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Final Exam Study Guide (CHE 102, Spring 2007) The final exam, on Tuesday June 12th, is a comprehensive exam. It is open to lecture and lab notes but closed to chemistry textbooks. You do not need to rely on memorization as much but have the ability to solve the problems and use provided information. Quizzes, homework problems, practice exams, exams one to three, and the active learning exercises are indicative of the type of questions you will be asked. You do need a calculator and a copy of the period table will be available to you. You are responsible for material covered both in the textbook and in the lectures. Generally, you need to be proficient in naming organic compounds and draw their structural formulas. You will need to be very familiar with the organic reactions we have studies over the course, including those of alkenes, alkynes, alcohols, phenols, ethers, thiols, aldehydes, ketones, carboxylic acids, esters, amines and amides. You are expected to know how to synthesize organic products involving the reactions we have learned and predict products from starting material. Here is a general study guide for each chapter to help you focus as you get ready for the final. Since what you will not be tested on is minimal versus the testable material, I first list two areas that you don’t need to study and you won’t be tested on: How to draw structural formulas of monomers that form a polymer or a three-monomer section of a polymer (from chapter 12). Fisher Projections (chapter 14) Everything else is a fair game. Chapter Specific Study Guide Chapter 11 Identify properties characteristic of organic or inorganic compounds. Write the IUPAC names and structural formulas for alkanes. Write the IUPAC names for alkanes with substituents. Identify the properties of alkanes and write a balanced equation for combustion. Classify organic molecules according to their functional groups. Chapter 12 Write the IUPAC names for alkenes and alkynes; give common names for simple structures. Write the structural formulas and names for constitutional cis-trans isomers of alkenes. Write the structural formulas and names for the organic products of addition reactions of alkenes and alkynes. Describe the bonding in benzene; name aromatic compounds, and write their structural formulas. Describe the physical and chemical properties of aromatic compounds; draw structural formulas produced by substitution of benzene. Chapter 13 Give IUPAC and common names for alcohols, phenols, and Thiols; draw their condensed structural formulas. Give the IUPAC names of ethers; draw the condensed structural formula. Describe some physical properties of alcohols, phenols, and ethers. Write equations for combustion, dehydration, and oxidation of alcohols. Chapter 14 Identify compounds with the carbonyl group as aldehydes and ketones; give the IUPAC and common names for aldehydes and ketones; draw their condensed structural formulas. Compare the boiling points and solubility of aldehydes and ketones to those of alkanes and alcohols. Draw the structural formulas of reactants and products for the oxidation or reduction of aldehydes and ketones. Write the products of the addition of alcohols to aldehydes and ketones. Identify chiral and achiral carbon atoms in an organic molecule. Chapter 16 Give the common names, IUPAC names and condensed structural formulas of carboxylic acids. Describe the boiling points, solubility and ionization of carboxylic acids in water. Name an ester; write equations for the formation and hydrolysis of an ester. Write the IUPAC and common names for esters; draw condensed structural formulas. Describe the boiling points and solubility of esters. Draw the condensed structural formulas of the hydrolysis products. Chapter 18 Classify amines as primary, secondary, or tertiary. Name amines using common and IUPAC names; draw the condensed structures given the names. Describe the boiling points and solubility of amines; write equations for the neutralization of amines. Identify heterocyclic amines; distinguish between the types of heterocyclic amines. Write the amide products of amidation and give their common and IUPAC names. Write the equations for the hydrolysis of amides. Supplemental Material Name compounds that contain alkene and alkyne functionality in addition to their main functional group Combine reactions in all chapters to form new organic products). Saponification and other lab techniques (review these) Much of these are skills you have learned in lecture, covered by your homework problems, quizzes, group activity exercises, and active learning exercises. As such, you ought to be adept in these topics and very familiar with them.