other properties of flowing liquids. Specifically when set up in a loop with a buffering liquid between the incoming and outgoing fluid running in a circuit, and with active transport pumps on the outgoing fluid's tubes, the system is called a Countercurrent multiplier, enabling a multiplied effect of many small pumps to gradually build up a large concentration in the buffer liquid.Other countercurrent exchange circuits where the incoming and outgoing fluids touch each other are used for retaining a high concentration of a dissolved substance or for retaining heat, or for allowing the external buildup of the heat or concentration at one point in the system.Countercurrent exchange circuits or loops are found extensively in nature, specifically in biologic systems. In vertebrates, they are called a Rete mirabile, originally the name of an organ in fish gills for absorbing oxygen from the water. It is mimicked in industrial systems. Countercurrent exchange is a key concept in chemical engineering thermodynamics and manufacturing processes, for example in extracting sucrose from sugar beet roots.Countercurrent multiplication is a similar but different concept where liquid moves in a loop followed by a long length of movement in opposite directions with an intermediate zone. The tube leading to the loop passively building up a gradient of heat (or cooling) or solvent concentration while the returning tube has a constant small pumping action all along it, so that a gradual intensification of the heat or concentration is created towards the loop. Countercurrent multiplication has been found in the kidneys as well as in many other biological organs.