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Heat Transfer and Energy 101 – Section 302 Ross A. Lazear February 20, 2007 AOS Review What is heat? Review What is heat? •Heat is energy in the process of being transferred from one object to another because of the temperature difference between them. •2nd law of thermodynamics: Heat is always transferred from warm to cold objects so as to warm the originally cooler object and cool the originally warmer object. •Heat is measured in “Joules.” Review • Two liters of boiling water has more heat (energy) than one liter of boiling water • Heat will not flow between two objects of the same temperature • The transfer of heat is always from a high temperature object to a lower temperature object. Heat transfer changes the internal energy of both systems involved, as in the first law of thermodynamics (conservation of energy). Specific Heat • Specific heat = Amount of heat energy required to raise the temperature of 1 g of a substance 1 oC. • An object with a high specific heat is an object that requires a large amount of heat energy in order to change its temperature (an example of this is water, with a specific heat of 1.00 cal g-1 oC-1) • A good example of this is a sand beach: http://outside.away.com/images/travel_photo_gallery/tropical_escapes_ss/image1.jpg Review Heat can be transferred by: Review Heat can be transferred by: CONDUCTION CONVECTION ADVECTION RADIATION Conduction • Transfer of heat through a material substance, molecule by molecule • If you were to put a metal rod over a flame, radiation from the flame will first transfer energy from the flame to the rod. • Then, the molecules in direct contact with the flame will gain energy and vibrate faster (remember the definition of temperature!) • The heated molecules will come in contact with nearby molecules, and gradually spread the heat through the material. Conduction The measurement of how well (or how fast) a material can transfer heat through conduction depends on how the material’s molecules are structurally bounded together. Substance Heat Conductivity (W/mK) Still air at 20o C 0.023 Dry soil 0.25 Water at 20o C 0.6 Snow 0.63 Mud 2.1 Ice 2.1 Granite 2.7 Iron 80 Silver 427 Conduction • Air is a very poor conductor of heat, which is why styrofoam cups are used to hold hot coffee. • In general, metals have very large conductivities. Thus, when they are heated, molecules will rapidly transfer heat through the metal. • So, if air is such a poor conductor of heat, how does the air in the lower atmosphere heat up so quickly when the sun comes out in the morning? Convection • Convection: Heat transfer by the mass movement of a fluid in the vertical, occurring in liquids and gases (fluids). • Warm air is less dense than cold air at the same atmospheric pressure (Ideal Gas Law!) • Think of cold air as being heavier. Thus, when the Earth’s surface is heated by solar (shortwave) radiation, heat conduction occurs. The thin layer of air molecules at the Earth’s surface is heated through conduction. This must begin to rise, because warm air is less dense than cold air. • Remember the Ideal Gas Law . . . Convection • Pressure always decreases with increasing height in the atmosphere • Recall, p = rRT • For a rising parcel of warm air, think of the parcel as a balloon. • As the parcel rises, lower pressure will exert less of a force on the parcel’s “wall.” This will allow the parcel to expand, and the temperature must then decrease. • Thus, a warm parcel will cool as it is lifted! This parcel is then displaced by other “thermals.” The process starts all over again, and a convective circulation arises. Convection • The cooling rate of a DRY thermal (the rising portion of the convective circulation) can actually be calculated: If a thermal consists of dry air, it will always cool at a rate of . . . 9.8 oC/km If a thermal is moist, the rate of cooling due to ascent varies based on the amount of water vapor the thermal contains (which depends on temperature). http://www.flyaboveall.com Convection • This is the same process that produces fair weather cumulus clouds and severe thunderstorms! http://en.wikipedia.org/wiki/Cumulus_humilis Convection Thanks to youtube, here are some great examples of atmospheric convection: http://www.youtube.com/watch?v=_cl0aw87LqA http://www.youtube.com/watch?v=1arvRoQBdWc http://www.youtube.com/watch?v=YXMVEpYRqyo http://www.youtube.com/watch?v=hV60nvuc7jc Advection • The transfer of heat by wind • The figure above demonstrates “warm air advection.” • Warm air is being advected eastward by the surface wind. • Over time, we expect the temperature to warm over the trees. Advection Locate regions of warm advection, cold advection, and neutral advection Radiation • Transferred through wave energy: Electromagnetic waves • Shorter wavelengths carry more energy than longer wavelengths • The wavelengths of the radiation emitted by an object depends on the temperature of that object (i.e., the sun mainly emits radiative energy in the visible spectrum, and the earth emits radiative energy in the infrared spectrum). Radiation • A photon of ultra-violet radiation carries more energy than a photon of infrared radiation. • The shortest wavelengths in the visible spectrum are purple, and the longest wavelengths are red. Radiation Emitted radiation can be: • Absorbed Increasing the internal energy of the gas molecules. • Reflected Radiation is not absorbed or emitted from an object but it reaches the object and is sent back. The Albedo represents the reflectivity of an object and describes the percentage of light that is sent back. • Scattered Scattered light is deflected in all directions, forward, backward, sideways. It is also called diffused light. • Transmitted Radiation not absorbed, reflected, or scattered by a gas, the radiation passes through the gas unchanged. Summary