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PH 401 Dr. Cecilia Vogel Lecture 1 Review Review 301 quantum section Outline light waves matter waves duality, complementarity wave function probability Light and Quantum Quantum Mechanics began historically with light Light was known to be an EM wave obey wave equation 2E=me∂2E/∂t2. solutions sin(kx-wt) and cos(kx-wt) and any combo thereof Light also found to have particle nature individual, indivisible photons Each photon has E=hf=w and p = h/l = k Where EM wave has large amplitude bright, many photons any one photon likely to be ther Wave-particle duality Light (and matter( have both wave and particle properties gives people issues due to perceptions: IF you perceive a wave as having a wavelength IF you perceive a particle as having a position that’s not the whole story Reality is a gray area between these extremes the wave/particle has a spread of positions and a spread of wavelengths All well-behaved functions are like this: DxDk>1/2 Matter Matter particles, like electrons, have particle properties (of course) individual, indivisible particles energy & momentum Matter particles, also have wave properties! They diffract! They interfere! Obey a wave equation = Time-dependent Schroedinger eqn Duality equations wave and particle properties are related E hf h p h/l E w p k wavefunction is a function of (kx-wt) Complex Wavefunction If you have issues with a physical quantity like wavefunction being complex all measureable quantities will be real like probability density = |Y|2. OR you can think of wavefucntion as having two components like light has E-field and B-field each component will be real but you will have two components to calculate with two coupled differential eqns complex functions make the math easier! Wave Function Wave nature described by wavefunction NOT like water or sound wave where matter actually moves More like light, wavefunction is a field electric field (and B(x,t) = magnetic field). has a value for every point in space For matter the wave function is Y(x,t) like nothing we’ve encountered before. Not an EM wave. does not have a direction in space. Wavefunction Interpreted For light beam, where the wave function (E-field) is large, the light is bright there are lots of photons For beam of matter particles, where the wave function is large there are lots of particles. The “bright” spots in interference pattern are where lots of photons or matter particles strike. Probability Interpretation If you have one particle, rather than a beam, the wavefunction only gives probability density P(x,t) = |Y(x,t)|2. there is no way to predict precisely where it will be. Where the wave function is large the particle is likely to be. The “bright” spots in interference pattern are where a photon or matter particle is likely to strike. Probability and Probability Density P(x,t) = |Y(x,t)|2 is the probability density at position x at time t like mass density. To get probability, must have finite region of space the probability of the particle being in a volume of space P volume |Y(r,t) | dV 2